• Title/Summary/Keyword: Corrosion in chloride environment

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Tensile Properties of Hybrid FRP Rods with Glass and Carbon Fibers (유리와 탄소섬유로 제작된 하이브리드 FRP 로드의 인장특성에 관한 실험연구)

  • You, Yong-Jun;Park, Ji-Sun;Park, Young-Hwan;Kim, Keung-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.275-282
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    • 2006
  • Recently, Fiber Reinforced Polymers(FRP) has been emerged as an alternative material to solve the corrosion of steel reinforcement in reinforced concrete structures. FRP exhibits higher specific strength and lower weight compared to steel reinforcement. Moreover, good resistance to corrosion of the FRP may be useful in aggressive environments causing deterioration such as chloride environment. However, causes for higher initial cost of FRP than that of steel, little information on the long-term behavior of FRP, and brittle failure make the efforts to apply FRP in civil structures slow. Glass fiber among the fibers used to manufacture FRP can be seen as the most beneficial material with regard to initial costs. But its low elastic modulus, which attains barely a quarter of steel, nay thus lead to excessive deflections when used as reinforcement for flexural members. This research was carried out on the tensile properties of hybrid rods made with glass and carbon fibers to improve those of FRP rod made with glass fiber. Parameters were resin type and the arrangement of glass and carbon fibers. The tensile properties of hybrid rods were compared with those of rods manufactured with only glass or carbon fibers. The results indicated that the tensile properties of hybrid rod were good when the carbon fiber was arranged in the core.

Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System (3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향)

  • Khan, Md. Al-Masrur;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.82-92
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    • 2022
  • This study aims to investigate the effect of total electrochemical cell resistance (TECR) on electrochemical impedance (EI) measurements of reinforced concrete (RC) by electrochemical impedance spectroscopy (EIS) using a three-electrode system. A series of experimental study is performed to measure electrochemical behavior of a steel bar embedded in a concrete cube specimen, with a side length of 200 mm, in various experimental conditions. Main variables include concrete dry conditions, coupling resistance between sensing electrodes and concrete surface, and area of the counter electrode. It is demonstrated that EI values remains stable when the compliant voltage of a measuring device is sufficiently great compared to the potential drop caused by TECR of concrete specimens. It is confirmed that the effect of the coupling resistance of TECR is far more influential than other two factors (concrete dry conditions and area of the counter electrode). The results in this study can be used as a fundamental basis for development of a surface-mount sensor for corrosion monitoring of reinforced concrete structures exposed to wet-and-dry cycles under marine environment.

Reductive Degradation of hexachloroethane by using Iron Minerals: Kinetics studies (철 광물에 의한 헥사클로에탄의 환원적 분해: 반응 속도 연구)

  • Kim, Sung-Kuk;Park, Sang-Won
    • Journal of Soil and Groundwater Environment
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    • v.9 no.2
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    • pp.20-27
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    • 2004
  • Kinetic characteristics dependent on several factors such as iron mineral and organic solvents were investigated. When F $e^{0}$ , FeS and Fe $S_2$ were used as mediators, minerals affecting reaction rate were in the following order : $Fe_{0}$ 0/ > FeS > $FeS_2$ when in contact $C_2$C $l_{6}$ . The more chloride substituted, the higher reaction rate were observed. The reaction rates were dependent on pH, shaking rate, temperature and specific surface area. 1, 10-phenanthroline and EDTA degradation rates were fast, indicating that they adsorbed on the surface of the iron which makes the electron transfer reaction easy. Nitrate which has $\pi$* orbital of molecular can increase electron transfer rate because it is delocalized in its entity. The reaction rates were not affected by hydroquinone. Degradation rates were much enhanced with naturally occurring kaolinite because of the surface corrosion of Fe mineral. However, The reaction rate was not affected by F $e^{2+}$ or S $O_4$$^{2-}$ presented in solution.n.

Strength and Durability Characteristics of Low-alkali Mortar for Artificial Reefs Produced by 3D Printers (인공어초 3D 프린터 출력을 위한 저알칼리 모르타르의 강도와 내구성능)

  • Lee, Byung-Jae;Kim, Bong-Kyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.67-72
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    • 2022
  • Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.