• 제목/요약/키워드: Corrosion current

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An Electrochemical Study on the Corrosion Resistance Improvement of Galvanizing Steel by Dipping to Solution with Inhibitor (인히비터 첨가용액의 침지에 의한 용융아연도금 강판의 내식성 개선에 관한 전기화학적 연구)

  • Moon, Kyung-Man;Cho, Hwang-Rae;Kang, Tae-Young;Lee, Myung-Hoon;Kim, Yun-Hae
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.2
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    • pp.173-181
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    • 2007
  • Recently, galvanizing method is predominantly being used not only a economical point of view but also due to it s stability and long life. For example, guard rail of high way, all kinds of structures for ship etc. were protected with galvanizing and demand of galvanized structural materials was being increased with more and more. However, galvanized structures were inevitably being deteriorated with time eventually because they were corroded with solution of galvanizing film and exfoliation of it s film in the present severe corrosive environment. Therefore, it is necessary to improve the corrosion resistance of the galvanizing film through various methods such as variation of chemical composition of galvanizing bath, chromate treatment and coating treatment. In this study, three test specimens such as pure galvanizing, galvarium, and chromate treatment were submerged at tap water with inhibitor addition. And the effect of their corrosion resistance improvement was comparatively investigated with electrochemical method. Corrosion current density of the galvanized steel was the largest among three specimens, however, the galvarium steel showed the lowest corrosion current density. Futhermore, these three kinds of test specimens indicated considerably excellent corrosion resistance by dipped at tap water with inhibitor addition. Especially, the galvanized steel showed the best effect of corrosion resistance improvement than other test specimens.

A study on the prevention of the electric corrosion by leakage current using the Life of Sacrificial Anode in electric railway (전기철도 누설전류의 희생양극법을 이용한 전식 방지에 관한 연구)

  • Yeom, Sung-Bae;Park, Joon-Yeal;Lim, Myung-Hwan;Park, Sang-Wook;Kang, A-Ram
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.379-382
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    • 2009
  • Recently, Since the advent of KTX, the Electric Corrosion by leakage current is on the issue. The corrosion of Underground metal establishment near KTX system causing by its high voltage current become very serious problem. So We must figure for this. For the prevention of corrosion, Many methods is on the discussion. In this paper, We studied the Sacrificial Anode in many methods for its high efficiency.

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The Study of Corrosion of Heat Exchanger Tube for Absorption Refrigeration Machine (흡수식냉동기용 열교환기 세관의 부식에 관한 연구)

  • 임우조;정기철;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.147-152
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    • 2002
  • This paper was studied on corrosion of heat exchanger tube for absorption refrigeration machine. In the 62 % lithium bromide solution at $60^{\circ}C$, polarization test of Cu, Al-brass, 10 % cupro nickel(90-10 % Cu-Ni) and 30 % cupronickel(70-30 % Cu-Ni) tube was carried out. And polarization behavior, polarization resistance characteristics, open circuit potential, anodic polarization of heat exchanger tube for absorption refrigeration machine were considered. The main results are as following: The open circuit potential of Al-brass tube becomes less noble than that of Cu tube, corrosion current density of that becomes lower than Cu tube. The open circuit potential of cupronickel tube is more noble than that of Cu tube, corrosion current density of that is controlled than Cu tube. The passivation critical current of 30 % Cu-Ni tube is lower than that of 10 % Cu-Ni tube, potential of passive region of that is more wide than 10 % Cu-Ni tube.

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Micro-electrochemical Characteristics of Sensitized 304 Stainless steel Using Micro-droplet cell Techniques (마이크로 드로플릿 셀 기법을 이용한 예민화 된 304 스테인리스강의 미세전기화학 특성)

  • Kim, Kyu-Seop;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.300-309
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    • 2010
  • The influences of sensitization on localized corrosion resistance of 304 stainless steel, were investigated, using micro-dropletcell techniques. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local current with the potentiodynamic polarization, linear polarization and a.c. impedance. Micro-electrochemical tests were carried out inside of the grain and on grain boundaries separately. It was found that sensitization decreased the pitting potential, increasing corrosion current density around grain boundaries. Galvanic current density was also measured between grain and grain boundaries.

Effects of Mg on corrosion resistance of Al galvanically coupled to Fe (Fe와 galvanic couple된 알루미늄의 내식성에 미치는 마그네슘의 영향)

  • Hyun, Youngmin;Kim, Heesan
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.40-49
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    • 2013
  • Effects of magnesium and pH on corrosion of aluminum galvanically coupled to iron have studied by using potentio- dynamic and static tests for polarization curves, Mott-Schottky test for analysis of semiconductor property, and GD-AES and XPS for film analysis. Pitting potential was sensitive to magnesium as an alloying element but not to pH, while passive current was sensitive to pH but not to magnesium. It was explained with, instead of point defect model (PDM), surface charge model describing that the ingression of chloride depends on the state of surface charge and passive film at film/solution interface is affected by pH. In addition, galvanic current of aluminum electrically coupled to iron was not affected by magnesium in pH 8.4, 0.2M citrate solution but was increased by magnesium at the solution of pH 9.1. The galvanic current at pH 9.1 increased with time at the initial stage and after the exposure of about 200 minute, decreased and stabilized. The behavior of the galvanic current was related with the concentration of magnesium at the surface. It agreed with the depletion of magnesium at the oxide surface by using glow discharge atomic emission spectroscopy (GD-AES). In addition, pitting potential of pure aluminum was reduced in neutral pH solution where chloride ion maybe are competitively adsorbed on pure aluminum. It was confirmed by the exponential decrease of pitting potential with log of [$Cl^-$] around 0.025 M of [$Cl^-$] and linear decrease of the pitting potential. From the above results, unlike magnesium, alloying elements with higher electron negativity, lowering isoelectric point (ISE), are recommended to be added to improve pitting corrosion resistance of aluminum and its alloys in neutral solutions as well as their galvanic corrosion resistance in weakly basic solutions.

The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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Degradation Diagnosis of Overhead Power Lines Using Eddy Current Technology (와전류 기법을 이용한 가공전력선 열화 진단)

  • Kim, Chng-Hyeok;Kim, Tag-Yong;Oh, Yong-Cheul;Choi, Woon-Sik;Jo, Choon-Nam
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.5
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    • pp.322-327
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    • 2014
  • Internal corrosion of the distribution line can be detected in order to develop techniques of non-destructive inspection methods that operate only on the metal track eddy current diagnosis is possible by applying the technique investigated. Sensor for the production of a finite element method modeled by using an eddy current sensor, a distribution line by using an accelerated aging samples of sodium hydroxide was prepared. Sheathed cables for internal corrosion studies detected using an eddy current sensor is considered to be possible.

A New Protection Strategy of Impressed Current Cathodic Protection for Ship

  • Oh, Jin-Seok;Kim, Jong-Do
    • Journal of Mechanical Science and Technology
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    • v.18 no.4
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    • pp.592-596
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    • 2004
  • Corrosion is never avoided in the use of materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. The anode of ICCP system is controlled by an external DC source with converter. The function of anode is to conduct the protective current into seawater. The proposed algorithm includes the harmonic suppression control strategy and the optimum protection strategy and has tried to test the requirement current density for protection, the influence of voltage, the protection potential. This paper was studied the variation of potential and current density with environment factors, time and velocity, and the experimental results will be explained.

Validation of Some Protection Guidelines for Neighboring Pipelines against Fault Currents from Power Transmission Tower

  • Lee, Seong-Min;Song, Hong-Seok;Kim, Young Geun
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.77-81
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    • 2007
  • Fault current can be discharged from power transmission tower due to lightning or inadvertent contact of crane, etc. Pipelines in proximity to either the source of the ground fault or the substation grounding grid may provide convenient conductive path for the fault current to travel. Inappropriate measures to the neighboring pipelines against the fault current may cause severe damages to the pipes such as coating breakdown, arc burn, puncture, loss in wall thickness, or brittle heat-affected zone. Like inductive and conductive AC coupling, steadily induced fault current right after the coating breakdown can lead to corrosion of the pipeline. In this work, some protection guidelines against fault currents used in the field have been validated through the simulation and analytical method.

A Study on the Corrosion Monitoring of Multi-functional Sensors for Reinforced Concrete Structures: Part 1 (철근 콘크리트 구조물용 다기능 멀티센서의 부식 모니터링에 관한 연구: Part 1)

  • Jin, Chung-Kuk;Jeong, Jin-A;Kyoung, Eun-Jin
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.270-274
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    • 2012
  • This study represents the result of corrosion monitoring on reinforced concrete specimens by means of multi-functional corrosion monitoring sensors. To confirm the effectiveness of the sensors, eight different kinds of condition were adopted. Test factors were corrosion potential, current, corrosion rate, resistivity, and temperature, which were monitored with the sensors. Through this study, judging corrosion of steel in concrete with single corrosion factor such as corrosion potential was difficult, because many other factors can have an influence on the reaction of corrosion. By using three different kinds of sensors, it could enhance the accuracy of corrosion monitoring.