• 제목/요약/키워드: Corrosion Properties

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고농도 염화물을 함유하는 혼합시멘트 계에서 철근부식에 따른 미세구조의 변화와 전기화학적 특성 (Microstructure modification and electrochemical properties of steel corrosion in the blended cement systems containing internal chlorides)

  • 나종윤;이승헌;김창은
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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    • pp.131-134
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    • 1999
  • Microstructure modification and electrochemical properties are investigate to estimate the effects of internal chlorides on the steel corrosion in the blended cement systems. According to the test results, slag cement system showed high chloride binding capacity and low corrosion rate. The impedance data showed three distince arcs from lowest(mHz) frequency to highest (MHz) frequency due to product layer, interfacial reaction and bulk matrix. Through the microstructural investigation, fine steel-matrix interface of slag cement system was observed but rough steel-matrix interface of OPC system was observed. Friedel's salt was thought that the substantial material contributed to the chloride binding of slag cement system.

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진공증착법으로 제조된 Zn-Cr박막의 특성에 관한 연구 (A Study on the Properties of the Zn-Cr Alloy Films by Evaporation)

  • 주봉환;이규환;권식철;백운승
    • 연구논문집
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    • 통권23호
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    • pp.109-120
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    • 1993
  • A study on corrosion and adhesion properties of evaporated Zn-Cr films were conducted on steel strip by two-source evaporater. Corrosion resistance of Zn-Cr coated steel was evaluated by salt spray test in 5% NaCl. Adhesion property of Zn-Cr films on steel substrate was evaluated by tape test after $180^\circC$ bending. Adhesion was improved with increasing the Cr content and reached the maximum at the Cr content of 6 to 8wt%. Corrosion resistance was enhanced with increasing the Cr content and improved by rolling Zn-Cr coated specimen, as a post-treatment.

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수중불분리성 콘크리트 중의 철근부식 평가 (Estimation on Corrosion of Reinforcing bar in Antiwashout Underwater Concrete)

  • 문한영;김성수;김홍삼;김종필
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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    • pp.447-450
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    • 2000
  • Recently, antiwashout underwater concrete has used for underwater structure such as high strength massive concrete structures. When, concrete is placed in seawater the quality and durability of concrete could be doubt to especcially because the amount of cement placed in the concrete can be diminished by flowing seawater. In this study, antiwashout underwater concrete mixed with mineral admixtures for improvement of properties was placed in air, water, and salt water. Half-cell potential and current density was of specimens which made under different conditions measured for estimating corrosion degree. The experimental results demostrate that corrosion resistantce in saltwater was little and mineral admixtures improved properties of concrete.

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Corrosion protection behavior of AZ31 magnesium alloy with cathodic electrophoretic coating pretreated by cerium based conversion coatings at various pH

  • Fazal, Basit Raza;Phuong, Nguyen Van;Moon, Sungmo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.268-268
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    • 2015
  • The corrosion protection behavior of AZ31 magnesium alloy (Mg alloy) with cathodic electrophoretic coating (E-coating) pretreated by cerium-based conversion coatings at various pH was investigated in this study. Cerium-based conversion coatings (CeCCs) were deposited on AZ31 Mg alloy by immersion treatment in the nitrate-based cerium salt solution. The morphology and composition of the CeCCs were analyzed using scanning electron microscopy and energy dispersive X-ray spectroscopy. The corrosion properties of the AZ31 Mg alloy pretreated with cerium coating and subsequently E-coated were studied during salt-spray testing. The surface morphologies of the E-coated Mg alloy were examined in detail after different testing times using digital photography. It was found that the protective properties of the E-coating on AZ31 Mg alloy generated are heavily dependent upon the CeCC factors such as treatment time, coating thickness and pH of the solution.

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Development of Ultra-High Strength Galvannealed Steel Sheets

  • Fujita, Nobuhiro;Matsumura, Ken-Ichiro;Nonaka, Toshiki;Tomokiyo, Toshimasa
    • Corrosion Science and Technology
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    • 제9권1호
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    • pp.16-19
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    • 2010
  • Application of ultra-high strength steel sheets is one of the most important methods to satisfy weight reduction and crash safety of a vehicle. Recently, there has been a trend to apply ultra-high strength steel sheets widely to underbody parts in which corrosion resistance is required. In this work, ultra-high strength galvannealed steel sheets with a tensile strength of 1180 MPa were developed. Newly developed ultra-high strength galvannealed steel sheets have comparable properties, such as mechanical properties, spot weldability, crashworthiness and adhesion of coatings, to conventional steel sheets.

Ag925의 전기화학적 특성에 미치는 네오디뮴 함량의 영향 (Effect of Neodymium concentration on electrochemical properties of 925 silver)

  • 신병현;정승진;정원섭
    • 한국표면공학회지
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    • 제54권2호
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    • pp.71-76
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    • 2021
  • Ag925, silver with added copper, is popular alloy due to its low price. However, it has a difficult to use because of the low corrosion resistance. In various alloys, neodymium (Nd) works as an element to improve corrosion resistance by reacting with interstitial elements in the alloy. When 1.5 wt. % Neodymium was added to Ag925, the potential on the activated polarization in a potentiodynamic polarization test was increased from -0.15 V to -0.05 V. Ag925 with added neodymium showed the passivation after activation polarization. But When the potential increased around 50 mV, the current density is increased to 3 × 10-3. Ag925 with the 1.5 wt. % Nd had the low corrosion rate.

지속 하중하에서 철근콘크리트 부재의 염화물 침투특성에 따른 철근부식에 관한 연구 (A Study on the Reinforcing Bar Corrosion Caused by Permeation of Chloride Ion Under Sustained Load)

  • 최일호;김형래;윤상천;지남용
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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    • pp.779-782
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    • 1999
  • This study was carried out to estimate the effects of the loading conditions on the corrosion of reinforcing bars and permeation of chloride ion. The permeation of chlorides depends not only on the transfer properties in concrete but also on the load applied in the case of reinforced concrete structures. Recent studies reported that the loading conditions affected the corrosion rate of the reinforcing bars under existence of an external current supply. But it was not reported that loading conditions affected corrosion of reinforcing bar caused by the characteristics of permeation and the process of cracking. In this experiment, it was shown that the corrosion of reinforcing bars and the characteristics of permeating were greatly affected by the loading conditions.

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금속의 내식성 향상을 위한 환경 친화형 무크롬 유기화합물의 표면처리 (Surface treatments of environmentally friendly Cr-free organic compounds for corrosion protection of metals)

  • 이원기;박찬영
    • 한국환경과학회지
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    • 제12권7호
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    • pp.801-807
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    • 2003
  • This work aims the search of environmentally friendly pre-treatment technologies to develop chromate replacements for metal finishing industries due to its toxicological properties. Since the corrosion resistance of steel was strongly related to water permeation, galvanized steel sheets were treated with various hydrophobic silane compounds and water-suspended polymer solution. Also, plasma gas discharge was applied to modify the surface of a polymer coated-steel sheet to be hydrophobic. The surface hydrophobicity of materials was introduced by CF$_3$H plasma exposure. The corrosion property before and after the plasma treatment was investigated in a slat spray tester with 3.5 wt.% NaCl at 35$^{\circ}C$. The results showed that both silane/polymer double coatings and plasma treatment of the galvanized steel exhibited significant retardation of corrosion.

스테인레스강의 가스질화 후 내식특성에 미치는 열처리조건의 영향 (Effects of Heat Treatment on Corrosion Resistance Properties of Gas Nitrided Stainless Steels)

  • 김한군;김용현
    • 열처리공학회지
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    • 제22권5호
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    • pp.298-306
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    • 2009
  • Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.