• Title/Summary/Keyword: Corrosion behaviors

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Fatigue Life Prediction for Electric Railway Catenary wires (가선재의 피로수명 예측)

  • Kim, Yong-Ki;Chang, Se-Ky
    • Proceedings of the KSR Conference
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    • 2003.10c
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    • pp.558-567
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    • 2003
  • The catenary wires are damaged by periodic running of train as well as repeated stress. The wires are also degraded by atmosphere corrosion at fields. Corrosion of wires increased surface roughness and deteriorated mechanical properties by providing fatigue crack initiation sited resulting in a bad effect on service life of the wires. Fatigue test of catenary wires performed to estimate service lifetime. Also, simulation to analyze stress on catenary wires was conducted through modelling the finite elements for dynamic behaviors of wires. Fatigue life of catenary wires was estimated with fatigue and simulation tests.

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Electrochemical Evaluation of Corrosion Properties of Aluminum Alloy as a Sacrificial Anode for Offshore Structure Protection (해양구조물의 방식을 위한 알루미늄 합금의 희생양극적 부식 특성의 전기화학적 평가)

  • Rhee, Jin-Ho;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.48 no.2
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    • pp.68-72
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    • 2015
  • The corrosion behavior of metals and alloys for the safety of offshore structures in seawater was investigated for the application of sacrificial anodes. The experiments were focused on the polarization behaviors and the surface morphology of each metal after experiments. Pure Zn, pure Al (Al1050), Al alloys (Al5052, Al6061), Mg alloys (AZ31, AZ91D) and steel (SCM440) were assessed in 3.5% sodium chloride solution by means of potentiodynamic polarization to verify the galvanic corrosion potential ($E_{couple}$). Potentiostat plots were plotted to compare the surface and corrosion current density ($i_{couple}$) of metals as sacrificial anodes in seawater to protect steel alloy as a cathode. Al alloys showed the best performance as a sacrificial anode, on the other hand, Mg alloys showed overprotection behavior. The surface morphologies of sacrificial anodes were observed by FESEM and compared.

Suppression of Aluminum Corrosion in Lithium Bis(trifluoromethanesulfonyl)imide-based Electrolytes by the Addition of Fumed Silica

  • Louis, Hamenu;Lee, Young-Gi;Kim, Kwang Man;Cho, Won Il;Ko, Jang Myoun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1795-1799
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    • 2013
  • The corrosion property of aluminum by lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is investigated in liquid and gel electrolytes consisting of ethylene carbonate/propylene carbonate/ethylmethyl carbonate/diethyl carbonate (20:5:55:20, vol %) with vinylene carbonate (2 wt %) and fluoroethylene carbonate (5 wt %) using conductivity measurement, cyclic voltammetry, scanning electron microscopy, and energy dispersive X-ray spectroscopy. All corrosion behaviors are attenuated remarkably by using three gel electrolytes containing 3 wt % of hydrophilic and hydrophobic fumed silica. The addition of silica particles contributes to the increase in the ionic conductivity of the electrolyte, indicating temporarily formed physical crosslinking among the silica particles to produce a gel state. Cyclic voltammetry also gives lower anodic current responses at higher potentials for repeating cycles, confirming further corrosion attenuation or electrochemical stability. In addition, the degree of corrosion attenuation can be affected mainly by the electrolytic constituents, not by the hydrophilicity or hydrophobicity of silica particles.

Effect of the change of second phase hardness on corrosion fatigue behavior of dual phase steel in 3% nacl solution (3% NaCl 수용액중에서 복합조직강의 부식피로거동에 미치는 제2상 속도변화의 영향)

  • 오세욱;김웅집
    • Journal of Ocean Engineering and Technology
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    • v.6 no.2
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    • pp.85-93
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    • 1992
  • The only hardness of 2nd phase of martensite in dual phase steel which was composed of the martensite and ferrite was changed. Fatigue test was conducted by cantilever type of self-made rotated bending fatigue testing machine. The corrosion fatigue fracture behaviors of dual phase steel were investigated in 3% NaCl solution at $N_f$ = $1.5\times$$10^5$ $N_f$=1.0 $\times$ $10^6$ cycles. The fatigue strength was increased with increasing the hardness of 2nd phase. The size and number of corrsion pits were influenced by the 2nd phase hardness and pits remain constant in size just after they were transited into cracks. The life of crack initiation was effected by stress level. The shape of relation of $\Delta$K and da/dn has smaller scattering in it in 3% NaCl solution than that in air. The higher the 2nd phase hardness is, the higher the corrosion fatigue life becomes. Corrosion fatigue fracture behavior was effected by mechanics in case of $N_f$=1.5$\times$10$^5$$N_f$=1.5$\times$10$^6$ cycles.

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Corrosive Characterisics of 12Cr Alloy Steel and Fatigue Characteristics of the Artificially Degraded 12Cr Alloy Steel (고온의 인공해수 중 12Cr강의 부식피로특성에 관한 연구)

  • Jo, Seon-Yeong;Kim, Cheol-Han;Bae, Dong-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.5
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    • pp.772-778
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    • 2001
  • In this study, corrosion fatigue characteristics of 12Cr alloy steel were investigated in 3.5wt.% NaCl solution of 150$^{\circ}C$ and 4.5bar. Behavior of corrosion fatigue cracks was measured by the indirect compliance method and compared with the results in distilled water and in air. 1) 12Cr alloy steel was susceptible to temperature. Its susceptibility was increased as the temperature was increased. 2) The crack growth characteristics of 12Cr alloy steel in distilled water were similar to 3.5wt.% NaCl solution. 3) The temperature of solution affects to the crack growth characteristics of 12Cr alloy steel. In corrosion solutions of 4.5bar, 150$^{\circ}C$, fracture surfaces of corrosion fatigue crack growth at a/W=0.3 was showed the trans-granular fracture suface. As the crack grew up, it was changed to inter-granular type. In condition of high temperature, The crack growth behaviors of 12Cr alloy steel were remarkable.

A Study on the Post-Weld Heat Treatment Effect Affecting Corrosion Behavior and Mechanical Property of Welding Part of RE36 Steel for Marine Structure (해양구조물용 RE36강 용접부의 부식거동 및 기계적 특성에 미치는 용접후 열처리 효과에 관한 연구)

  • 김성종;문경만
    • Journal of Welding and Joining
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    • v.19 no.1
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    • pp.65-74
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    • 2001
  • A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

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A Study on the Mechanical Properties and Corrosion Resistance of GCD40 by Plasma Nitriding (플라즈마 질화처리한 GCD40의 기계적성질 및 내식성에 관한 연구)

  • Kim, M.K.;Jung, B.H.;Kim, S.S.
    • Journal of Power System Engineering
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    • v.6 no.1
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    • pp.74-81
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    • 2002
  • The characteristics of corrosion resistance for the surface of ductile cast iron(GCD40) by plasma nitriding process have been studied in terms of electrochemical polarization behaviors including corrosion potential($E_{corr}$), anodic polarization trends, polarization resistance($R_p$), and also have been studied microstructures, hardness and specific wear of nitrided layer Nitrided layer showed an enhanced hardness values in all the plasma nitriding condition investigated. In the result of wear test, specific wear of nitrided specimens were much decreased than that of non-treated specimens. In the results of XRD, ${\gamma}'phase\;and\;{\varepsilon}$ phase were detected in nitrided surface. And it was found that ${\varepsilon}$ phase was decreased and ${\gamma}'phase$ was increased respectively, as the nitriding time became longer. In the test of corrosion resistance, natural potentials in all the nitrided specimens were towards noble directions than in the case of non-treated specimens. The measurement of electrode potentials revealed that corrosion resistivity of plasma nitrided specimens were higher than in the case of the non-treated specimens.

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Enhancing Effects of NaHSO3 on Corrosion of T91 Steel

  • Wu, Tangqing;Tan, Yao;Wang, Jun;Xu, Song;Liu, Lanlan;Feng, Chao;Yin, Fucheng
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.368-378
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    • 2020
  • In the paper, corrosion behavior of T91 steel in different concentrations of NaHSO3 solution was studied in combination with scanning electron microscope (SEM) and electrochemical measurements. The results showed that the steel exhibited active anodic dissolution characteristics in the solution, and NaHSO3 concentration affected both cathodic and anodic behaviors. The steel surface was covered by intact corrosion products in the solutions, but the compactness and mechanical properties of the corrosion products degraded with the increase of NaHSO3 concentration. In low-concentration NaHSO3 solution the steel tended to undergo uniform corrosion with slight corrosion pits, but its corrosion mode gradually transited to localized corrosion as the NaHSO3 concentration increased. The mechanical property degradation of the corrosion products caused by sulfur compounds and the pH decrease of the solution are the important factors to accelerating its corrosion process.

Surface Compatibility and Electrochemical Behaviors of Zirconia Abutment for Prosthodontics (보철용 지르코니아 어버트먼트의 표면적합도와 전기화학적 거동)

  • Park, K.H.;Jeong, Y.H.;Kim, W.G.;Choe, H.C.;Kim, M.S.
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.41-46
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    • 2009
  • The fit between dental implant fixture and zirconia abutment is affected by many variables during the fabrication process by CAD/CAM program and milling working. The purpose of this study was to evaluate the surface compatibility and electrochemical behaviors of zirconia abutment for prosthodontics. Zirconia abutments were prepared and fabricated using zirconia block and milling machine. For stabilization of zirconia abutments, sintering was carried out at $1500^{\circ}F$ for 7 hrs. The specimens were cut and polished for gap observation. The gap between dental implant fixture and zirconia abutment was observed using field-emission scanning electron microscopy (FE-SEM). The hardness and corrosion resistance of zirconia abutments were observed with vickers hardness tester and potentiostat. The gap between dental implant fixture and zirconia abutment was $5{\sim}12{\mu}m$ for small gap, and $40{\sim}60{\mu}m$ for large gap. The hardness of zirconia surface was 1275.5 Hv and showed micro-machined scratch on the surface. The corrosion potentials of zirconia abutment/fixture was .290 mV and metal abutment/fixture was .280 mV, whereas $|E_{pit}-E_{corr}|$ of zirconia abutment/fixture (172 mV) was higher than that of metal abutment/fixture (150 mV). The corrosion morphology of metal abutment/fixture showed the many pit on the surface in compared with zirconia abutment/fixture.