• Title/Summary/Keyword: Corrosion Properties

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Performance of Hot-dip Zn-6%Al-3%Mg Alloy Coated Steel Sheet as Automotive Body Material

  • Shimizu, Takeshi;Asada, Hiroshi;Morikawa, Shigeru
    • Corrosion Science and Technology
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    • v.9 no.2
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    • pp.74-80
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    • 2010
  • For the purpose of applying a hot-dip Zn-6mass%Al-3mass%Mg alloy coated steel sheet (ZAM) to automotive body materials, a laboratory study of the general properties required for inner and outer panels of automotive bodies was performed. Even with only light coating weight, ZAM showed an excellent corrosion resistance in terms of both cosmetic and perforation corrosion compared to the currently used materials for automotive bodies, GI70 and GA45. In our study, it was confirmed that ZAM exhibits as good as or better properties than GI70 in terms of spot weldability and press formability. Furthermore, since the same corrosion resistance can be achieved with less coating weight by applying ZAM, laser weldability is better than GI and GA.

Simulation of corroded RC structures using a three-dimensional irregular lattice model

  • Kim, Kunhwi;Bolander, John E.;Lim, Yun Mook
    • Structural Engineering and Mechanics
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    • v.41 no.5
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    • pp.645-662
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    • 2012
  • Deteriorative effects of steel corrosion on the structural response of reinforced concrete are simulated for varying degrees of corrosion. The simulation approach is based on a three-dimensional irregular lattice model of the bulk concrete, in which fracture is modeled using a crack band approach that conserves fracture energy. Frame elements and bond link elements represent the reinforcing steel and its interface with the concrete, respectively. Polylinear stress-slip properties of the link elements are determined, for several degrees of corrosion, through comparisons with direct pullout tests reported in the literature. The link properties are then used for the lattice modeling of reinforced concrete beams with similar degrees of corrosion of the main reinforcing steel. The model is successful in simulating several important effects of steel corrosion, including increased deflections, changes in flexural cracking behavior, and reduced yield load of the beam specimens.

Chloride Diffusion Coefficient and Steel Corrosion Properties of Concrete containing Hydrotalcite-based Corrosion Inhibitor (하이드로탈사이트계 방청제를 혼입한 콘크리트의 염화물확산계수 및 철근부식특성)

  • Kang, In-Young;Kim, Gyu-Yong;Yoon, Min-Ho;Hwang, Eui-Chul;Seo, Won-Woo;Son, Min-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.90-91
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    • 2017
  • Concrete can be used semi-permanently unless the steel is corroded. However, the concrete exposed to the marine environment is exposed to sea breeze, so chloride ions penetrate into the concrete and the steel is corroded accordingly. In order to solve these problems, there is a method of increasing the covering depth of the concrete and an application of the epoxy paint to the steel. In this study, the hydrotalcite type corrosion inhibitor was mixed with the concrete and the compressive strength, chloride diffusion coefficient and the corrosion properties of the steel were examined.

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Microstructural, mechanical, and electrochemical analysis of carbon doped AISI carbon steels

  • Muhammad Ishtiaq;Aqil Inam;Saurabh Tiwari;Jae Bok Seol
    • Applied Microscopy
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    • v.52
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    • pp.10.1-10.15
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    • 2022
  • The effect of carbon doping contents on the microstructure, hardness, and corrosion properties of heat-treated AISI steel grades of plain carbon steel was investigated in this study. Various microstructures including coarse ferrite-pearlite, fine ferrite-pearlite, martensite, and bainite were developed by different heat treatments i.e. annealing, normalizing, quenching, and austempering, respectively. The developed microstructures, micro-hardness, and corrosion properties were investigated by a light optical microscope, scanning electron microscope, electromechanical (Vickers Hardness tester), and electrochemical (Gamry Potentiostat) equipment, respectively. The highest corrosion rates were observed in bainitic microstructures (2.68-12.12 mpy), whereas the lowest were found in the fine ferritic-pearlitic microstructures (1.57-6.36 mpy). A direct correlation has been observed between carbon concentration and corrosion rate, i.e. carbon content resulted in an increase in corrosion rate (2.37 mpy for AISI 1020 to 9.67 mpy for AISI 1050 in annealed condition).

The Study on the Atmospheric Corrosion Tests of Materials in Northeast Asia (동북 아시아 지역에서의 대기중 재료부식 시험에 관한 연구)

  • 김선태;임봉빈
    • Journal of Environmental Science International
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    • v.7 no.3
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    • pp.361-368
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    • 1998
  • The structure such as building and cultural properties was composed of various materials like wood, metal and stone that have been utilized and exposed to air, wind and rain far a long time. However, because of their special characteristics as structure, collecting of samples that may involve their destruction cannot be permitted, ever for material analysis. Therefore, h order to study the Influence of atmospheric pollution on structure, atmospheric corrosion tests were achieved by making use of materials(bronze. ancient copper, copper, steel and marble) in field exposure tests. Atmospheric exposure sites are selected from places which are characterized by urban, rural, Industrial and marine enoronments In Northeast Asia. According to the results of atmospheric corrosion tests: The corrosion rates of Industrial states In china were more serious than other sampling sites. In the correlation of meteorological factors. wet hours was defiled as Intogeacted hours under that atmospheric temperature is above $0^{\circ}C$ and relative humidity in above 80% that has a great influence on corrosion tests of materials in case of a short time. The relative humidity was above about 75% that resulted in great increase of corrosion rates. In the esimation of corrosion rates between materials, corrosion rates of steel was about thirty times and decuple larger than that of other materials excluding marble in unshelterd exposure and In sheltered exposure.

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Effect of Heat Treatment on the Microstructures and Properties of HVOF Sprayed Ni-Cr-W-Mo-B Alloy Coatings (초고속화염용사법으로 제조된 Ni-Cr-W-Mo-B 합금 코팅의 미세조직과 특성에 미치는 열처리 효과)

  • 민경오;이창희
    • Journal of Welding and Joining
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    • v.18 no.6
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    • pp.48-54
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    • 2000
  • The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

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Enhanced Corrosion Protection Performance by Novel Inhibitor-Loaded Hybrid Sol-Gel Coatings on Mild Steel in 3.5% NaCl Medium

  • Suleiman, Rami K.
    • Corrosion Science and Technology
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    • v.18 no.5
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    • pp.168-174
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    • 2019
  • The sol-gel methodology has been applied successfully in the synthesis of a novel hybrid coating based on dimethoxymethyl-n-octadecylsilane precursor. The newly synthesized parent coating was functionalized further with two commercially-available corrosion-inhibitive pigments Moly-$white^{(R)}$ 101-ED and Hfucophos $Zapp^{(R)}$, applied to mild steel panels, and immersed continuously in 3.5% NaCl electrolytic solution for 288 h. The corrosion protection performance of the prepared functional coatings was evaluated using electrochemical impedance spectroscopy (EIS) and DC polarization techniques. An enhancement in the barrier properties has been revealed from the electrochemical characterization data of the hybrid films, in comparison with untreated mild steel substrates following long-term immersion in 3.5% NaCl. The corrosion resistance properties of the newly developed coatings over mild steel substrates found to be largely dependent on the type of the loaded inhibitive pigment in which the Moly-white inhibitor has a positive impact on the corrosion protection performance of the parent coating, while an opposite behavior was observed upon mixing the base polymeric matrix with the commercially-available Zapp corrosion inhibitor.

A Study on the Development of Corrosion Prediction System of RC Structures due to the Chloride Contamination (염해를 받는 철근콘크리트 구조물의 철근부식시기 예측시스템 개발에 관한 연구)

  • Kim, Do-Gyeum;Park, Seung-Bum
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.4 no.1
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    • pp.121-129
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    • 2000
  • In general. service life of the sea-shore concrete structures is largely influenced by the corrosion of reinforcing steel due to the chloride contamination, and the penetration of chloride ions into concrete is governed by concrete condition state as a micro-structure. In this study, characteristics of chloride diffusion in concrete are analyzed in accordance with the mixing properties and durability of concrete, by considering the facts that micro-structure of concrete varies with the mixing properties and can indirectly be analyzed by using the durability test. In order to predict the service life of existing concrete structures, chloride diffusion equation for the concrete structures under various service conditions and the major parameters used in that equation are formulated as the mathematical models. Based on the results of chloride diffusion analysis in accordance with the mixing properties and durability of concrete and mathematical models formulated in this study, a prediction system is developed to predict the corrosion initiation of reinforcing steel in the sea-shore concrete structures.

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Nonlinear Analysis of RC Beams Damaged by Corrosion of Tension Main Rebar (인장 주근이 부식된 RC보의 비선형 해석)

  • Shin, Sung-Woo;Lee, Han-Seung;Yoo, Suk-Hyeong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.191-198
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    • 2005
  • This study was carried out to investigate quantitatively the relationship between the degree of rebar corrosion and the strength of reinforced concrete beams. After producing equations for the relationship between both the tensile properties of rebars and bond properties and the corrosion percentage of rebars, finite element analysis and bending tests were conducted for RC beams damaged by corrosion of tension main rebar. As a result, it was made that the strength of RC beams damaged by corrosion could be practically simulated by FEM analysis using experimentally determined material properties representing the bond and the mechanical characteristics of corroded rebars.

Effect of Si on the Corrosion Properties of Mg-Li-Al Light Alloy (경량화 Mg-Li-Al합금의 내식성에 미치는 Si의 영향)

  • 김순호
    • Resources Recycling
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    • v.7 no.5
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    • pp.52-57
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    • 1998
  • Effect of Si in the electrochemical corrosion characteristics of Mg-Li-Al light alloy has been investigated by means of potentiodynamic polarization study. The elecrochemical behaviors were evaluated in 003% NaCl solution and the solution buffered with KH$_{2}PO_{5}{\cdot}$NaOH at room temperature. It was found that the addition of very small quantity of Si (0.48 wt%) in Mg-Li-Al light alloy increased corrosion rates and amount of corrosion products and decreated the pitting resistance of the alloy. From the results it was concluded that Si which is added to increase the strength of Mg-Li-Al alloy is harmful to corrosion properties of the alloy.

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