• Title/Summary/Keyword: Corrosion density

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Characteristics of LDPE resin film depending on RP contents (적인 함유량에 따른 LDPE 수지 film의 특성연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6655-6665
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    • 2015
  • Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

Performance and Emission Characteristics of a Diesel Engine Operated with Wood Pyrolysis Oil (목질 열분해유를 사용하는 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Park, Jun-Hyuk;Choi, Young;Woo, Se-Jong;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.102-112
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    • 2012
  • The vast stores of biomass available in the worldwide have the potential to displace significant amounts of fuels that are currently derived from petroleum sources. Fast pyrolysis of biomass is one of possible paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO), also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is emulsification of BCO with diesel and bio diesel. In this study, a diesel engine operated with diesel, bio diesel (BD), BCO/diesel, BCO/bio diesel emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by BCO emulsions were examined. Results showed that stable engine operation was possible with emulsions and engine output power was comparable to diesel and bio diesel operation. However, in case of BCO/diesel emulsion operation, THC & CO emissions were increased due to the increased ignition delay and poor spray atomization and NOx & Soot were decreased due to the water and oxygen in the fuel. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion and clogging especially in the injection system.

A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence (LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구)

  • 문형순;권봉재;정문영;신상룡
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.8
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    • pp.17-25
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    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

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Evaluation of Bioactivity of Ti-6Al-7Nb Alloys with Various Hydrothermal Treatment Times (열수처리 시간에 따른 Ti-6Al-7Nh 합금의 생체활성 평가)

  • Kwon O. S.;Choi S. K.;Park K. B.;Lee M. H.;Bae T. S.;Lee O. Y.
    • Korean Journal of Materials Research
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    • v.14 no.12
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    • pp.876-884
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    • 2004
  • This study was to investigate whether the bioactivity of the anodized and hydrothermally treated Ti-6Al-7Nb alloy were affected by the time of hydrothermal treatment. Anodizing was performed at current density 30 $mA/cm^2$ up to 300 V in electrolyte solutions containing $DL-{\alpha}-glycerophosphate$ disodium salt hydrate $(DL-{\alpha}-GP)$ and calcium acetate (CA). Hydrothermal treatment was done at $300^{\circ}C$ for 30 min, 1 hr, 2 hrs, and 4 hrs to produce a thin film layer of hydroxyapatite (HA). The bioactivity was evaluated from HA formation on the surfaces in a Hanks' solution with pH 7.4 at $36.5^{\circ}C$ for 10, 20, and 30 days. Anodic oxide films were porous with pore size of $1\sim4{\mu}m\;and\;3\sim4{\mu}m$ thickness. The anodic oxide films composed with strong anatase peak with presence of rutile peak, and showed the increase in intensity of anatase peak after hydrothermal treatment. It was shown that the intensity of anatase peak increased with increasing the time of hydrothermal treatment but was no difference in rutile peak. The corrosion voltage was the highest in the group of hydrothermal treatment for 2 hrs (Ecorr: -338.6 mV). The bioactivity in Hank's solution was accelerated with increasing the time of hydrothermal treatment.

Effect of Al Addition on the Surface Nitrogen Permeation Treatment of 13%Cr Stainless Steels (13%Cr 스테인리스강의 표면 질소침투처리에 미치는 Al첨가의 영향)

  • Yoon, S.S.;Kim, K.D.;Lee, H.W.;Kang, C.Y.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.3
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    • pp.221-230
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    • 1999
  • The surface nitrogen permeation of Al alloyed 0.14%C-13%Cr stainless steels was investigated after heat treating at $1050^{\circ}C{\sim}1150^{\circ}C$ in the nitrogen gas atmosphere. The strong affinity between Al and nitrogen permeates the nitrogen through the interior of the steels. Two precipitates of round type and needle type are observed at the surface layer. These precipitates mainly consist of AlN containing plenty of aluminum. The surface layer of 0.53%Al alloyed specimen shows ferrite phase, while the surface layers of 1.65%Al and 2.27%Al alloyed specimens appear ${\gamma}$ plus ${\alpha}$ phases. The depth of nitrogen permeation depends upon the Al content and microstructure of the matrix. The 1.65%Al alloyed specimen representing ${\alpha}+{\gamma}$ matrix phases at the nitrogen permeation temperature shows the maximum case depth in this experiment. Although the surface hardness increases by raising the Al content of the specimen owing to the increase of nitride precipitation density, the nitride precipitation deteriorates the corrosion resistance in the solution of HCl, $H_2SO_4$, and $FeCl_3$.

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Effect of Sulfuric Acid Addition on the Aluminum AC Etching in HCl Solution (염산용액내에 황산 첨가에 의한 알루미늄의 교류에칭 특성)

  • Kim, Hangyoung;Choi, Jinsub;Tak, Yongsug
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.463-468
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    • 1998
  • When sulfuric acid was added in HCl etching solution, corrosion of aluminum metal was inhibited by the chemical adsorption of sulfate ions. In the presence of $SO_4^{-2}$, cyclic voltammetry showed that the protective oxide film was formed on the inner surfaces of etch pits and, pit density was increased by nucleation on both the aluminum surface and the pits inside. Structure and distribution of etch pits found in AC etching of aluminum were strongly influenced by the concentration of $SO_4^{-2}$ and the amount of cathodic pulse charging. Below $0.8mC/cm^2$ of cathodic pulse charging, oxide films formed inside actively dissolving pits indicated the higher resistance to pit nucleation as the concentration of $SO_4^{-2}$ increases. However, the structural change of oxide films occurred above the $0.8mC/cm^2$ charging and the effect of $SO_4^{-2}$ was minimized, and it resulted in the rapid formation of etch pits.

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The Evaluation of Structural Behavior of Hollowed PPC Girder Using Lightweight Aggregate Concrete (경량골재 콘크리트를 활용한 중공 PPC 거더의 구조거동 평가)

  • Lho, Byeong Cheol;Lee, Kyung Su;Kim, Ik Sang;Cha, Kwang Il
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.5
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    • pp.75-81
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    • 2011
  • Recently prestressed concrete bridges are generally used instead of reinforced concrete. PSC is more durable than RC because it can reduce crack problems, reinforcement corrosion, leakage and carbonation etc. And also PSC is more effective because there is no crack in tension area, and the entire concrete section is considered in section analysis. And it can reduce section size because vertical component by prestressing force can reduce the shear force. However, using high strength concrete can increase the self weight of bridge because of it's higher density. So the hollowed PPC girder with light weight aggregate can be a alternative. In this study the hollowed PPC girder with light weight aggregate is designed and the performance of hollowed PPC girder is evaluated by experimental tests as well as numerical analysis. As a result, The hollowed PPC girder of light aggregate behaved fully elastically under service load of 110kN, and the plastic behavior was showed after elastic behavior through experimental test, and it can be also estimated by numerical analysis.

Microstructure and Biocompatibility of Ti-Nb-Si-HA Composites Fabricated by Rapid Sintering Using HEMM Powders

  • Woo, Kee-Do;Kim, Sang-Hyuk;Kang, Dong-Soo;Kim, Dong-Gun
    • Korean Journal of Materials Research
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    • v.23 no.7
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    • pp.353-358
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    • 2013
  • To improve coating ability and the life of the coating, Ti based composite materials with hydroxyapatite(HA) should be developed. The raw materials of Ti-26wt%, Nb-1wt%, and Si with 10wt% HA were mixed for 24 h by a mixing machine and milled for 1 h to 6 h by planetary mechanical ball milling. Ti-26%Nb-1%Si-(10%HA) composites, composed of nontoxic elements, were fabricated successfully by spark plasma sintering(SPS) at $1000^{\circ}C$ under 70MPa. The relative density of the sintered Ti-Nb-Si-HA composites using the 24 h mixed powder, and the 6 h milled powder, was 91% and 97 %, respectively. The effects of HA contents and milling time on microstructure and mechanical properties were investigated by SEM and hardness tester, respectively. The Vickers hardness of the composites increased with increasing milling time and higher HA content. The Young's modulus of the sintered Ti-26%Nb-1%Si-10%HA composite using the 6 h-milled powder was 55.6 GPa, as obtained by compression test. Corrosion resistance of the Ti-26wt%Nb-1wt%Si composite was increased by milling and by the addition of 10wt%HA. Wear resistance was improved with increasing milling time. Biocompatibility of the Ti-Nb-Si alloys was improved by the addition of HA.

Effect of carbon and boron addition on sintering behavior and mechanical properties of hot-pressed SiC (카본 및 보론 첨가가 탄화규소 열간 가압 소결거동 및 기계적 특성에 미치는 영향)

  • Ahn, Jong-Pil;Chae, Jae-Hong;Kim, Kyoung-Hun;Park, Joo-Seok;Kim, Dae-Gean;Kim, Hyoung-Sun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.1
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    • pp.15-21
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    • 2008
  • SiC has an excellent resistance to oxidation and corrosion, high temperature strength and good thermal conductivity. However, it is difficult to density because of its highly covalent bonding characteristics. Hot-press sintering process was applied to fabricate fully densified SiC ceramics with carbon and boron addition as a sintering additive. The addition of carbon improved the mechanical properties of SiC because it could induce a fine and homogeneous microstructure by the suppression of abnormal growth of SiC grain. Also, the addition of carbon could control the phase transformation of SiC. The phase transformation of 6H to 4H increased with sintering temperature but the addition of carbon decreased that kind of phase transformation.

Microstructure of Ti-6Al-4V alloy (Ti-6Al-4V 합금의 미세구조 분석)

  • Kim, Tae Wan;Yoon, Yo Han;Oh, Ho Ra;Park, Jong Bum;Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.3
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    • pp.126-130
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    • 2016
  • Ti alloys have been used for orthopedic devices, automobile and aircraft because it has several beneficial properties such as a low density, a low modulus of elasticity, excellent high-temperature strength, excellent corrosion resistance and biocompatibility. In this study, Ti-64 composition (6 wt% Al, 4 wt% V) is investigated as a representative Ti-alloy system on the crystallographic characteristics and microstructure. We investigated crystal structure of the Ti-64 sample by XRD, and analyzed microstructure by compositional differences measured using FE-SEM and EDX.