• Title/Summary/Keyword: Corrosion Protection Methods

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Apparatus on Corrosion Protection and Marine Corrosion of Ship (선박의 해양 부식과 부식방지 장치)

  • Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.44 no.3
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    • pp.105-116
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    • 2011
  • Ships and offshore structures are exposed to harsh marine environments, and maintenance and repair are becoming increasingly important to the industry and the economy. The major corrosion phenomenons of metals and alloys in marine environment are pitting corrosion, stress corrosion cracking, crevice corrosion, fatigue corrosion, cavitation-erosion and etc. due to the effect of chloride ions and is quite serious. Methods of protection against corrosion can generally be divided into two groups: anodic protection and cathodic protection. Anodic protection is limited to the passivity characteristics of a material in its environment, while cathodic protection can apply methods such as sacrificial anode cathodic protection and impressed current cathodic protection. Sacrificial anode methods using Al and Zn alloys are widely used for marine structures and vessels intended for use in seawater. Impressed current cathodic protection methods are also widely used in marine environments, but tend to generate problems related to hydrogen embrittlement caused by hydrogen gas generation. Therefore, it is important to the proper maintenance and operation of the various corrosion protection systems for ship in the harsh marine environment.

An Experimental Study on the Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitor (방청제에 의한 콘크리트 내의 철근 방식법에 관한 실험적 연구)

  • 배수호;정영수;권영우;김년산;권혁진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.710-713
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    • 2000
  • The corrosion protection methods of reinforcing steel in concrete are the various methods such as increasing thickness of cover concrete, using of reinforcing bars coated with epoxy, dosage of corrosion inhibitor as concrete admixture, cathodic protection method and etc. The most economical method of them will be the corrosion protection method using corrosion inhibitor as concrete admixture. Therefore, the purpose of this research is to investigate the performance of corrosion protection of ordinary strength and high strength concrete using corrosion inhibitor, respectively. For this purpose, after manufacturing ordinary strength and high strength concrete with and without corrosion inhibitor, the accelerated corrosion tests for reinforcing steel were conducted according to the periodic cycles (140 day) of wetting ($65^{\circ}C$, 90% R.H.) and drying period ($15^{\circ}C$, 65% R.H.). As a result, th high strength concrete using corrosion inhibitor showed an excellent performance of corrosion protection.

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Effect of flow velocity on corrosion rate and corrosion protection current of marine material (해양 금속재료의 부식속도와 방식전류에 미치는 유속의 영향)

  • Lee, Seong Jong;Han, Min Su;Jang, Seok Ki;Kim, Seong Jong
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.226-231
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    • 2015
  • In spite of highly advanced paint coating techniques, corrosion damage of marine metal and alloys increase more and more due to inherent micro-cracks and porosities in coatings formed during the coating process. Furthermore, flowing seawater conditions promote the breakdown of the protective oxide of the materials introducing more oxygen into marine environments, leading to the acceleration of corrosion. Various corrosion protection methods are available to prevent steel from marine corrosion. Cathodic protection is one of the useful corrosion protection methods by which the potential of the corroded metal is intentionally lowered to an immune state having the advantage of providing additional protection barriers to steel exposed to aqueous corrosion or soil corrosion, in addition to the coating. In the present investigation, the effect of flow velocity was examined for the determination of the optimum corrosion protection current density in cathodic protection as well as the corrosion rate of the steel. It is demonstrated from the result that the material corrosion under dynamic flowing conditions seems more prone to corrosion than under static conditions.

An Experimental Study on the Corrosion Characteristics of Reinforcing Steel in Concrete by the Accelerated Corrosion Test (부식촉진시험에 의한 콘크리트 내의 철근의 부식특성에 관한 실험적 연구)

  • 배수호;정영수;김년산;권영우;권혁진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.503-507
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    • 2000
  • The corrosion protection methods of reinforcing steel in concrete are the various methods such as increasing thickness of cover concrete, using of reinforcing bars coated with epoxy, dosage of corrosion inhibitor as concrete admixture, cathodic protection method and etc. In this study, the performance of corrosion protection was investigated for the test specimens using corrosion inhibitors and cathodic protection, respectively. For this purpose, the accelerated corrosion tests for reinforcing steel were conducted according to the periodic cycles(140 days) of wetting($65^{\circ}C$, 90% R.H) and drying period($15^{\circ}C$, 65% R.H) for the test specimens. As a result, it can be concluded from the test that the effect of corrosion inhibitor was found to be variable with products, the cathodic protection method was found to be independent of salt concentration in concrete.

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Evaluation of Corrosion Protection for Epoxy and Urethane Coating by EIS under Various Cyclic Corrosion Tests

  • Hyun, Jonghun;Shon, Minyoung
    • Corrosion Science and Technology
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    • v.10 no.3
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    • pp.95-100
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    • 2011
  • Protective coatings play an important role in the protection of metallic structures against corrosive environment. The main function of anticorrosive coating is to prevent the materials from corrosive agents, such as water, oxygen and ions. In the study, the corrosion protection properties of urethane and epoxy coating systems were evaluated using EIS methods exposed to the corrosion acceleration test such as Norsok M501, Prohesion and hygrothermal cyclic test. AFM analysis of the coating systems was carried out to monitor the change of roughness of coatings. Urethane coating system was more stable than the epoxy coating under given cyclic conditions. Water uptake into the urethane coatings was less than that into the epoxy coating. The urethane coating system showed better corrosion protection than epoxy coating system based on the changes of the impedance modulus at low frequency region with exposure time. Consequently, the corrosion protection properties of the epoxy and urethane coatings was well correspond with their surface roughness changes and water uptakes.

Selection of concrete lining corrosion protection method for large sewer tunnels (하수터널의 콘크리트 라이닝 부식 방지공법 선정방법에 관한 고찰)

  • Moon, Joon-Shik;Lee, Sungjune
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.16 no.4
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    • pp.347-360
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    • 2014
  • Recently construction of large sewer tunnels used also as underground sluiceways/storages is increasing in order to prevent urban inundation, untreated sewage flow into rivers from combined sewer overflows and consequential river pollution due to climate change. Most of these large sewer tunnels are constructed with concrete and the concrete lining should be protected from corrosion caused by hydrogen sulfide($H_2S$). This paper introduced popular concrete corrosion protection methods for large sewer tunnels with 100-plus years of life cycle, and pros and cons of each corrosion protection methods were described by giving specific examples. However, it is difficult to objectively assess corrosion protection alternatives because of insufficient track record of corrosion protection methods applied to large sewer tunnels. In this paper, the evaluation process for selecting a corrosion protection alternative was introduced for large sewer tunnels using a case study.

Lifetime of Insoluble Anode for Cathodic Protection on Concrete Construction

  • Sohn, Kicheon;Chang, Hyunyoung;Kim, Youngsik
    • Corrosion Science and Technology
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    • v.4 no.2
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    • pp.56-59
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    • 2005
  • In rebar concrete structure, the corrosion of rebar can arise the deterioration of concrete structure and may affect the safety of the whole system. Recently, several methods for corrosion protection have been used and are more important for concrete structure using the sand including chloride ion. Among several protections, electrical cathodic protection has been expected to be one of the most useful methods in corrosion protection for reinforcement of concrete structures. The anode for cathodic protection needs high current density, high corrosion resistance and low overvoltage. To fill up the special qualities, the insoluble anodes were developed and these anodes were coated with metal oxide of $TiO_2$, $ZrO_2$, $RuO_2$, and $IrO_2$. Lifetime of these anodes can be one of the important factors affecting the lifetime of concrete structure in cathodic protection. In this work, several anodes were made by sol-gel method and thermal decomposition method and the lifetime of these anodes was evaluated by NACE international standard test method, TM 0294-94. Also, we did analyze the properties of coated metal oxides.

Advanced Cathodic Protection Modeling Associated with Coating Degradation Conditions

  • Im, Gwan-Jin;Kim, Ki-Joon;Lee, Myung-Hoon
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.177-183
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    • 2009
  • There are two effective methods in use to protect ship ballast tank against corrosion. One is paint coating and the other cathodic protection(CP). The conventional cathodic protection design has mainly relied on the expert's experience. During the last two decades computer modeling has been significantly developed as an advanced design technology for cathoidic protection systems not only for ships, but also for offshore structures. However the present computer modeling of cathodic protection systems have some limitations simulating corrosion in the ballast tank with a deteriorated coating. In this study, "coating breakdown factor" considering coating degradation states with time has been attempted to improve the cathodic protection modeling using the data from literatures.

Methods of Improving Operational Reliability of Oil Well Casing

  • Sergey A. Dolgikh;Irek I. Mukhamatdinov
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.1-10
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    • 2024
  • Oil well casing leak is caused by contact of casing outer surface with formation electrolyte. It is usually associated with an aquifer with a high salt content or absence of a cement ring behind the casing. The only way to reduce external casing corrosion is through cathodic protection. Through cathodic polarization of casing structure, electron content in crystal lattice and electron density will increase, leading to a potential shift towards the cathodic region. At Tatneft enterprises, cathodic protection is carried out according to cluster and individual schemes. The main criterion for cathodic protection is the size of protective current. For a casing, the protective current is considered sufficient if measurements with a two-contact probe show that the electric current directed to the casing has eliminated all anode sites. To determine the value of required protective current, all methods are considered in this work. In addition, an analysis of all methods used to determine the minimum protective current of the casing is provided. Results show that the method of measuring potential drop along casing is one of the most reliable methods for determining the value of protective current.

Investigation of Design Methodology for Impressed Current Cathodic Protection Optimum System

  • Yao, Ping;Wu, Jianhua
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.197-200
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    • 2008
  • In this paper, physical scale modeling was employed to identify the configurations of ICCP system and the electric field signatures. Computational boundary element modeling technique has been used to simulate the performance of the CP system and to predict the associated electric fields signatures. The optimization methods combined with the computer models and physical scale modeling will be presented here, which enable the optimum system design to be achieved both in terms of the location and current output of the anode but also in the location of reference electrodes for impressed current cathodic protection(ICCP) systems. The combined methodology was utilized to determine optimal placement of ICCP components (anodes and reference electrodes) and to evaluate performance of ICCP system for the 2%, 10% and 14% wetted hull coatings loss. The objective is to design the system to minimise the electric field while at the same time provide adequate protection for the ship. The results show that experimental scale modeling and computational modeling techniques can be used in concert to design an optimum ICCP system and to provide information for quickly analysis of the system and its surrounding environment.