• Title/Summary/Keyword: Corrosion characteristics

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Investigation on Electrochemical Corrosion and Stress Corrosion Cracking Characteristics of Anodized 5083-H321 Alloy in Natural Seawater (양극산화된 5083-H321 합금의 천연해수 내 전기화학적 부식 및 응력부식균열 특성에 관한 연구)

  • Hwang, Hyun-kyu;Shin, Dong-Ho;Jung, Kwang-Hu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.5
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    • pp.259-264
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    • 2020
  • Many studies have been conducted to improve the corrosion resistance and durability of various aluminum alloys through the anodizing technique. It is already used as a unique technique for enhancing the properties of aluminum alloys in various industries. This paper investigated the electrochemical corrosion and stress corrosion cracking characteristics of anodized aluminum 5083-H321 alloy in natural seawater. The corrosion characteristics were assessed by the electrochemical technique and potentiodynamic polarization test. The stress corrosion cracking characteristic was evaluated with a slow strain rate tensile test under 0.005 mm/min rate, which showed that the hard anodizing film had a thickness of about 16.8 ㎛. Although no significant characteristics of stress corrosion cracking were observed in the slow strain rate test, the anodized specimen presented excellent corrosion resistance. The corrosion current density was measured to be approximately 4.2 times lower than that of the base material, and no surface damage was observed in the anodic polarization test.

Case studies on the probabilistic characteristics of ultimate strength of stiffened panels with uniform and non-uniform localized corrosion subjected to uniaxial and biaxial thrust

  • Cui, Jinju;Wang, Deyu;Ma, Ning
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.97-118
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    • 2019
  • Based on Nonlinear Finite Element Analysis (NFEA), this paper focuses on the bi-axial ultimate strength of typical bottom structures under corrosion. On one hand, uniform and not simultaneous corrosion across different structures is introduced, and surrogate models by Gaussian Process (GP) are built for both longitudinal and transverse cases individually, and corresponding probabilistic characteristics are investigated; meanwhile, corrosion effects on interaction between bi-axial stresses at ultimate state are studied. On the other hand, non-uniform localized pitting corrosion of normally distributed circular shapes is introduced, and different pitting corrosion densities are considered; structural bi-axial ultimate strengths under pitting corrosion are studied, and the results are compared with that from equivalent uniform corrosion; the probabilistic characteristics of structural ultimate strength in life cycle are studied; finally, the ultimate strength under randomly distributed pitting corrosion is compared with results from normally distributed pitting and uniform corrosion under various boundary conditions.

Anti-Corrosion Characteristics of WC-based Alloy Coatings Fabricated by HVOF Process - Polarization Characteristics in Alkaline Solution - (HVOF 용사법에 의해 제조된 WC계 합금 코팅층의 방식특성(II) - 알칼리 용액에서의 분극특성 -)

  • Kim, Tae-Yong;Kim, Yeong-Sik;Kim, Jae-Dong
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.40-44
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    • 2014
  • The purpose of this paper is to investigate polarization characteristics of WC-based alloy coatings in alkaline solution. The coatings were fabricated with WC-CrC-Ni, WC-Co-Cr and WC-Co composite powders by HVOF process. Corrosion tests of coatings and substrate were carried out using potentiostat/galvanostat at solution with pH 8 and pH 13. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be studied from polarization curve, and corrosion behavior was analyzed by SEM and EDS. WC-Co-Cr coating and WC-CrC-Ni coating showed more favorable anti-corrosion characteristics than WC-Co coating and substrate at solution with pH 8 and pH 13.

An Experimental Study on the Anti-corrosion and Anti-wear Characteristics of MoS$_2$ Bonded Films for Automotive Wheel Joints (방청 및 내마모 특성이 향상된 자동차 휠 조인트용 $MoS_2$계 고체 피막 윤활제)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
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    • v.16 no.3
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    • pp.173-181
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    • 2000
  • Friction, wear and corrosion characteristics of various MoS$_2$ bonded film lubricants were investigated to apply them to automotive wheel joints. MoS$_2$ bonded film lubricants were formulated by combinations of several additives and binders, and they were coated onto the pre-treated surfaces of specimens. Friction and wear characteristics were evaluated with Falex pin & vee-block test and LFW-1 block-on-ring test. For the corrosion resistant characteristics of the films, salt solution spray corrosion tests were performed. Results showed that MoS$_2$ bonded films containing both inorganic and organic corrosion-resistant additives yielded a synergy effect on anti-corrosion resistance. Also, binders having the better water-proof and thermal stability showed the lower friction and higher corrosion resistance.

Anti-Corrosion Characteristics of WC-based Alloy Coatings Fabricated by HVOF Process - Polarization Characteristics in Acid Solution - (HVOF 용사법에 의해 제조된 WC계 합금 코팅층의 방식특성(I) - 산성용액에서의 분극특성 -)

  • Kim, Tae-Yong;Kim, Yeong-Sik
    • Journal of Power System Engineering
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    • v.18 no.4
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    • pp.72-77
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    • 2014
  • The aim of this study to investigate polarization characteristics of WC-based alloy coatings fabricated by high velocity oxygen fuel(HVOF) process. The coatings were fabricated by HVOF process with WC-CrC-Ni, WC-Co-Cr, WC-Co composite powders. Corrosion tests were carried out using potentiostat/galvanostat at solution with pH 2 and pH 6. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be analyzed from polarization curve. WC-Co-Cr coating showed more incorrodible characteristics than other coatings at solution pH 2. WC-CrC-Ni coating was more favorable anti-corrosion characteristics than other coatings at solution with pH 6.

The Effect of Seawater Temperature on the Electrochemical Corrosion Behaviour of Stainless Steels and Anodized Aluminum Alloys (스테인리스강과 양극산화된 알루미늄 합금의 전기화학적 부식특성에 미치는 해수온도의 영향)

  • Chong, Sang-Ok;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.2
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    • pp.85-93
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    • 2021
  • The corrosion damage of materials in marine environment mainly occurs by Cl- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

Effect of Fusing Treatment on Anti-Corrosion Characteristics of Ni-based Self-flux Alloy Coating (니켈기 자융성 합금 코팅의 방식특성에 미치는 후열처리의 영향)

  • Kim, Tae-Yong;Kim, Jae-Dong;Kim, Yeong-Sik
    • Journal of Power System Engineering
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    • v.17 no.4
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    • pp.79-85
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    • 2013
  • This study aims at investigating the effect of a fusing treatments on anti-corrosion characteristics of Ni-based self-flux alloy coating. Ni-based coatings were fabricated by flame spray process on steel substrates, and fusing treatments were performed using a vacuum furnace at $800^{\circ}C$ $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. After fusing treatments, corrosion tests were carried out using potentiostat/galvanostat at solution with pH 2 and pH 6. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be analyzed from polarization curve. Fusing-treated coating at $1100^{\circ}C$ showed more favorable anti-corrosion characteristics than as-sprayed coating. Anticorrosive effect of fusing-treated coating at solution with pH 2 was relatively greater than at solution with pH 6. Fusing-treated coating at $1100^{\circ}C$ showed the most excellent anti-corrosion characteristics.

Corrosion Characteristics of Excavated Bronze Artifacts According to Corrosion Environment (부식 환경에 따른 출토 청동 유물의 부식 특성)

  • Jang, Junhyuk;Bae, Gowoon;Chung, Kwangyong
    • Korean Journal of Heritage: History & Science
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    • v.53 no.1
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    • pp.24-33
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    • 2020
  • In excavated bronze artifacts, corrosion products of various shapes and colors are observed due to multiple corrosion factors coexisting in the burial environment, and these corrosion products can constitute important data not only in terms of long-term corrosion-related information, but also in connection with preservation of artifacts. As such, scientific analysis is being carried out on the corrosion layer and corrosion products of bronze artifacts, and the corrosion mechanism and the characteristics of corrosion products elucidated, which is essential for interpreting the exposed burial environment and its association with corrosion factors inside the burial environment. In this study, after classifying excavated bronze artifacts according to alloy ratio and fabrication technique, comprehensive analysis of the surface of corrosion artifacts, corrosion layer, and corrosion products was carried out to investigate the corrosion mechanism, formation process of the corrosion layer, and characteristics of corrosion products. The study designated two groups according to alloy ratio and fabrication technique. In Group 1, which involved a Cu-Sn-Pb alloy and had no heat treatment, the surface was rough and external corrosion layers were formed on a part, or both sides, of the inside and the outside, and the surface was observed as being green or blue. α+δ phase selection corrosion was found in the metal and some were found to be concentrated in an empty space with a purity of 95 percent or more after α+δ phase corrosion. The Cu-Sn alloy and heat-treated Group 2 formed a smooth surface with no external corrosion layer, and a dark yellow surface was observed. In addition, no external corrosion layer was observed, unlike Group 1, and α corrosion was found inside the metal. In conclusion, it can be seen that the bronze artifacts excavated from the same site differ in various aspects, including the formation of the corrosion layer, the shape and color of the corrosion products, and the metal ion migration path, depending on the alloy ratio and fabrication technique. They also exhibited different corrosion characteristics in the same material, which means that different forms of corrosion can occur depending on the exposure environment in the burial setting. Therefore, even bronze artifacts excavated from the same site will have different corrosion characteristics depending on alloy ratio, fabrication technique, and exposure environment. The study shows one aspect of corrosion characteristics in specific areas and objects; further study of corrosion mechanisms in accordance with burial conditions will be required through analysis of the corrosive layer and corrosive product characteristics of bronze artifacts from various regions.

Characteristics of Pit Corrosion and Estimation Models of Corrosion Depth in Buried Water Pipes (상수도관의 부식특성과 부식깊이 추정 모델)

  • Kim, Jea-Hag;Ryu, Tae-Sang;Kim, Ju-Hawn;Ha, Sung-ryung
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.689-699
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    • 2007
  • The accurate estimation of water pipe deterioration is indispensable to prevent pipe breakage and manage in advance. In this study, corrosion of water pipe is adopted, which is relatively underestimated although it takes most part of deteriorating pipeline. Predicting corrosion rate and corrosion depth of a pipe can make an increase the life span of the pipeline, which is laid under the ground according to characteristics of soil and water corrosion. For the purpose, mathematical models that can presume nominal depth through estimation of pit corrosion and corrosion rate is introduced. As comparison of results with conventional methods in other foreign countries, it is evaluated that the external corrosion depth is estimated less than the models, proposed by other researchers and the internal corrosion rate was processed faster than the external corrosion rate.

Effects of Corrosion Resistance Characteristics of Opponent Materials in relative Motion on Sliding Wear Behavior of Mild Carbon Steel (상대재 내식성이 철강재료의 미끄럼마모 특성에 미치는 영향)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.35 no.2
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    • pp.139-147
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    • 2019
  • This study investigates the effects of corrosion resistance characteristics of opponent materials in relative motion on the sliding wear behavior of mild carbon steel. Pin specimens made of mild carbon steel are tested at several sliding speeds against mating discs made of two types of alloyed steels, such as type D2 tool steel (STD11) and type 420 stainless steel (STS420J2), with different corrosion resistance characteristics in a pin-on-disc type sliding wear test machine. The results clearly show that the sliding wear behavior of mild carbon steel is influenced by the corrosion resistance characteristics of the mating disc materials at low sliding speeds. However, the sliding wear behavior at high sliding speeds is irrelevant to the characteristics because of the rising temperature. During the steady state wear period, the sliding wear rate of mild carbon steel against the type 420 stainless steel at a sliding speed of 0.5 m/s increases considerably unlike against the type D2 tool steel. This may be because the better corrosion resistance characteristics achieve a worse tribochemical reactivity. However, during the running-in wear period at low sliding speeds, the wear behavior of mild carbon steel is influenced by the microstructure after heat treatment of the mating disc materials rather than by their corrosion resistance characteristics.