• Title/Summary/Keyword: Corrosion in chloride environment

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A performance-based design method for chloride-induced cover cracking of RC structures

  • Yang, Dong-Hui;Yi, Ting-Hua;Li, Hong-Nan
    • Computers and Concrete
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    • v.20 no.5
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    • pp.573-582
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    • 2017
  • Chloride-induced cover cracking will aggravate the performance deterioration for RC structures under the chlorideladen environment, which may endanger the safety of structures and occupants. Traditional design method cannot ensure that a definite performance is satisfied. To overcome the defects, a study on the performance-based design method was carried out in this paper. Firstly, the limit state functions were established for the corrosion initiation and cover cracking. Thereafter, the uncertainty analysis was performed to study the effects of random factors on the time-dependent performances. Partial factor formulae were deduced through the first-order reliability method for performance verification. Finally, an illustrative example was presented and the sensitivity of cover depth to other parameters was carried out. It is found that the uncertainties of the random variables have great effects on the required cover depth. It is demonstrated that the performance-based design method can ensure that the target performance can be satisfied and support to formulate a rational maintenance and repair strategy for RC structures under the chloride environment.

Prediction of Deterioration Process for Concrete Considering Combined Deterioration of Carbonation and Chlorides Ion (중성화와 염해를 고려한 콘크리트의 복합열화 예측)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.902-912
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    • 2003
  • The most common deteriorating processes of concrete structures are carbonation and chloride ion ingress. Many concrete structures have been suffered from chloride ions diffusion or carbonation induced reinforcement corrosion damage and many studies have been done on it. However, those studies were confined mostly to the single deterioration of carbonation or chloride attack only, although actual environment is rather of combined conditions. In case of many in-situ concrete structures, deterioration happened more for the case of combined attack than the single case of carbonation or chloride attack. In this paper, chloride profiles of carbonated concrete is predicted by considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3∼5 mm over depth from carbonation depth. The analytical modeling of chloride diffusion was suggested to depict the relative influence of the carbonation depth. The diffusion coefficients of carbonation concrete and uncarbonated concrete with elapsed time were considered in this modeling.

Reliability-Based Service Life Estimation of Concrete in Marine Environment (신뢰성이론에 기반한 해양환경 콘크리트의 내구수명 평가)

  • Kim, Ki-Hyun;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.22 no.4
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    • pp.595-603
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    • 2010
  • Monte-Carlo simulation technique is often used in order to predict service life of concrete structure subjected to chloride penetration in marine environment based on probability theory. Monte-Carlo simulation method, however, the method gives different results every time that the simulation is run. On the other hand, moment method, which is frequently used in reliability analysis, needs negligible computational cost compared with simulation technique and gives a constant result for the same problem. Thus, in this study, moment method was applied to the calculation of corrosion-initiation probability. For this purpose, computer programs to calculate failure probabilities are developed using first-order second moment (FOSM) and second-order second moment (SOSM) methods, respectively. From the analysis examples with the developed programs, SOSM was found to give a more accurate result than FOSM does. The sensitivity analysis has shown that the factor affecting the corrosion-initiation probability the most was the cover depth, and the corrosion-initiation probability was influenced more by its coefficient of variation than its mean value.

A Study on the Evaluation of the Environmental Performance of Salt Damage in Concrete Bridges under Marine Environment (해양 환경하 콘크리트 교량의 염해환경 성능평가 연구)

  • Chai, Won-Kyu;Lee, Myeong-Gu;Son, Young-Hyun;Hong, Sung-Wook
    • Journal of the Korean Society of Safety
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    • v.33 no.5
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    • pp.60-69
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    • 2018
  • This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

Penetration Properties of Airborne Chlorides on Concrete Exposed in Marine Environment (해안환경에 노출된 콘크리트의 비래염분 침투 특성)

  • Lee, Jong-Suk;An, Gi-Hong
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.553-558
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    • 2012
  • Airborne chlorides are transported to inland by sea wind to be attached to seashore concrete structure surface then penetrated into concrete structure members. Since the surface attached chloride amount are dependent on the amount of airborne chlorides, the prediction of distribution of airborne chlorides is important information in preventing chloride corrosion problems in seashore concrete structures. The prediction of surface chloride amount from airborne chlorides environment is extremely difficult than concrete directly in contact with seawater. In addition, their penetrating tendency is different from that of concrete immersed in seawater. In this study, properties of surface and penetrated chlorides under airborne chlorides environment are investigated. Concrete specimens were manufactured and exposed to marine environment for 3 years. The specimens were analyzed at the time durations of 1, 2, and 3 years to check surface chloride amount to penetrated chloride depth. The results revealed that there were certain differences according to surface roughness of concrete and with and without washing effect due to rainfalls. The evaluation results showed that penetrated chlorides depend on amount of airborne chlorides and duration of exposure. In addition, a notable tendency of having deeper chloride penetration and higher chloride content in concrete members under long-term exposure was observed.

Fuzzy inference based cover thickness estimation of reinforced concrete structure quantitatively considering salty environment impact

  • Do, Jeong-Yun
    • Computers and Concrete
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    • v.3 no.2_3
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    • pp.145-161
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    • 2006
  • This article involves architecting prototype-fuzzy expert system for designing the nominal cover thickness by means of fuzzy inference for quantitatively representing the environment affecting factor to reinforced concrete in chloride-induced corrosion environment. In this work, nominal cover thickness to reinforcement in concrete was determined by the sum of minimum cover thickness and tolerance to that defined from skill level, constructability and the significance of member. Several variables defining the quality of concrete and environment affecting factor (EAF) including relative humidity, temperature, cyclic wet and dry, and the distance from coast were treated as fuzzy variables. To qualify EAF the environment conditions of cycle degree of wet-dry, relative humidity, distance from coast and temperature were used as input variables. To determine the nominal cover thickness a qualified EAF, concrete grade, and watercement ratio were used. The membership functions of each fuzzy variable were generated from the engineering knowledge and intuition based on some references as well as some international codes of practice.

Studies on the influence of zinc oxide as an inhibitor for the corrosion of mild steel in simulated concrete environments (콘크리트 환경에서 ZnO의 철근 부식 억제에 관한 연구)

  • Ha, Tae-Hyun;Bae, Jeong-Hyo;Lee, Hyun-Goo;Kim, Dae-Kyeong;Ha, Yoon-Cheol
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1873-1875
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    • 2005
  • The effect of zinc oxide as an inhibitor for the corrosion of steel in concrete environment was studied by weight loss measurements, potential-time behaviour and anodic polarization technique. The salient features of the investigation were: in 100% OPC extracts, the passivity of steel was readily destroyed, however extracts containing various concentration of zinc oxide, the passivity of steel was maintained even in the presence of 30,000 ppm of chloride. Alkalinity of concrete was maintained by the addition of zinc oxide. The efficiency of the inhibitor was found to increase with increasing inhibitor concentration. Addition of zinc oxide in the range 3 to 4% by weight of cement was sufficient to protect the rebars.

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Corrosivity of Atmospheres in the Korean Peninsula

  • Kim, Y.S.;Lim, H.K.;Kim, J.J.;Park, Y.S.
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.109-117
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    • 2011
  • The Korean Peninsula is located in the middle latitude of the northern hemisphere and has a clear 4-seasons and shows the typical temperate climate. Because of seasonal winds, it is cold and dry by a northwestern wind in the winter and it is hot and humid by a southeast wind in the summer. Also, temperature difference between the winter and the summer is large and it shows a rainy season from June to July but recently this regular trend may be greatly changed by an unusual weather phenomena. Since the Peninsula is east high west low type, the climate is complicated too. Because these geographical and climate characteristics can affect the properties of corrosion of metals and alloys, a systematic research on atmospheric corrosion in the Peninsula is required to understand and control the corrosion behavior of the industrial facilities. This paper analyzed the atmospheric corrosion factors for several environments in the Korean Peninsula and categorized the corrosivity of atmospheric corrosion of metals and alloys on the base of the related ISO standards. Annual pH values of rain showed the range of 4.5~5.5 in Korean Peninsula from 1999 to 2009 and coastal area showed relatively the low pH's rain. Annual $SO_2$ concentrations is reduced with time and its concentrations of every major cities were below the air quality standard, but $NO_2$concentration revealed a steady state and its concentration of Seoul has been over air quality standard. In 2007, $SO_2$classes of each sites were in $P_0{\sim}P_1$, and chloride classes were in $S_0{\sim}S_1$, and TOW classes were in ${\tau}_3{\sim}{\tau}_4$.That is, $SO_2$ and chloride classes were low but TOW class was high in Korean Peninsula. On the base of these environmental classes, corrosivity of carbon steel, zinc, copper, aluminium can be calculated that carbon steel was in C2-C3 classes and it was classified as low-medium, and zinc, copper, and aluminium showed C3 class and it was classified as medium.

An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe according to Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Jo, Hwang-Rae;Lee, Myung-Hoon;Kim, Yun-Hae;Moon, Kyung-Man
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.39-46
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    • 2007
  • The sea water pipe of a ship's engine room is a severely corrosive environment caused by fast flawing sea water containing chloride ions and high conductivity. Therefore, leaking of sea water may occur as a result of local corrosion of the welded zone. Leaking is usually controlled by various welding methods. In this study, when the sea water pipe is welded with certain welding methods and welding electrodes, the corrosion resistance of WM (Welding metal) and HAZ (Heat affected zone) was investigated using electrochemical methods. Although the corrosion potential of the HAZ is higher than that of WM, the corrosion resistance of WM is superior to HAZ. However, when WM and HAZ are both opened to the sea water, the WM part with the anode was more seriously corroded than was the HAZ of the cathode by performance of a galvanic cell due to difference of the corrosion potential between HAZ and WM. In particular TIG welding showed relatively good results in corrosion resistance of both HAZ and WM compared to other welding methods.

Influence of Carbonation on the Chloride Diffusion in Concrete (탄산화 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구)

  • Oh, Byung-Hwan;Lee, Sung-Kyu;Lee, Myung-Kue;Jung, Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.829-839
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    • 2003
  • Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation but the future studies for combined environment will assure the precise assessment.