• 제목/요약/키워드: Corrosion protection

검색결과 561건 처리시간 0.019초

3% NaCl용액중에 있어서 4340강의 부식거동과 과방식에 의한 수소포화거동에 미치는 인히비타의 영향 (The effect of inhibitors affecting to corrosion behaviors and hydrogen embrittlement behaviors due to over-propection of a 4340 steel in 3% NaCl solution)

  • 문경만;백태실;이상태
    • Journal of Advanced Marine Engineering and Technology
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    • 제13권4호
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    • pp.54-62
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    • 1989
  • When some kinds of inhibitors, i.e. $1{\times}10{-3}mol/l$ arsenic trioxide, 0.2 mol/l 2-mercaptoethanol, 0.2mol/l thiourea were added to 3% NaCl solution, there were some considererable effects to decrease corrosion current density in natural potential condition and the effect fo solution temperature increasing corrosion rate was smaller than that of no addition to 3% NaCl solution. However the susceptibility of hydrogen embrittlement due to over-protection in case of cathodic protection was much greater than that of no addition, especially was the greatest in case of addition of 2-mercaptoethanol. Therefore adding inhibitors for anti-corrosion effect, it is suggested that selection of the optimum protection potential is important from the view point of prevention against hydrogen embrittlement due to over-protection in case of cathodic protection.

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소형선박용 스테인리스강 축의 음극방식 응용 (Optimum Cathodic Protection for Stainless Steel Shaft of Small-Size Boat)

  • 배일용;박정대;강대선;이명훈;김기준
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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    • pp.232-233
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    • 2005
  • Stainless steel has been stably used closed by passivity oxidation films($Cr_2O_3$) is made by neutral atmospheric environment. However, passivity oxidation films of the surface of stainless steel occasionally comes to be destroyed in seawater which is influenced by an environment having halogen ion like $Cl^-$, then, localization corrosion comes to occur. Stainless steel 304 for shaft system material of the small-size FRP fishing boat on seawater environments made an experiment on simulation of sacrifical anode(Al, Zn). Through these experiment and study, following results have been obtained ; According to the field inspection and corrosion simulation, the corrosion on the 2nd class stainless steel shaft(STS 304) in FRP fishing boat has been verified to occur by crevice corrosion and galvanic corrosion etc.. According to the comparison and analysis of Stainless steel 304 shaft materials after simulation leaving unprotected and applying cathodic protection, unprotected shaft specimen of stainless steel 304 was severely corroded, but, protected shaft specimen was not totally corroded. This result is assumed to be made by the facts that anodic reaction, $Fe{\rightarrow}Fe^{2+}$ + $2e^-$, has been restricted by the cathodic protection current of sacrificial anode material.

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Effect of Additional Ag Layer on Corrosion Protection of Cu-Electrodeposited AZ31 Mg Alloy

  • Phuong, Nguyen Van;Moon, Sungmo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.97-97
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    • 2017
  • This study investigated the corrosion protection by electrodeposited copper layer on AZ31 Mg alloy with and without additional silver layer by immersion test, salt spray test, OCP transient and potentiodynamic polarization experiment. The single electrodeposited Cu layer on AZ31 Mg alloy showed a nodular structure with many imperfections of crevices between the nodules, which resulted in the fast initiation of pitting corrosion within first few hours of immersion. Double-layer coating of Cu and outer Ag layer slightly increased the initiation time for pitting corrosion. Triple-layer coatings of Cu/Ag/Cu exhibited the most efficient corrosion protection of AZ31 Mg alloy, compared to the single- and double-layer coatings. Surface morphology of the outer Cu layer in the triple-layer was changed from the nodular structure to fine particle structure with no crevices due to the presence of an additional Ag layer. Thus, the improved corrosion resistance of AZ31 Mg alloy by electrodeposited Cu/Ag or Cu/Ag/Cu layers is readily ascribed to the decreased number of imperfections in the electrodeposited layers due to the additional silver layer. It is concluded that the additional silver layer provides many nucleation sites for the second Cu plating, resulting in the formation of finer and denser structure than the first Cu electrodeposit.

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Practical Experiences with Corrosion Protection of Water Intake Gates in Mekong River

  • Phong, Truong Hong;Tru, Nguyen Nhi;Han, Le Quang
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.328-331
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    • 2008
  • Corrosion behaviour of water intake gate steel structures with different protective measures was investigated. Five material alternatives were taken for investigation, including: imported and recycled stainless steel, carbon steel with hot zinc spraying, painting and composite coatings. Results of corrosion rate for carbon steel, SUS 304, hot zinc spray coats in three water systems of Mekong river basin (saline, blackish and fresh) were also presented. Corrosion rate of carbon steel decreased with decreasing salinity in the investigated water environments. Meanwhile, these values for zinc coated steel, behaved by another way. Environmental data for these systems were filed and discussed in relation with corrosion characteristics. Method of Life Cycle Assessment (LCA) was applied in materials selection for water intake gate construction. From point of Life Cycle Cost (LCA) the following ranking was obtained: Zinc sprayed steel < Recycled stainless steel < Composite coated steel < Painting steel < SUS 304 From investigated results, hot zinc spray coating has been applied as protective measure for steel structures of water intake systems in Mekong river basin.

철근콘크리트 구조물에 Zn-Al 금속용사 전기방식 공법의 적용성에 관한 실험적 연구 (An Experimental Study on the Application of Cathodic Protection By Applying Zn-Al Metal Spray to an RC Structure)

  • 한만해;유조형;임영철;이한승
    • 한국건축시공학회지
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    • 제10권5호
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    • pp.21-29
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    • 2010
  • 희생양극방식은 지하구조물이나 해양환경하에서 구조물의 방식공법으로 소개되어지고 있다. 1970년대 이후, 희생양극방식이 철근콘크리트 구조물에 적용되어지고 있다. 희생양극방식은 전세계적으로 1990년대 이후 그 유효성을 검증되었다. 그러나, 희생양극방식은 시공적이나 경제적인 약간의 문제점을 가지고 있다. 그 문제점을 해결하기 위하여 고 내구성 금속을 용사시키는 희생양극방식이 개발되었다. 양극재(아연, 알루미늄)를 금속용사로 도포하여 실험체를 제작한 후, 실험체의 부식전류를 측정하여 양극재의 방식성능을 확인하였다. 실험결과 철근 콘크리트 구조물을 대상으로 금속용사를 이용한 희생양극방식이 우수한 방식성능을 가지는 것을 알 수 있었다.

Engineering Technology Far-end Telecontrol Cathodic Protection on the Structure of Jetty Bridge Cap Beams

  • Liu, Yi-Hsiung;Lim, Pau-Yee;Shih, Chien-Chis
    • Corrosion Science and Technology
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    • 제2권1호
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    • pp.47-52
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    • 2003
  • 23 cap beams on the 1 Km length jetty bridge in Shin-da power plant (Taipower co., Taiwan) utilize far-end telecontrol cathodic protection technology which is the first case ever used in Taiwan. The system comprises cathodic protection system and te1econtrol monitoring system. The control and monitoring such as protection current adjustment, protection potential and depolarization measurement of the 23 cap beams can be adjusted through system telecontrol operations. Thereby allows monitoring and control of the 23 anode zones in a convenient and cost effective way. This system is at present still in its best running condition since Sept. 1997 when it was completed. All the 23 cap beams can achieve the 100 mV depolarization potential criteria of protection. It meet the specifications of reinforced concrete cathodic protection standard and proved to be very excellent.

Effects of Weld Fume on the Corrosion Protection of Epoxy Coated on Carbon Steel

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • 제10권3호
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    • pp.80-86
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    • 2011
  • Welding was widely used in shipbuilding industries as a joining method. In present study, the effects of welding fume contaminated on steel surface on corrosion protection were examined by water ballast simulation test and condensation chamber test. Pull-off adhesion test, blistering test and cathodic disbondment test were carried out to evaluate the effects of residual welding fume. Consequently, it was clearly indicated that the residual welding fume didn't affect the corrosion protection of epoxy coated on steel when surface was treated by light sweep blasting to heavy sweep blasting which was applied in this study.

염해환경하 철근콘크리트의 철근 부식 및 방식기법 연구 (Research of Steel Corrosion and Corrosion Protection System for Reinforcing Steels in Concrete Exposed to Chloride Environments.)

  • 문홍식;이상국;송호진;정영수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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    • pp.653-658
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    • 2001
  • Recent long-span bridges, such as Kwang-Ahn Grand bridge, Seo-Hae Grand Bridge, Young-Jong Grand Bridge, etc, have been designed and constructed near the shore. Thus, it needs to analyze the durability of marine concrete structures which are exposed to severe chloride environments. It is well known that corrosion of reinforcement steel in concrete is one of the major factors for the durability of concrete structures. The objective of this experimental study is to investigate the performance of impressed current system and corrosion inhibitors for the corrosion protection of reinforced concrete structures. Concrete test specimens were made with various test parameters, such as cover depth, steel diameter, compressive strength, direction and frequency of notch. For the efficient evaluation of these corrosion protection systems, these tests have been carried out in the shore.

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삼인산 나트륨과 아질산 나트륨에 의한 탄소강 부식방지 특성 연구 (Study on The Corrosion Inhibition Characteristics of Carbon Steel by Sodium Phosphate And Sodium Nitrite)

  • 문전수;이재근
    • Corrosion Science and Technology
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    • 제9권3호
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    • pp.137-141
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    • 2010
  • Sodium nitrite is widely used as one of the popular corrosion inhibitors for the protection of ferrous metal in closed cooling water system, such as a diesel engine and a chiller. The optimum treatment conditions are studied through laboratory tests using linear polarization resistance (LPR) technique. Corrosion rate of the carbon steel electrode could be maintained less than $2.5{\times}10^{-3}$ mmpy in the test condition of 500 ppm as ${NO_2}^-$, 200 ppm as $Cl^-$, $70^{\circ}C$ and pH 6.8. The pH control is confirmed not to be an important factor in the protection of carbon steel by sodium nitrite inhibitor. The addition of tolyltriazole was needed for the protection of the copper alloy in the sodium nitrite treatment system.

상수도 배관용 무선 원격 부식모니터링 시스템 (The Remote Wireless Corrosion Monitoring System for Water Pipeline)

  • 하태현;배정효;이현구;하윤철;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 학술회의 논문집 정보 및 제어부문 B
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    • pp.637-640
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    • 2003
  • The owner of water pipeline has a burden of responsibility for the protection of corrosion and the prevention against leakage of water. So, they have been installed a CP(Cathodic Protection) System in oder to protect corrosion. And they also have been measured and analyzed the data about P/S(Pipe to Soil) potential of water pipeline. The P/S potential is basic data of evaluation for water pipeline corrosion. In this paper, results of development about remote wireless corrosion monitoring system for water pipe line are presented briefly.

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