• Title/Summary/Keyword: Corrosion of RPV steel

Search Result 5, Processing Time 0.019 seconds

Corrosion Behaviors of Neutron-Irradiated Reactor Pressure Vessel Steels with Various Nickel and Chromium Contents (Ni과 Cr 함량이 다른 원자로 압력용기용 강의 중성자 조사 후 내식성 평가)

  • Choi, Yong
    • Journal of the Korean institute of surface engineering
    • /
    • v.52 no.6
    • /
    • pp.293-297
    • /
    • 2019
  • Quasi-nano-hardness and corrosion behaviors of neutron-irradiated reactor pressure vessel (RPV) steels such as 15Ch2MFA (Ni<0.4, 2.520 n/㎠ (En>1.0 MeV) for 32 days. Quasi-nano-hardnesses of the 15Ch2MFA and 15Cr2NHFA steels were 183.8 and 179.8 Hv, respectively. Their corrosion rates and corrosion potentials were 2.4×10-4Acm-2, -515.9 mVSHE and 6.8×10-4 Acm-2, -523.6 mVSHE in NACE standard TM0284-96 solution at room temperature, respectively. 15Ch2MFA steel showed better quasi-nano-hardness and corrosion resistance than 15Cr2NHFA steel in this test condition.

Ni Plating Technology for PWR Reactor Vessel Cladding Repair

  • Hwang, Seong Sik;Kim, Dong Jin
    • Corrosion Science and Technology
    • /
    • v.18 no.5
    • /
    • pp.190-195
    • /
    • 2019
  • SA508 low-alloy steel for a reactor vessel was exposed to primary water in a pressurized water reactor (PWR) plant because the cladding layer of type 309 stainless steel for the RPV was removed, due to an accident in which the detachment of the thermal sleeve occurred. The major advantage of the electrochemical deposition (ECD) Ni plating technique is that the reactor pressure vessel can be repaired without significant thermal effects, and Ni has solid corrosion resistance that can withstand boric acid. The corrosion rate assessment of the damaged part was performed, and its trend was analyzed. Essential variables of the Ni plating for repair of the damaged part were derived. These conditions are applicable variables for the repair plating device, and have been carefully adjusted using the repair plating device. The process for establishing ASME technical standards called Code Case N-840 is described. The process of developing Ni-plating devices, and the electroplating procedure specification (EPS) are described.

He Generation Evaluation on Electrodeposited Ni After Neutron Exposure (중성자 조사에 따른 Ni도금피복재에서의 He발생량평가)

  • Hwang, Seong Sik;Kwon, Junhyun;Kim, Dong Jin;Kim, Sung Woo
    • Corrosion Science and Technology
    • /
    • v.20 no.5
    • /
    • pp.308-314
    • /
    • 2021
  • Neutron dose level at bottom head of a reactor pressure vessel (RPV) was calculated using reactor vessel neutron transport for a Korean nuclear power plant A. At 34 EFPY with a 40-year (2042) design life after plating repair, irradiation fast neutron effect was 6.6x1015 n/cm2. As helium(He) gas can be generated by Ni only at 1/106 level of 5 × 1021 n/cm2, He generation possibility in the Ni plating layer is very little during 40 years of operation (2042, 34 EFPY). Thermal neutrons can significantly affect the generation of He from Ni metal. At 10 years after a repair, He can be generated at a level of about 0.06 appm, a level that can add general welding repair without any consideration. After 40 years of repair, 9.8 appm of He may be generated. Although this is a rather high value, it is within the range of 0.1 to 10 appm when welding repair can be applied. Clad repair by Ni electroplating technology is expected to greatly improve the operation efficiency by improving the safety and shortening the maintenance period of the nuclear power plant.

Microstructural Characterization of Clad Interface in Welds of Ni-Cr-Mo High Strength Low Alloy Steel (Ni-Cr-Mo계 고강도 저합금강 용접클래드 계면의 미세조직 특성 평가)

  • Kim, Hong-Eun;Lee, Ki-Hyoung;Kim, Min-Chul;Lee, Ho-Jin;Kim, Keong-Ho;Lee, Chang-Hee
    • Korean Journal of Metals and Materials
    • /
    • v.49 no.8
    • /
    • pp.628-634
    • /
    • 2011
  • SA508 Gr.4N Ni-Cr-Mo low alloy steel, in which Ni and Cr contents are higher than in commercial SA508 Gr.3 Mn-Mo-Ni low alloy steels, may be a candidate reactor pressure vessel (RPV) material with higher strength and toughness from its tempered martensitic microstructure. The inner surface of the RPV is weld-cladded with stainless steels to prevent corrosion. The goal of this study is to evaluate the microstructural properties of the clad interface between Ni-Cr-Mo low alloy steel and stainless weldment, and the effects of post weld heat treatment (PWHT) on the properties. The properties of the clad interface were compared with those of commercial Mn-Mo-Ni low alloy steel. Multi-layer welding of model alloys with ER308L and ER309L stainless steel by the SAW method was performed, and then PWHT was conducted at $610^{\circ}C$ for 30 h. The microstructural changes of the clad interface were analyzed using OM, SEM and TEM, and micro-Vickers hardness tests were performed. Before PWHT, the heat affected zone (HAZ) showed higher hardness than base and weld metals due to formation of martensite after welding in both steels. In addition, the hardness of the HAZ in Ni-Cr-Mo low alloy steel was higher than that in Mn-Mo-Ni low alloy steel due to a comparatively high martensite fraction. The hardness of the HAZ decreased after PWHT in both steels, but the dark region was formed near the fusion line in which the hardness was locally high. In the case of Mn-Mo-Ni low alloy steel, formation of fine Cr-carbides in the weld region near the fusion line by diffusion of C from the base metal resulted in locally high hardness in the dark region. However, the precipitates of the region in the Ni-Cr-Mo low alloy steel were similar to that in the base metal, and the hardness in the region was not greatly different from that in the base metal.

A Study on the Integrity Evaluation Method of Subclad Crack Under Pressurized Thermal Shock (가압열충격 사고시 클래드 하부균열 안전성 평가 방법에 관한 연구)

  • Kim, Yeong-Jin;Kim, Jin-Su;Gu, Bon-Geol;Choe, Jae-Bung;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.25 no.7
    • /
    • pp.1139-1146
    • /
    • 2001
  • The reactor pressure vessel(RPV) is usually cladded with stainless steel to prevent corrosion and radiation embrittlement, and a number of subclad cracks have been found during an in-service-inspection. These subclad cracks should be assured for a safe operation under normal conditions and faulted conditions such as pressurized thermal shock(PTS). Currently available integrity assessment procedure for an RPV, ASME Code Sec. XI, are built on the basis of linear fracture mechanics (LEFM). In PTS condition, however, thermal stress and mechanical stress give rise to high tensile stress at the cladding and elastic-plastic behavior is expected in this area. Therfore, ASME Code Sec. XI is overly conservative in assessing the structural integrity under PTS condition. In this paper, the fracture parameter (stress intensity factor, K, and RT(sub)NDT) from elastic analysis using ASME Sec. XI and finite element method were validated against 3-D elastic-plastic finite element analyses. The difference between elastic and elastic-plastic analysis became significant with increasing crack depth. Therfore, it is recommended to perform elastic-plastic analysis for the accurate assessment of subclad cracks under TPS which causes plastic deformation at the cladding.