• Title/Summary/Keyword: Corrosion mechanism

검색결과 403건 처리시간 0.021초

Cut Edge Corrosion of Painted Zn and 55%Al-Zn Coated Steels under Alternate Wetting and Drying

  • Nishikata, A.;Tsuda, T.;Tsuru, T.
    • Corrosion Science and Technology
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    • 제9권1호
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    • pp.34-38
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    • 2010
  • Electrochemical study on cut edge corrosion of prepainted Zn coated (GI) and 55%Al-Zn coated (GL) steels has been performed in wet-dry cyclic conditions. Maximum width of delaminated polymer coating from the cut edge for GI and GL specimens was evaluated under wet-dry cyclic conditions. The cyclic tests were carried out for 1000 h by changing of relative humidity, where the salt of NaCl was deposited on the specimen every 48 h. The cut edge corrosion test under NaCl deposit indicated that the delamination of the GL specimen progresses at a higher rate than the GI. The electrochemical corrosion monitoring was also performed under condition of alternate exposure to immersion in NaCl solution and drying at 60%RH and $25^{\circ}C$. On the basis of the results of the delamination tests and electrochemical measurements, the mechanism of cut edge corrosion for GI and GL were discussed.

A study on the corrosion characteristics of GMA and FS welded Aluminium alloy (알루미늄 합금 접합부의 부식 특성 연구)

  • 윤병현;노중석;김홍주;장웅성
    • Proceedings of the KWS Conference
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    • 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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    • pp.293-295
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    • 2004
  • For the evaluation of corrosion resistance, Al 6061-T6 alloy was welded by Friction Sti. Welding(FSW) and Gas Metal Arc Welding(GMAW) evaluated by Tafel method and immersion test. The Tafel and immersion test results indicated that GMA weld was severely attacked compared with those of friction stir weld. It may be mainly due to the galvanic corrosion mechanism act on the CMA weld.

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The Effects of AC Corrosion on Underground Gas Pipeline Running Parallel with High Power Cables (전력케이블과 가스배관의 병행구간에 대한 교류부식 영향)

  • 배정효;김대경;김기준
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • 제49권10호
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    • pp.577-582
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    • 2000
  • This paper analyze the interference problems, especially Ac corrosion when the gas pipeline is buried with power cable in the same submarine tunnel. This paper present the results of the study about interference mechanism(inductive coupling, conductive coupling, resistive coupling), AC corrosion, limitation of safety voltage, modeling of power cables, gas pipeline and grounding systems, analysis of induction voltage and optimal arrangement of power cables.

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Integrated characterization of the corrosion products of Mg alloy (마그네슘 합금 부식 산화물에 대한 특성 연구)

  • Gwon, Sang-Jun;Heo, Jin-Yeong;Lee, Hong-Gi
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 한국표면공학회 2015년도 춘계학술대회 논문집
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    • pp.179-180
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    • 2015
  • pure Mg and some Mg alloys are relatively rapidly corroded after operation, resulting in the decrease of mechanical strength and change of local ion concentration. In this study, the corrosion mechanism of biodegradable implant materials was investigated by corrosion tests of the Mg alloy in Hank's solution. Particularly, the crystal structures and chemical bonding state of corrosion reactants was systematically examined.

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A Study on the Crevice Corrosion for Ferritic Stainless Steel (페라이트 스테인리스강의 틈부식에 대한 연구)

  • Baik Shin-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • 제10권1호
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    • pp.51-54
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    • 2004
  • In recently days, the breed fish farm is increased in the beach side for farming fish. In such a farm, the heater is requested for preventing freezing in cold season. The heating material are requested high corrosion resistance and strength for endurance high corrosive salt and pressure. In case of low corrosion resistance and/or strength, the heating element shall be broke down and eventually make spillage or leaking contaminated salt. In the most cases, crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. In this study, the crevice corrosion of Ferritic type 430 stainless steel is investigated. The size of specimen is $15{\times}20{\times}3mmt$. Test solution is 1N H2SO4 + 0.05N NaCl. The artificial crevice gap size is $0.24{\times}3{\times}15mmL$. Crevice corrosion is measured under applied voltage 300mV(SCE) to the external surface. the result of this study showed that 1) the induced time for initiation of crevice is 750seconds, 2) potential is dropped in the crevice from the top of gap opening from -320 to -399mV. The result confirmed that the potential drop(IR mechanism) in the crevice is one of mechanism for crevice corrosion.

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Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (II) (해수환경중 캐비테이션 침식-부식 하에서의 응력부식균열 거동 (II))

  • 안석환;임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • 제36권2호
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    • pp.139-146
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    • 2000
  • Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor $K_1$becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

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A Study on Cormsion Characteristics of Suspension Material by Surface Processing (표면가공법에 따른 현가장치재의 부식특성에 관한 연구)

  • Park Keyoungdong;Rpu Hyoungioo
    • Transactions of the Korean Society of Automotive Engineers
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    • 제13권3호
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    • pp.17-23
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    • 2005
  • In this study, the high strength and superior toughness spring steels as the suspension material, used for automobile and railroad industries were utilized to carry out the following investigations. Corrosion times were controlled in 7, 14,30 and 60days to examine the relation between corrosion pit and compressive residual stress in the static corrosion environment after shot peened. And then corrosion current and corrosion potential were measured for every 24 hours to investigate the corrosion mechanism. Shot peened material shows the low or rate of corrosion current as compared with unpeened material. In case of hot peened material which has the highest residual stress, it has a low corrosion current density.

Flow-Accelerated Corrosion Behavior of SA106 Gr.C Steel in Alkaline Solution Characterized by Rotating Cylinder Electrode

  • Kim, Jun-Hwan;Kim, In-Sup
    • Nuclear Engineering and Technology
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    • 제32권6호
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    • pp.595-604
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    • 2000
  • Flow-Accelerated Corrosion Behavior of SA106 Gr.C steel in room temperature alkaline solution simulating the CANDU primary water condition was studied using Rotating Cylinder Electrode. Systems of RCE were set up and electrochemical parameters were applied at various rotating speeds. Corrosion current density decreased up to pH 10.4 then it increased rapidly at higher pH. This is due to the increasing tendency of cathodic and anodic exchange half-cell current. Corrosion potential shifted slightly upward with rotating velocity. Passive film was formed from pH 9.8 by the mechanism of step oxidation and the subsequent precipitation of ferrous species into hydroxyl compound. Above pH 10.4, the film formation process was active and the film became stable. Corrosion current density showed increment in pH 6.98 with the rotating velocity, while it soon saturated from 1000 rpm above pH 9.8. This seems that activation process which represents formation of passive film on the bare metal surface controls the entire corrosion process

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Factors Affecting Stress Corrosion Cracking Susceptibility of Alloy 600 MA Steam Generator Tubes

  • Kang, Yong Seok;Lee, Kuk Hee;Shin, Dong Man
    • Corrosion Science and Technology
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    • 제20권1호
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    • pp.22-25
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    • 2021
  • In the past, Alloy 600 nickel-based alloys have been widely used in steam generators. However, most of them have been replaced by thermally treated alloy 690 tubes in recent years because mill annealed alloy 600 materials are known to be susceptible to stress corrosion cracking. Unlike this general perception, some steam generators using mill annealed alloy 600 tubes show excellent performance even though they are designed, manufactured, and operated in the same way. Therefore, various analyses were carried out to determine causes for the degradation of steam generators. Based on the general stress corrosion cracking mechanism, tube material susceptibility, residual stress, and sludge deposits of steam generators were compared to identify factors affecting stress corrosion cracking. It was found that mill annealed alloy 600 steam generator tubes showed higher resistance to stress corrosion cracking when the amount of sludge deposits on tube surface was smaller and residual stress generated during the fabrication was lower.

Three-dimensional Computational Modeling and Simulation of Intergranular Corrosion Propagation of Stainless Steel

  • Igarashi, T.;Komatsu, A.;Motooka, T.;Ueno, F.;Yamamoto, M.
    • Corrosion Science and Technology
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    • 제20권3호
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    • pp.105-111
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    • 2021
  • In oxidizing nitric acid solutions, stainless steel undergoes intergranular corrosion accompanied by grain dropping and changes in the corrosion rate. For the safe operation of reprocessing plants, this mechanism should be understood. In this study, we constructed a three-dimensional computational model using a cellular automata method to simulate the intergranular corrosion propagation of stainless steel. The computational model was constructed of three types of cells: grain (bulk), grain boundary (GB), and solution cells. Model simulations verified the relationship between surface roughness during corrosion and dispersion of the dissolution rate of the GB. The relationship was investigated by simulation applying a constant dissolution rate and a distributed dissolution rate of the GB cells. The distribution of the dissolution rate of the GB cells was derived from the intergranular corrosion depth obtained by corrosion tests. The constant dissolution rate of the GB was derived from the average dissolution rate. Surface roughness calculated by the distributed dissolution rates of the GBs of the model was greater than the constant dissolution rates of the GBs. The cross-sectional images obtained were comparable to the corrosion test results. These results indicate that the surface roughness during corrosion is associated with the distribution of the corrosion rate.