• 제목/요약/키워드: Corrosion in chloride environment

검색결과 206건 처리시간 0.034초

Valorization of Cork Waste to Improve the Anti-Corrosion Properties of Concrete Reinforcements

  • Belkhir, S.;Bensabra, H.;Chopart, J.P.
    • Corrosion Science and Technology
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    • 제21권2호
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    • pp.100-110
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    • 2022
  • Corrosion of steel reinforcement is the most important mode of concrete structures damages. It strongly depends on the composition and physicochemical properties of the cementitious medium. The use of waste materials as lightweight aggregates in concrete is environmentally recommended in polluted environments such as marine and/or industrial atmospheres in order to reduce its porosity and ensure the requested protection of reinforcing steel. The present study investigated the effect of waste cork addition on corrosion resistance of steel rebar in mortar specimen prepared in the laboratory. The main objective of this study was to improve the corrosion resistance of reinforcing steel. Another objective of this study was to valorize this ecological product and preserve the environment. Results obtained from various electrochemical tests indicated that the presence of a fine cork powder substantially improved the corrosion resistance of steel in the mortar contaminated by chloride ions. This improvement was reflected by a notable decrease in corrosion current density and a shift of corrosion potential of the steel towards more noble values. Moreover, the presence of a fine cork powder in the mortar had no adverse effect on its mechanical properties.

표면도장공법에 의한 균열부 콘크리트의 염소이온 침투제어 특성 (The Effect of Surface Treatment Systems on Chloride Penetration in Cracked Concrete)

  • 채규봉;윤인석;이창수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.525-528
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    • 2008
  • 건전하게 시공된 콘크리트는 충분한 내구성으로 장기수명을 갖는 것으로 알려졌다. 그러나 대다수의 콘크리트 표면에 존재하는 균열은 염소이온의 침투에 대한 빠른 침투 통로가 되어 내구성능을 저하시키는 것은 분명하다. 균열이 발생한 콘크리트의 수명을 연장하기 위한 중요한 사항은 염소이온으로 인한 부식의 위험성을 재고하는 것이다. 균열폭은 높은 철근비로 감소시킬 수 있으나, 실질적으로 균열이 발생한 콘크리트의 내구성 저하이다. 이처럼 균열폭이 작은 경우, 표면도장공법은 균열이 발생한 콘크리트의 내구성을 간단히 향상시킬 수 있는 하나의 방안으로 고려될 수 있다. 따라서, 다양한 표면도장공법이 균열이 발생한 콘크리트를 실링할 수 있는지에 대한 검토가 필요하다. 본 연구는 이와 같이 표면도포공법이 미세균열을 통한 염소이온 침투에 미치는 영향을 실험적 측면에서 고찰하고자 하였다. 실험변수로 침투재와 도포재의 단일 적용과 복합적용이 실험변수로 고려되었으며, 급속염소이온 침투 실험을 통하여 균열대비 염소이온 침투깊이를 검토하였다.

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콘크리트의 염소이온 확산특성에 미치는 시멘트 종류의 영향 (Influence of Cement Type on the Diffusion Characteristics of Chloride Ion in Concrete)

  • 박재임;배수호;이광명;김지상;차수원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.573-576
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-binder(W/B) ratio, age, cement type and constituents, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of cement type on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. For this purpose, the diffusion characteristics in concrete with cement type such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) were estimated for the concrete with W/B ratios of 32% and 38%, respectively. It was observed from the test that the difussion characteristics of BBC containing OPC and ground granulated blast-furnace slag was found to be most excellent of the cement type used in this study.

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Particle filter for model updating and reliability estimation of existing structures

  • Yoshida, Ikumasa;Akiyama, Mitsuyoshi
    • Smart Structures and Systems
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    • 제11권1호
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    • pp.103-122
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    • 2013
  • It is essential to update the model with reflecting observation or inspection data for reliability estimation of existing structures. Authors proposed updated reliability analysis by using Particle Filter. We discuss how to apply the proposed method through numerical examples on reinforced concrete structures after verification of the method with hypothetical linear Gaussian problem. Reinforced concrete structures in a marine environment deteriorate with time due to chloride-induced corrosion of reinforcing bars. In the case of existing structures, it is essential to monitor the current condition such as chloride-induced corrosion and to reflect it to rational maintenance with consideration of the uncertainty. In this context, updated reliability estimation of a structure provides useful information for the rational decision. Accuracy estimation is also one of the important issues when Monte Carlo approach such as Particle Filter is adopted. Especially Particle Filter approach has a problem known as degeneracy. Effective sample size is introduced to predict the covariance of variance of limit state exceeding probabilities calculated by Particle Filter. Its validity is shown by the numerical experiments.

단독 및 복합열화 환경하에서 염화물을 함유한 콘크리트의 내구성 평가에 관한 연구 (The Study on the Durability Estimation of Concrete Contained Chloride ion by Individual and Combined Deterioration)

  • 김영선;문형재;조봉석;김재환;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.503-506
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    • 2005
  • Recently, corrosion of reforcement of reinforced concrete structures and carbonation is raised problem of durability because of exhaustion of river sand and rapid increase of sea sand and also, concrete structure of sea environment is attacked to combined deterioration according to penetration of chloride ion and carbonation, change of temperature, repetition of dryness and wetness. Therefore, In this study, data base were presented to solve the problem about using sea sand to concrete structure situated in combined deterioration environment by exposuring concrete specimen contained chloride ion under the individual and combined deterioration.

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해양환경에 폭로한 콘크리트의 내염특성에 대한 실험적 연구 (I) (An Experimental Study on the Salt Resistance Properties with Concrete Materials under Marine Exposure Environment (I))

  • 신도철;김영웅;김용철;김동철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.51-56
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    • 2002
  • Protection against salt attack in seawater is obtained by using a dense, quality concrete with a low water-cement ratio, and a components appropriate for producing concrete having the needed salt resistance. The objective of this study is to evaluate the feature of corrosion with using the various concrete materials under marine exposure environment. According to the test results, slag powder and anti -corrosion inhibitor showed high chloride resistance effect. Also concre crack have an influence on corrosion of steel in spite of mixed design for salt resistance concrete. The requirement for low permeability is essential not only to delay the effect of salt attack, but also to afford adquate protection to reinforcement with admixtures.

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해양 환경 하에서 16.7Cr-10Ni-2Mo 스테인리스강의 표면 손상에 미치는 캐비테이션의 영향 (Effect of cavitation on surface damage of 16.7Cr-10Ni-2Mo stainless steel in marine environment)

  • 정상옥;한민수;김성종
    • Corrosion Science and Technology
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    • 제14권5호
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    • pp.239-246
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    • 2015
  • Stainless steel is generally known to have characteristics of excellent corrosion resistance and durability, but in a marine environment it can suffer from localized corrosion due to the breakdown of passivity film due to chloride ion in seawater. Furthermore, the damage behaviors are sped up under a cavitation environment because of complex damage from electrochemical corrosion and cavitation-erosion. In this study the characteristics of electrochemical corrosion and cavitation erosion behavior were evaluated on 16.7Cr-10Ni-2Mo stainless steel under a cavitation environment in natural seawater. The electrochemical experiments have been conducted at both static conditions and dynamic conditions inducing cavitation with different current density parameters. The surface morphology and damage behaviors were compared after the experiment. After the cavitation test with time variables morphological examinations on damaged specimens were analyzed by using a scanning electron microscope and a 3D microscope. the galvanostatic experiment gave a cleaner surface morphology presented with less damage depth at high current density regions. It is due to the effect of water cavitation peening under the cavitation condition. In the cavitation experiment, with amplitude of $30{\mu}m$ and seawater temperature of $25^{\circ}C$, weight loss and cavitation-erosion damage depth were dramatically increased after 5 hours inducing cavitation.

Corrosion Inhibition of Steel for Water Pipe Line by Adding a Non-Toxic Spearmint Extracts

  • Farooq, Hina;Kim, Jae-Yeon;Lee, Do-Il;Byeon, Jai-Won
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제17권2호
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    • pp.122-128
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    • 2017
  • Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.

제주도 대기환경의 부식성 평가 (Assessment of Atmospheric Corrosivity at Jeju Island)

  • 김귀식;양경조;허철구;송정화
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.253-259
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    • 2004
  • The Jeju Island in Korea is the clean area which the tradition culture is preserved locally well with the nature environment of Heaven's blessing. An air pollution is becoming recently serious problem as the industrial development is proceeded with the urbanization. This study investigates that the atmosphere environment at Jeju area influences on the metal corrosion. A study of the atmosphere corrosion for carbon steel, copper, zinc ana aluminium exposed on five test sites indoors and outdoors. Corrosion results are treated statistically and adjusted to a model previously proposed for carbon steel, copper, zinc and aluminium based on the influence of environmental parameters and main pollutants($SO_2$ and chlorides) on tire atmosphere corrosion of metals. Through this study, we try to set the standards atmosphere corrosion at Jeju Island.

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해안가의 계절별 비래염분량의 분포 특성 (Distribution properties of seasonal airborne sea salt in the seashore)

  • 이종석;최원성;문한영
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.237-240
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    • 2004
  • When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of a seasonal distribution at 33 spots, 6 areas in the East, West, South coast for 1 year. Results indicated that in the South coast, the amount of the airborne sea salt is comparatively higher in summer. in the West coast. higher in winter. On the other hand, in the East coast, the amount of the airborne sea salt is rarely affected by a season.

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