• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.3
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• pp.387-395
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• 2013

Recently, several circumferential cracks were found in the control rod drive mechanism (CRDM) nozzles of U.S. nuclear power plants. According to the accident analyses, coolant leaks were caused by primary water stress corrosion cracking (PWSCC). The tensile residual stresses caused by welding, corrosion sensitive materials, and boric acid solution cause PWSCC. Therefore, an exact estimation of the residual stress is important for reliable operation. In this study, finite element simulations were conducted to investigate the effects of the tube geometry (thickness and radius) on the residual stresses in a J-groove weld for different CRDM tube locations. Two different tube locations were considered (center-hole and steepest side hill tube), and the tube radius and thickness variables ($r_o/t$=2, 3, 4) included two different reference values ($r_o$=51.6, t=16.9mm).

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.1
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• pp.81-89
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• 2018

Austenitic stainless steels have excellent corrosion resistance, durability and fire resistance. Especially, since STS304L among austenitic types is a low-carbon variation of STS304 and has excellent intergranular corrosion resistance, it can often be used under the welded condition without heat treatment after field welding. This paper investigated ultimate behaviors such as ultimate strength and weld metal fracture mechanism of STS304L fillet-welded connections with TIG(tungsten inert gas) welding through test results. Main variables of specimens are weld length and welding direction against loading. Fracture of specimens are classified into three modes(tensile fracture, shear fracture and block shear fracture). Ultimate strengths were compared according to the welding direction and weld length and TFW series with transverse fillet weld had the highest strength compared with other types(LFW series with longitudinal fillet weld and FW series with all round weld). It is known that current design specifications such as KBC 2016 and AISC2010 underestimated the strength of TFW and LFW specimens and provided unconservative estimates for FW specimens. Finally, strength equations were proposed considering material properties of STS 304L material.

• Corrosion Science and Technology
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• v.11 no.1
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• pp.1-8
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• 2012

The development of martensitic grades which can be processed in continuous galvanizing lines requires the reduction of the oxides formed on the steel during the hot dip process. This reduction mechanism was investigated in detail by means of High Resolution Transmission Electron Microscopy (HR-TEM) of cross-sectional samples. Annealing of a martensitic steel in a 10% $H_2+N_2$ atmosphere with the dew point of $-35^{\circ}C$ resulted in the formation of a thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film and amorphous $_{a-X}MnO.SiO_{2}$ oxide particles on the surface. During the hot dip galvanizing in Zn-0.13%Al, the thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was reduced by the Al. The $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides however remained embedded in the Zn coating close to the steel/coating interface. No $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formation was observed. During hot dip galvanizing in Zn-0.20%Al, the $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was also reduced and the amorphous $_{a-X}MnO.SiO_{2}$ and $a-SiO_{2}$ particles were embedded in the $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formed at the steel/coating interface during hot dipping. The results clearly show that Al in the liquid Zn bath can reduce the crystalline $_{C-X}MnO.SiO_{2}$ (x>1) oxides but not the amorphous $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides. These oxides remain embedded in the Zn layer or in the inhibition layer, making it possible to apply a Zn or Zn-alloy coating on martensitic steel by hot dipping. The hot dipping process was also found to deteriorate the mechanical properties, independently of the Zn bath composition.

• Journal of the Korea Concrete Institute
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• v.17 no.6 s.90
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• pp.931-938
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• 2005

When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the seawater. Because the damages of corrosion resulting from the chloride ion are very serious, many researches have been performed. Silver nitrate colormetric method that can measure easily penetration depth of chloride ion has been executed, recent)y. However, characteristics of silver nitrate colormetric method were not fully examined. Therefore, the objective of this paper Is to study the applicability of colormetric method. For the purpose of this, effect factors and reaction mechanism of colormetric method were investigated, and the colormetric method is applied for marine concrete structures. According to the results of silver nitrate colored method, two reactions such as white reaction of AgCl and brown reaction of AgOH were shown when $AgNO_3$ was sprayed in splited section. And velocity constant ratio(K) of two reactions appeared that white reaction, AgCl reacts with the fast speed by 3240. When the colormetric method was applied in concrete, it is reasonable that $AgNO_3$ solution more than 0.05N concentration was sprayed. It is confirmed that the colormetric method is useful tool for estimating the chloride of concrete structures in situ. The average chloride amount of colored parts indicates $0.9kg/m^3$ per concrete unit weight.

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.1
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• pp.62-68
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• 2001

In order to characterize the microscopic fracture behaviour of the weldment din stress corrosion cracking(SCC) phenomena, SCC and acoustic emission(AE) tests were carried out simultaneously and the correlation between mechanical paramenters obtained from SCC and AE tests was investigated. In the case of base metal, much more AE events were produced at -0.5V than at -0.8V because of the dissolution mechanism before the maximum load. Regardless of the applied voltages to the specimens, however, AE events decreased after the maximum load. In the case of weldment, lots of AE events with larger amplitude $range(40{\sim}100dB)$ were produced because of the singularities of weld HAZ in comparision to the base metal and post-weld heat-treated(PWHT) specimens. Numerous and larger cracks for the weldment were observed on the fractured surfaces by SEM examination. From these results, it was concluded that SCC for the weldment appeared most severely in synthetic seawater. Weld HAZ was softened by PWHT which also contributed to the reduced susceptibility to corrosive environment in comparison to the weldment.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.569-577
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• 2021

CFRP(Carbon Fiber Reinforced Plastic) can maintain the same strength even if the diameter is reduced by about one - third, and the weight is about one - twentieth of that of the deformed reinforcing bars that have been used in the construction industry. In particular, it is resistant to corrosion, which is the weakest part of reinf orcing bars, and there is no concern that it will deteriorate over time, It is light and durable, so transportation costs are low and it is convenient for high-rise buildings. This paper experimentally clarifies the adhesive properties of CFRP and clarifies its behavior. That is, bond strength test was conducted with the directness of CFRP and the strength of concrete as experimental variables, and the bond mechanism was clarified experimentally. Furthermore, based on the experimental results, we constructed the bond stress-slip-strain relationship of CFRP compared to the existing deformed reinforcing bars.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.4
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• pp.455-472
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• 2018

It is important to study how to manage dry storage casks of spent nuclear fuels (SNF), because wet storage spaces for SNF will shortly be at full capacity in the Republic of Korea. The US has operated a dry storage cask system for several decades, and has carried out significant studies into how to successfully manage dry storage cask for SNF. This type of expertise and experience is currently lacking in the Republic of Korea. The degradation of dry casks is an important issue that must be considered. In particular, chloride-induced stress corrosion cracking (CISCC) is known to lead to the release of radioisotopes from canisters. The U.S. Department of Energy, U.S. Nuclear Regulatory Commission, and the Electric Power Research Institute have undertaken research into the CISCC mechanism. In addition, Sandia National Laboratories (SNL) has extensively researched CISCC and how to manage it in dry storage canisters. In this review paper, the probabilistic model proposed by the SNL is analyzed and, based on this model, US-based CISCC research is reviewed in detail. This paper will inform the management of dry cask storage of SNF from light water reactors in austenite stainless steel canisters in the Republic of Korea.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.288-294
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• 2009

Various polymer electrolyte membrane fuel cell (PEMFC) startup procedures were tested to explore possible techniques for reducing performance decay and improving durability during repeated startup-shutdown cycles. The effects of applying a dummy load, which prevents cell reversal by consuming the air at the cathode, on the degradation of a membrane electrode assembly (MEA) were investigated via single cell experiments. The electrochemical results showed that application of a dummy load during the startup procedure significantly reduced the performance decay, the decrease in the electrochemically active surface area (EAS), and the increase in the charge transfer resistance ($R_{ct}$), which resulted in a dramatic improvement in durability. After 1200 startup-shutdown cycles, post-mortem analyses were carried out to investigate the degradation mechanisms via various physicochemical methods including FESEM, an on-line $CO_2$ analysis, EPMA, XRD, FETEM, SAED, FTIR. After 1200 startup-shutdown cycles, severe Pt particle sintering/agglomeration/dissolution and carbon corrosion were observed at the cathode catalyst layer when starting up a PEMFC without a dummy load, which significantly contributed to a loss of Pt surface area, and thus to cell performance degradation. However, applying a dummy load during the startup procedure remarkably mitigated such severe degradations, and should be used to increase the durability of MEAs in PEMFCs. Our results suggest that starting up PEMFCs while applying a dummy load is an effective method for mitigating performance degradation caused by reverse current under a repetition of unprotected startup cycles.

• Journal of Powder Materials
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• v.9 no.6
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• pp.441-448
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• 2002

Dispersions of non-soluble ceramic particles in a metallic matrix can enhance the strength and heat resistance of materials. With the advent of mechanical alloying it became possible to put the theoretical concept into practice by incorporating very fine particles in a flirty uniform distribution into often oxidation- and corrosion- resistant metal matrices. e.g. superalloys. The present paper will give an overview about the mechanical alloying technique as a dry, high energy ball milling process for producing composite metal powders with a fine controlled microstructure. The common way is milling of a mixture of metallic and nonmetallic powders (e.g. oxides. carbides, nitrides, borides) in a high energy ball mill. The heavy mechanical deformation during milling causes also fracture of the ceramic particles to be distributed homogeneously by further milling. The mechanisms of the process are described. To obtain a homogeneous distribution of nano-sized dispersoids in a more ductile matrix (e.g. aluminium-or copper based alloys) a reaction milling is suitable. Dispersoid can be formed in a solid state reaction by introducing materials that react with the matrix either during milling or during a subsequent heat treatment. The pre-conditions for obtaining high quality materials, which require a homogeneous distribution of small dis-persoids, are: milling behaviour of the ductile phase (Al, Cu) will be improved by the additives (e.g. graphite), homogeneous introduction of the additives into the granules is possible and the additive reacts with the matrix or an alloying element to form hard particles that are inert with respect to the matrix also at elevated temperatures. The mechanism of the in-situ formation of dispersoids is described using copper-based alloys as an example. A comparison between the in-situ formation of dispersoids (TiC) in the copper matrix and the milling of Cu-TiC mixtures is given with respect to the microstructure and properties, obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.5
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• pp.263-267
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• 2017

The Co-Cr as-cast alloys are widely used in the manufacturing of orthopedic implants made with investment casting techniques because of its high strength, good corrosion resistance and excellent biocompatibility properties. Carbide precipitation at grain boundaries and interdendritic regions is the major strenthening mechanism in the as-cast condition. In this study, effects of GPS (Gas Pressured Sintering) heat-treatment on the microstructure and crystallinity of the as-cast Co-Cr alloy prepared by investment casting were investigated. It was confirmed that the content of metal carbide ($Cr_{23}C_6$) was increased in the grain boundary by using optical microscopy (OM), field-emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS).