• Corrosion Science and Technology
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• v.22 no.5
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• pp.359-367
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• 2023

The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050 ℃ for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides (10 ㎛ diameter) and Nb-Mo carbides (1 - 9 ㎛ diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all tested temperatures. Localized corrosion initiation occurred at 0.4 V_SSE in a temperature environment of 80 ℃ for both as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largely unchanged after solution heat treatment, with O1s, Cr2p_3/2, Fe2p_3/2, and Ni2p_3/2 present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.

• Journal of the KSME
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• v.44 no.6
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• pp.34-39
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• 2004

형상기억합금(SMA : Shape Memory Alloy)은 일반적인 금속이나 합금에서는 찾아볼 수 없는 형상기억효과(shape memory effect)와 초탄성 (superelasticity) 거동을 보이고 있다. 이러한 특성은 1951년에 금-카드뮴(Au-Cd) 합금에서 처음으로 발견되었으며, 1963년에 미국 해군병기연구소(Naval Ordnance Laboratory)에서 니켈-티타늄 (Ni-Ti) 합금에서 형상기억효과를 발견한 후로 널리 상용화되었다. 니티놀(nitinol)이라고 불려지는 니켈-티타늄 계열의 형상기억합금은 단위 부피당 많은 에너지를 낼 수 있고, 내 부식성(corrosion resistance)과 생화학적 적합성(bio-compatibility)이 뛰어나다. 또한 100,000사이클 이상의 긴 사용수명을 갖기 때문에 작동기(actuator)로서 우수한 특징을 갖는다. (중략)

• Korean Journal of Heritage: History & Science
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• v.53 no.1
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• pp.24-33
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• 2020

In excavated bronze artifacts, corrosion products of various shapes and colors are observed due to multiple corrosion factors coexisting in the burial environment, and these corrosion products can constitute important data not only in terms of long-term corrosion-related information, but also in connection with preservation of artifacts. As such, scientific analysis is being carried out on the corrosion layer and corrosion products of bronze artifacts, and the corrosion mechanism and the characteristics of corrosion products elucidated, which is essential for interpreting the exposed burial environment and its association with corrosion factors inside the burial environment. In this study, after classifying excavated bronze artifacts according to alloy ratio and fabrication technique, comprehensive analysis of the surface of corrosion artifacts, corrosion layer, and corrosion products was carried out to investigate the corrosion mechanism, formation process of the corrosion layer, and characteristics of corrosion products. The study designated two groups according to alloy ratio and fabrication technique. In Group 1, which involved a Cu-Sn-Pb alloy and had no heat treatment, the surface was rough and external corrosion layers were formed on a part, or both sides, of the inside and the outside, and the surface was observed as being green or blue. α+δ phase selection corrosion was found in the metal and some were found to be concentrated in an empty space with a purity of 95 percent or more after α+δ phase corrosion. The Cu-Sn alloy and heat-treated Group 2 formed a smooth surface with no external corrosion layer, and a dark yellow surface was observed. In addition, no external corrosion layer was observed, unlike Group 1, and α corrosion was found inside the metal. In conclusion, it can be seen that the bronze artifacts excavated from the same site differ in various aspects, including the formation of the corrosion layer, the shape and color of the corrosion products, and the metal ion migration path, depending on the alloy ratio and fabrication technique. They also exhibited different corrosion characteristics in the same material, which means that different forms of corrosion can occur depending on the exposure environment in the burial setting. Therefore, even bronze artifacts excavated from the same site will have different corrosion characteristics depending on alloy ratio, fabrication technique, and exposure environment. The study shows one aspect of corrosion characteristics in specific areas and objects; further study of corrosion mechanisms in accordance with burial conditions will be required through analysis of the corrosive layer and corrosive product characteristics of bronze artifacts from various regions.

• Corrosion Science and Technology
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• v.22 no.3
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• pp.193-200
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• 2023

Titanium alloy (grade-4) is commonly used in industrial and medical applications. To improve its corrosion resistance and biocompatibility for medical use, it is necessary to form a titanium oxide film. In this study, the morphology of the oxide film formed by anodizing Ti-grade 4 using different electrolytes was analyzed. Wetting properties before and after surface modification with SAM coating were also observed. Electrolytes used were categorized as A, B, and C. Electrolyte A consisted of 0.3 M oxalic acid and ethylene glycol. Electrolyte B consisted of 0.1 M NH₄F and 0.1 M H₂O in ethylene glycol. Electrolyte C consisted of 0.07 M NH₄F and 1 M H₂O in ethylene glycol. Samples B and C exhibited a porous structure, while sample A formed a thickest oxide film with a droplet-like structure. AFM analysis and contact angle measurements showed that sample A with the highest roughness exhibited the best hydrophilicity. After surface modification with SAM coating, it displayed superior hydrophobicity. Despite having the thickest oxide film, sample A showed the lowest insulation resistance due to its irregular structure. On the other hand, sample C with a thick and regular porous oxide film demonstrated the highest insulation resistance.

• Journal of the Korean Institute of Gas
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• v.5 no.3 s.15
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• pp.45-50
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• 2001

Open rack vaporizer (ORV) has been used in liquefied natural gas (LNG) receiving terminal in order to vaporize LNG into natural gas (NG) by heat exchange with seawater The U-type ORV which had been operated with seawater for 14 years is one of the important utilities of the gas production and the weld part of tube connected with header_ pipe had experienced many corrosion problems. To elucidate the cause of corrosion at weld part of vaporizer tube, corrosion potentials were compared by parts. This study concerns on the measurement of corrosion pit depth using non-destructive method and the evaluation of stress distribution in an aspect of safety with finite element analysis. In order to confirm the reliability of galvanic corrosion between weld parts and base metal, the measurement of corrosion potential by parts was conducted for 20 minutes in 3.5$\%$(wt.) NaCl solution. Many non-destructive methods were tried to measure the remaining thickness of vaporizer tube at fields. For general corrosion, tangential radiography test was confirmed as an effective method. In case of a fine corrosion pit, the shape of corrosion pit was reproduced using surface replication method. From collected data, stress distributions were quantitatively evaluated with 2-dimensional finite element method and the diagnostic evaluation on internal pressure of the U-type vaporizer could be made.

• Archives of Metallurgy and Materials
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• v.64 no.3
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• pp.917-920
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• 2019

Usually porous metals are known as relatively excellent characteristic such as large surface area, light, lower heat capacity, high toughness and permeability for exhaust gas filter, hydrogen reformer catalyst support. The Ni alloys have high corrosion resistance, heat resistance and chemical stability for high temperature applications. In this study, the Ni-based porous metals have been developed with Hastelloy powder by gas atomization and water atomization in order to find the effects of powder shape on porous metal. Each Hastelloy powder is pressed on disk shape of 2 mm thickness with 12 tons using uniaxial press machine. The specimens are sintered at various temperatures in high vacuum condition. The pore properties were evaluated using Porometer and microstructures were observed with SEM.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.6
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• pp.569-575
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• 1984

The characteristics of the stress corrosion cracking of SUS 304 stainless steel weldments were studied with the speciments of the constant displacement type under the environment of 42% MgC $l_{2}$ boiled solution (143.+.-.2.deg.C). The susceptibility of initiation and propagation of the stress corrosion crack was quantitatively inspected in the weld metal, heat affected zone and heat affected zone with including the reinforcement shape, respectively. Also, those susceptibility were discussed in connection with the change of mechanical and microstructural characteristics caused by heating cycle of welding. Main results obtained are as follows: (1)Stress corrosion cracking is easiest to initiate and propagate in the heat affected zone of weldment. (2)The susceptibility of stress corrosion cracking of the weldment is largely improved by eliminating the reinforcement part of the weld bead. (3)The dominant factor of the cracking susceptibility of the heat affected zone appeared to be the phenomenon of softening and sensitizing caused by welding heat cycle. (4)Under the low loading conditions, the behavior of stress corrosion cracking of the SUS 304 steel weldment is largely influenced by the pitting phenomenon in the front region of the main crack.

• Structural Engineering and Mechanics
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• v.78 no.5
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• pp.599-610
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• 2021

Early detection of small concrete crack or reinforcement corrosion is necessary for Structural Health Monitoring (SHM). Global vibration based methods are advantageous over local methods because of simple equipment installation and cost efficiency. Among vibration based techniques, FRF based methods are preferred over modal based methods. In this study, a new coupled method using frequency response function (FRF) and proper orthogonal modes (POM) is proposed by using the dynamic characteristic of a damaged beam. For the numerical simulation, wave finite element (WFE), coupled with traditional finite element (FE) method is used for effectively incorporating the damage related information and faster computation. As reported in literature, hybrid combination of wave function based wave finite element method and shape function based finite element method can addresses the mid frequency modelling difficulty as it utilises the advantages of both the methods. It also reduces the dynamic matrix dimension. The algorithms are implemented on a three-dimensional reinforced concrete beam. Damage is modelled and studied for two scenarios, i.e., crack in concrete and rebar corrosion. Single and multiple damage locations with different damage length are also considered. The proposed methodology is found to be very sensitive to both single- and multiple- damage while being computationally efficient at the same time. It is observed that the detection of damage due to corrosion is more challenging than that of concrete crack. The similarity index obtained from the damage parameters shows that it can be a very effective indicator for appropriately indicating initiation of damage in concrete structure in the form of spread corrosion or invisible crack.

• Corrosion Science and Technology
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• v.13 no.4
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• pp.145-151
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• 2014

The objectives of this study are to investigate the effect of the concentration ratios of Ni and Fe ions on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the Ni and Fe concentration ratios of 20:20 ppm, 39:1 ppm and 1:39 ppm at $325^{\circ}C$ for 14 days. In the case of the same Ni and Fe ion ratio (20:20), nickel ferrite with a polyhedral shape was formed. Nickel oxide deposits with a needle shape were formed in the condition of high Ni to Fe ion ratio (39:1), While polyhedral iron oxide and needle-like nickel oxide formed in the condition of low Ni to Fe ion ratio (1:39). The amount of deposits increased, when Fe oxides were formed. This indicates that Fe rich oxides stimulated Ni oxide deposition.

• Corrosion Science and Technology
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• v.10 no.1
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• pp.1-5
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• 2011

The major purpose of the present study is to evaluate the performance of various galvanized (GI) or galvannealed (GA) mild steels and AHSS in stamping applications. Finite Element Analysis (FEA) of selected stamping operations was conducted to estimate the critical pressure boundary conditions that exist in practice. Using this information, laboratory tribotests, e.g. Twist Compression (TCT), Deep Drawing (DDT) and Strip Drawing (SDT) Tests, were developed to evaluate the performance of selected lubricants and die materials/coatings in forming galvanized steels of interest. The sheet materials investigated included mild steels and AHSS (e.g. DP600 GI/GA, DP780 GI/GA, TRIP780 GA and DP980 GI/GA). Experimental results showed that galvanized material resulted in more galling, while galvannealed material showed more powdering and flaking. The surface roughness and chemical composition of galvanized sheet materials affected the severity of galling under the same testing conditions, i.e. lubricants and die materials/coatings. The results of this study helped to determine the critical interface pressure that initiates lubricant failure and galling in stamping selected galvanized sheet materials. Thus, to prevent or postpone the critical interface conditions, the results of this study can be used to select the optimum combination of galvanized sheet, die material, die coating and lubricant for forming structural automotive components.