• 한국재료학회지
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• 제13권11호
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• pp.761-768
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• 2003

The corrosion resistance and cytotoxicity behavior of Ti alloys were studied as a function of Nb contents(3wt.%Nb, 20wt.%Nb, 40wt.%Nb). Ti-Nb alloys were melted by vacuum arc furnace and then rolled to 50% reduction ratio after homogenized at 105$0^{\circ}C$ for 24hrs. The corrosion resistance of Ti-Nb alloys were investigated by potentiodynamic polarization test in the 0.9% NaCl and 5% HCI solution. Biocompatibility of Ti-Nb alloys was evaluated by cytotoxicity test. The results can be summarized as follows 1) The microstructure change from equiaxial to acicular and the increased $\beta$ phase in Ti-Nb alloys were obtained as the Nb content increased. 2) For the corrosion test in the solution of 0.9% NaCl and 5% HCI, the corrosion behavior of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 3) For the cytotoxicity test, Ti-Nb alloys showed excellent biocompatibility compared to ASTM grade 2 CP Ti, 316L STS and Co-Cr alloys.

• 한국해양공학회지
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• 제25권6호
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• pp.56-59
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• 2011

The demand for cold rolled steel (CR) for structural members is gradually increasing. If no surface treatment (coating for corrosion resistance) for CR is conducted, its use is very limited because CR is vulnerable to corrosion. Therefore, we need to develop a coating solution to provide high corrosion resistance for CR. In this study, an organic/inorganic coating solution with Si and Ti (Si polysilicate 7 wt.% + Urethane 13 wt.% + Ti amorphous 0.5 wt.%; LR-0727(1)) was used to evaluate the corrosion resistance of CR under a salt spray test. The specimens with the LR-0727(1) coating were heat treated in a drying oven at $120{\sim}210^{\circ}C$for 5 min. The corrosion resistance was investigated using a salt spray test of 7 h. In addition, an adhesive test was conducted. Rust showed under a heat treatment of $150^{\circ}C$, but no vestiges were found over $160^{\circ}C$. The specimens with heat treatment at $160^{\circ}C$ or more did not experience delamination. From these results, it is considered that the temperature limit for optimum heat treatment is $160^{\circ}C$ considering energy efficiency.

• 한국건축시공학회지
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• 제14권6호
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• pp.505-513
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• 2014

본 연구에서는 전기화학적인 시험 및 CASS Test(염수분무시험)을 실시하여 중방식도장 시험체와 용융아연도금 시험체, Zn-Al 시험체와의 비교를 통해 Zn-Sn 금속용사의 방식 성능을 평가하였다. 시험 결과, 전기화학 시험을 통하여 Zn-Sn / Zn-Al 상온금속용사 시스템 공법의 방식원리는 방식전위에 의하여 확보되는 것을 확인하였으며 강구조물의 방식 공법으로서 상온금속용사 공법은 용융아연도금 공법과 중방식 도장공법과 비교하여 매우 우수한 방식성능을 가지고 있는 것이 CASS 시험을 통하여 검증되었다. 특히 Zn-Sn 금속용사와 Zn-Al 금속용사를 비교해본 결과 그 방식성이 현저하게 차이가 있지는 않았으나 Zn-Sn(65:35) 비율의 시험체가 가장 우수하였다. 또한 중방식 도장은 손상된 부분에서 현저하게 녹이 발생하고 도막이 박리되지만, Zn-Sn / Zn-Al 상온금속용사 시스템 공법은 갈바닉 희생방식에 의하여 매우 높은 부식 방지 특성을 가지고 있음을 확인 하였다.

• Corrosion Science and Technology
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• 제16권5호
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• pp.241-246
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• 2017

The comparative results of corrosion testing in humid tropical atmosphere in rural and coastal areas for hot dipped zinc coatings are presented below. The test was conducted in outdoor conditions over a period of five years. The mass loss and other performance characteristics of two types of zinc coatings were evaluated, analysed and discussed in relation to the climatic and environmental parameters. The corrosion rates of the coatings exposed to coastal conditions were about three times higher than the corrosion rates appreciated in rural conditions. The data demonstrates that the corrosion process obeys an equation of the form $M=At^n$, where M is the loss of metal and t is the time of exposure. A and n are constants which values depend on the environmental characteristics and the physicochemical behavior of the corrosion products respectively. Corrosion is strongly influenced by atmospheric time of wetness (TOW) and airborne salinity. The nature and composition of corrosion products are also considered. Simonkolleite, a major crystalline phase, was found in the zinc corrosion products exposed to coastal conditions, while zinc hydroxide and zinc hydrosulfate are easily found in rural settings.

• 한국항공우주학회지
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• 제35권1호
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• pp.46-51
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• 2007

연구는 Al 2024-T3511 재료를 사용하여 피로균열성장 시험을 통한 비부식과 부식에서의 일정진폭 피로균열 전파 테이터(a-N)를 구하여 비부식과 부식에서의 균열진전의 차이를 규명하였다. 또한 비부식과 부식에서의 균열진전 속도 선도(da/dN-${\Delta}K$)를 구하여 Paris의 식을 이용하여 비부식과 부식의 차이를 규명하였다. 그리고 ${\beta}c$(corrosion factor)의 새로운 개념을 도입하여 피로수명을 예측해 본 결과 실험치를 잘 모사할 수 있었다.

• Corrosion Science and Technology
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• 제20권3호
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• pp.129-142
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• 2021

Effects of corrosion inhibitors (i.e., sodium nitrite, sodium hexametaphosphate, trimethylamine (TEA), sugar, and urea) on the corrosion resistance of carbon steel in CaCl₂ solution were investigated. The test solution was designed with response surface methodology of design of experiments (DOE) in the range of 0 ~ 50 ppm for NaNO₂, 0 ~ 200 ppm for (NaPO₃)₆, 0 ~ 2000 ppm for TEA, 0 ~ 3000 ppm for sugar, 0 ~ 200 ppm for urea with 3 wt% CaCl₂. The corrosion potential and the corrosion rate were measured with potentiodynamic polarization tests and analyzed statistically to find main effects of inhibitor concentrations and interactions between them. As a result, hexametaphosphate was the most effective compound in reducing the corrosion rate. Sugar also reduced the corrosion rate significantly possibly because it covered the surface effectively with a high molecular weight. The inhibiting action of sugar was found to be enhanced by adding trimethylamine into the solution. Nevertheless, trimethylamine did not appear to be effective in inhibiting corrosion by itself. However, urea and sodium nitrite showed almost no inhibition on corrosion resistance of steel.

• 한국건설순환자원학회논문집
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• 제4권3호
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• pp.243-249
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• 2016

본 연구에서는 시멘트계 보수재 코팅이 철판의 부식 저항성에 미치는 영향을 평가하가 위해 보통 철판(Normal), 용접철판(Welding), 용접 후 보수재 철판(Welding & coating)의 세 가지 경우에 대하여 7일간 ICM(Impressed Current Method)를 통하여 부식을 촉진시켰다. 이후 Faraday 법칙을 통해 얻은 이론 부식률, 실험 부식률 그리고 부식 실험 후 측정한 휨 강도를 비교 평가하였다. Normal case와 Welding case에서는 약 70% 수준의 부식률이 측정되었으며, Welding & coating case에서는 약 17%정도의 부식률이 측정되었다. 이는 시멘트계 보수재료의 코팅이 염화물 이온의 침투를 효과적으로 차단하였으며 이로 인해 부식전류의 발생이 억제되었기 때문이다. 휨 강도 역시 부식률 평가와 같은 경향을 나타내었으며 Welding & coating case에서 Welding case 대비 약 3.4배 큰 강도가 평가되었다. 시멘트계 보수재 코팅이 용접부에 시행되면 용접부 철판의 부식 차단에 효과적일 것으로 판단된다.

• Steel and Composite Structures
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• 제46권3호
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• pp.385-401
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• 2023

Steel is becoming increasingly popular due to its high strength, excellent ductility, great assembly performance, and recyclability. In reality, steel structures serving for a long time in atmospheric, industrial, and marine environments inevitably suffer from corrosion, which significantly decreases the durability and the service life with the exposure time. For the mechanical properties of corroded steel, experimental studies are mainly conducted. The existing numerical analyses only evaluate the mechanical properties based on corroded morphology at the isolated time-in-point, ignoring that this morphology varies continuously with corrosion time. To solve this problem, the relationships between pit depth expectation, standard deviation, and corrosion time are initially constructed based on a large amount of wet-dry cyclic accelerated test data. Successively, based on that, an in-situ pitting evolution method for evaluating the residual tensile strength of corroded steel is proposed. To verify the method, 20 repeated simulations of mass loss rates and mechanical properties are adopted against the test results. Then, numerical analyses are conducted on 135 models of corrosion pits with different aspect ratios and uneven corrosion degree on two corroded surfaces. Results show that the power function with exponents of 1.483 and 1.091 can well describe the increase in pit depth expectation and standard deviation with corrosion time, respectively. The effect of the commonly used pit aspect ratios of 0.10-0.25 on yield strength and ultimate strength is negligible. Besides, pit number ratio α equating to 0.6 is the critical value for the strength degradation. When α is less than 0.6, the pit number increases with α, accelerating the degradation of strength. Otherwise, the strength degradation is weakened. In addition, a power function model is adopted to characterize the degradation of yield strength and ultimate strength with corrosion time, which is revised by initial steel plate thickness.

• Journal of Advanced Marine Engineering and Technology
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• 제17권3호
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• pp.42-49
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• 1993

Recently, because the lubricating oil showed a tendency to be emulsified and oxidized by high speed, high output and the extension of maintenance & conservation of marine engine, the cavitation erosion-corrosion at such an environment became a big problem on effective performance of engine. Therefore, there was a need to study the behavior and protection of erosion-corrosion damage, and then applied inhibitor to a protective method of cavitation erosion- corrosion damage. At this time, test environments were marine lubricating oil & various emulsified oil that mixed distilled water and sea water etc., and also used 20KHz, 24.mu.m piezoelectric vibrator as an experimental apparatus of cavitation erosion. With this apparatus, we investigated an influence of the emulsified oil on characteristics of erosion-corrosion and protection for erosion-corrosion by inhibitor at slide bearing metals.

• 한국해양공학회지
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• 제6권1호
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• pp.140-147
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• 1992

Corrsion fatigue test was performed under rotated bending in 3.5% NaCl aqueous solution having a temperature from 278.deg.K in order to investigate the effects of aqueous solution remperature on the corrosion fatigue fracture of raw material steel(SS41) and dual phase steel that was produced from SS41 by a series of heat treatment. Corrosion fatigue life decreases remarkably with increase in solution temperature or with decrease in stress level. The corrosion fatigue life and the crack propagation rate at 303.deg.K show the similar behaviors with those at 318.deg.K, which is assumed to be caused by concentration polarization phenamena. The number and the lengths of microcracks increase with increase in solution temperature, so they lead to the decrease in corrosion fatigue life.