• 제목/요약/키워드: Corrosion in chloride environment

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하이드로탈사이트계 방청제를 혼입한 콘크리트의 염화물확산계수 및 철근부식특성 (Chloride Diffusion Coefficient and Steel Corrosion Properties of Concrete containing Hydrotalcite-based Corrosion Inhibitor)

  • 강인영;김규용;윤민호;황의철;서원우;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.90-91
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    • 2017
  • Concrete can be used semi-permanently unless the steel is corroded. However, the concrete exposed to the marine environment is exposed to sea breeze, so chloride ions penetrate into the concrete and the steel is corroded accordingly. In order to solve these problems, there is a method of increasing the covering depth of the concrete and an application of the epoxy paint to the steel. In this study, the hydrotalcite type corrosion inhibitor was mixed with the concrete and the compressive strength, chloride diffusion coefficient and the corrosion properties of the steel were examined.

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Stress Corrosion Cracking of Heat Exchanger Tubes in District Heating System

  • Cho, Sangwon;Kim, Seon-Hong;Kim, Woo-Cheol;Kim, Jung-Gu
    • Corrosion Science and Technology
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    • 제18권2호
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    • pp.49-54
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    • 2019
  • The purpose of this paper is to present failure analysis, of the heat exchanger tube in a district heating system. SS304 stainless steel is used, as material for the heat exchanger tube. The heat exchanger operates in a soft water environment containing a small amount of chloride ions, and regularly repeats operation and standstill period. This causes concentration of chloride ions on the outer surface of the tube, as well as repeat of thermal expansion, and shrinkage of the tube. As a result of microscopic examination, cracks showed transgranular as well as branched propagation, and many pits were present, at the initiation point of each crack. Energy disperstive spectroscopy analysis showed Fe and O peak, as well as Cl peak, meaning that cracks were affected by Cl ion. Failure of the tube was caused by chloride-induced stress corrosion cracking by thermal stress, high temperature, and localized enrichment of chloride ions.

염화물을 함유한 콘크리트 중의 철근방식을 위한 방청제의 효과 (Effect of Corrosion Inhibitor for Reinforcing Steel in Concrete Containing Chlorides)

  • 문한영;김성수
    • 콘크리트학회지
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    • 제10권6호
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    • pp.325-333
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    • 1998
  • 염화물에 의한 콘크리트 중의 철근부식을 억제하기 위하여 콘크리트 배합시 방청제를 사용하는 방안이 일반적으로 많이 사용되고 있으나. 국내에서는 아직까지 방청제의 방식효과에 대한 연구는 찾아보기 어려운 실정이다. 본 연구에서는 염화물의 영향을 받는 콘크리트 중의 철근부식 억제를 위한 방안으로 방청제를 사용하여 철근의 방청효과를 알아보기 위하여 3종류의 방청제와 각각 사용량을 변화시킨 시험체를 제작하여 부식촉진 실험을 실시하였으며, 철근의 자연전위와 부시면적율을 측정하여 방식효과에 대하여 평가하였다. 그 결과 염화물의 혼입량이 지나치게 많을 경우에는 방청제의 양을 증가시켜도 방청효과가 크게 향상되지 않았으나. 염화물의 혼입량을 동일하게 사용하고 방청제의 양을 증가시켜도 방청효과가 크게 향상되지 않았으나, 염화물의 혼입량을 동일하게 방청제의 양을 증가시킬 경우에는 방청효과가 현저하게 좋아짐을 알 수 있었다.

염화물 환경에서 스테인리스강 용접부의 공식저항성 향상을 위한 마찰교반공정 적용효과에 관한 연구 (A study on the Application Effect of Friction Stir Processing for Enhanced Pitting Corrosion Resistance of Stainless Steel Welds in Chloride Environment)

  • 하종문;심덕남;김승현
    • 한국압력기기공학회 논문집
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    • 제19권2호
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    • pp.84-92
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    • 2023
  • As temporary storage facilities for spent nuclear fuels in domestic nuclear power plants are expected to be saturated, external intermediate storage facilities would be required in the future. Spent nuclear fuels are stored in metal canisters and then placed in a dry environment within concrete or metal casing for operation. In the United States, the dry storage method for spent nuclear fuels has been operated for an extended period. Based on the corrosion experiences of dry storage canisters in chloride environments, numerous studies have been conducted to reduce corrosion in welds. With the construction of intermediate storage facilities in Korea for spent nuclear fuels expected near coastal areas adjacent to nuclear power plants, there is a need for research on the corrosion occurrence of welds and mitigation methods for canisters in chloride environments. In this paper, we measured and compared the residual stresses in the Heat-Affected Zones (HAZ) after electron beam welding (EBW) and gas tungsten arc welding (GTAW) processes for candidate materials such as 304L, 316L, and duplex stainless steel(DSS). We investigated the possibility of microstructure control through the application of surface modification processes using friction stir processing (FSP). Corrosion tests on each welded specimen revealed a higher corrosion rate in EBW welds compared to GTAW. Furthermore, it was confirmed that corrosion resistance improved due to phase refinement and redistribution of precipitates when FSP was applied.

반전지-전위 측정방법을 활용한 슬래그 콘크리트의 철근 부식 저항성능 평가 (Evaluation of Steel Corrosion of Slag Concrete by Half-cell Potential Method)

  • 이보경;김규용;김래환;윤민호;이영욱;최경철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.3-4
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    • 2014
  • There is high probability of steel corrosion on the reinforced concrete exposed to marine environment by penetration of chloride ion. When making concrete structure with slag as admixture in marine environment, salt damage can be prevented. Therefore, this paper presents experimental results of steel corrosion resistance of slag concrete considering marine environment through half-cell potential method which is one of the nondestructive test. As a result of half-cell potential experiment, it was assumed that every specimen exposed to marine environment was not corroded, and as a result of destroying specimens, it was confirmed that there was no corrosion in specimens.

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Assessment of some parameters of corrosion initiation prediction of reinforced concrete in marine environments

  • Moodi, Faramarz;Ramezanianpour, Aliakbar;Jahangiri, Ehsan
    • Computers and Concrete
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    • 제13권1호
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    • pp.71-82
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    • 2014
  • Chloride ion ingress is one of the major problems that affect the durability of concrete structures such as bridge decks, concrete pavements, and other structures exposed to harsh saline environments. Therefore, durability based design of concrete structures in severe condition has gained great significance in recent decades and various mathematical models for estimating the service life of rein-forced concrete have been proposed. In spite of comprehensive researches on the corrosion of rein-forced concrete, there are still various controversial concepts in quantitation of durability parameters such as chloride diffusion coefficient and surface chloride content. Effect of environment conditions on the durability of concrete structures is one of the most important issues. Hence, regional investigations are necessary for durability based design and evaluation of the models. Persian Gulf is one of the most aggressive regions of the world because of elevated temperature and humidity as well as high content of chloride ions in seawater. The aim of this study is evaluation of some parameters of durability of RC structures in marine environment from viewpoint of corrosion initiation. For this purpose, some experiments were carried out on the real RC structures and in laboratory. The result showed that various uncertainties in parameters of durability were existed.

해양환경하에 방치한 콘크리트중의 철근의 부식 추정에 대한 연구 (A Study on the Estimation of Steel Corrosion in Concrete Exposed under the Environment of Seawater)

  • 문한영;김성수;류재석
    • 콘크리트학회지
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    • 제6권2호
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    • pp.129-137
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    • 1994
  • 해양환경하에 있는 콘크리트 구조물의 열화를 알아보고 철근의 부식 정도를 추정하기 위한 연구내용으로서 콘크리트 중에 철근을 묻은 공시체를 제작하여 간만의 차가 있는 해변에 1년 동안 노출시킨 상태로 시험을 실시 하여 콘크리트 중의 가용성 염분량, 철근의 자연전위값 및 철근의 부식정도에 대하여 고찰하였다. 본 연구 결과 콘크리트 중의 가용성 염분량은 물-시멘트비가 낮을수록, 혼화재를 혼입할 경우 적게 나타났으며 가용성 염분량이 클수록 철근의 부식이 크게 나타났다. 철근 부식의 정도가 심할수록 자연전위값이 감소하였으며 자연전위와 부식면적율과는 상관관계가 있음을 알 수 있었다.

부식촉진에 의한 해양.항만 철근 콘크리트 구조물의 철근 방식에 관한 실험적 연구 (Rapid Corrosion Test on Marine Reinforcing Steel)

  • 정근성;문홍식;송호진;이상국;정영수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.537-542
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    • 2001
  • Recently long-span bridges, such as Kwang-Ahn Grand bridge, Seo-Hae Grand Bridge, Young-Jong Grand Bridge, etc, have been designed and constructed near the shore. It needs to maintain the durability of marine concrete structures which are exposed to severe chloride environments. It is well known that corrosion of reinforcement steels in concrete structure is the most important cause for the durability of concrete structure which can be controlled by systematic preparatory corrosion protection works for economic and safe infrastructures. Various corrosion protection systems have been used for the corrosion protection of reinforcement steels from detrimental chemical components such as chloride, sulphate and etc. Since chloride can be penetrated into concrete in a variety way, an effective method has to be adopted by taking into full economical aspects and technical data of each protection system. The objective of this experimental study is to investigate the corrosion behavior of reinforcing steel in laboratory concrete specimens which are exposed to cyclic wet and dry saltwater, and then to develop pertinent corrosion protection system, such as corrosion inhibitors and cathodic protection for reinforced concrete bridges exposed to chloride environment. Resistance of various corrosion inhibitors and impressed current system have been experimentally evaluated under severe environmental conditions, and thus effective corrosion protection systems could have been Practically developed for future concrete construction.

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Fuzzy methodology application for modeling uncertainties in chloride ingress models of RC building structure

  • Do, Jeongyun;Song, Hun;So, Seungyoung;Soh, Yangseob
    • Computers and Concrete
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    • 제2권4호
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    • pp.325-343
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    • 2005
  • Chloride ingress is a common cause of deterioration of reinforced concrete located in coastal zone. Modeling the chloride ingress is an important basis for designing reinforced concrete structures and for assessing the reliability of an existing structure. The modeling is also needed for predicting the deterioration of a reinforced structure. The existing deterministic solution for prediction model of corrosion initiation cannot reflect uncertainties which input variables have. This paper presents an approach to the fuzzy arithmetic based modeling of the chloride-induced corrosion of reinforcement in concrete structures that takes into account the uncertainties in the physical models of chloride penetration into concrete and corrosion of steel reinforcement, as well as the uncertainties in the governing parameters, including concrete diffusivity, concrete cover depth, surface chloride concentration and critical chloride level for corrosion initiation. There are a lot of prediction model for predicting the time of reinforcement corrosion of structures exposed to chloride-induced corrosion environment. In this work, RILEM model formula and Crank's solution of Fick's second law of diffusion is used. The parameters of the models are regarded as fuzzy numbers with proper membership function adapted to statistical data of the governing parameters instead of random variables of probabilistic modeling of Monte Carlo Simulation and the fuzziness of the time to corrosion initiation is determined by the fuzzy arithmetic of interval arithmetic and extension principle. An analysis is implemented by comparing deterministic calculation with fuzzy arithmetic for above two prediction models.

경화된 콘크리트의 상태에 따른 염화물 확산특성 비교 (Comparison of Diffusion Characteristic of Chloride According to the Condition of Hardened Concrete)

  • 임영문;양은익;민석홍
    • 한국안전학회지
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    • 제19권3호
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    • pp.89-94
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    • 2004
  • Most reinforcements in concrete are constructed by steel. Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly professed by the chloride ingress. In general, chloride in concrete can be discriminated by two components, total chloride and fire chloride. This paper provides a testing method on the coefficient of chloride diffusion in concrete and the relationship between total chloride and free chloride in concrete for the composition of predicting model on diffusion rate of chloride. In order to complete this predicting model, this study will use chloride penetration characteristic, diffusion coefficient and experiment of color change on silver nitrate solution. This predicting model is going to help that grasp special quality on salt content inclusion of concrete structure that is exposed in chloride environment. Accurate predicting model can be effectively used not only in selecting of repair time but also in preventing from various deteriorations.