• 제목/요약/키워드: Corrosion Product

검색결과 216건 처리시간 0.029초

오스템퍼링 한 저합금구상흑연주철의 부식마멸특성 및 그 기구에 관한 연구 (A Study on Corrosive Wear Characteristics and the Mechanism of Austempered Low-Alloy Ductile Iron)

  • 박흥식;진동규
    • 대한기계학회논문집
    • /
    • 제17권6호
    • /
    • pp.1404-1411
    • /
    • 1993
  • 본 연구는 오스템퍼링 온도와 유지시간을 변화시켜 오스템퍼링 한 저합금구 상흑연주철을 실험재로 하여 증류수 및 NaCI수용액 중에서의 부식마멸특성 및 그 기구 를 규명하여 Tribology 설계에 대한 자료를 제시하는 것을 목적으로 하였다.

전자 기기의 유해 전자파 차폐를 위한 친환경 제품 디자인 활용도 분석 (Synthesis of Application on the Product Design for the Shielding of the Electromagnetic wave in the Electrical Appliances)

  • 성낙봉
    • 한국콘텐츠학회논문지
    • /
    • 제11권9호
    • /
    • pp.129-136
    • /
    • 2011
  • 본 논문에서는 생활가전기기와 정보통신가전기기의 다양한 외형디자인에 응용할 수 있는 옻과 숯을 이용한 친환경 소재의 전자파 차폐 물질을 제시하였다. 제시된 전자파 차폐 물질은 전자레인지에서 사용되는 2.45 GHz에서는 약 96.3%, 이동전화의 사용 주파수 900 MHz, 1.8 GHz에서 각각 97.2%, 98.7%의 전자파를 차폐하였다. 기존에는 전자레인지와 이동전화에서는 방출되는 강한 전자파를 차단하기 위해 금속 재질이나 플라스틱 표면에 도전성 재료를 피복하는 방법이 이용되고 있으나, 친환경 소재인 옻과 숯을 활용함으로써 금속 재질을 탈피하여 제품의 경량화, 내열성, 내마모성, 내식성을 이룰 수 있는 한편, 부드럽고 친근한 이미지의 제품디자인이 가능하다.

연주롤용 육성용접 재료의 고온마모 및 부식특성에 미치는 Nb, V의 영향 (The Effects of Nb, V on the High Temperature Wear and Corrosion of the Overlaying Materials for Continuous Casting Rolls)

  • 김창규;황동수;윤재홍;강창룡;곽희환
    • 동력기계공학회지
    • /
    • 제8권3호
    • /
    • pp.30-35
    • /
    • 2004
  • In the steel making industries, the continuous casting process has been applied to the number of company because of its economical benefit. Casting rolls are utilized for frictional drive and transport of solidifying slap. Dimensional tolerances, mechanical stability and surface condition of the cast roll can affect both the surface and internal quality of the product being cast. To overcome these problems, the industry is accelerating on the rate of technology improvements. Samples were overlaid on the S45C steel by submerged arc welding process. And the hardness, wear, electrochemical corrosion and oxidation tests were carried out. Test results were that all these materials were satisfying basic requirements of caster rolls. By these results, the addition of 0.1%Nb and 0.15%V increase mechanical properties and tempering resistance by its superior carbide forming characteristics in low carbon $12{\sim}13%Cr$ martensitic stainless steels.

  • PDF

정수처리에서 pH 저감에 의한 응집효율향상에 관한 연구 (Improving Coagulation Performance with pH Preadjustment in Drinking Water Treatment)

  • 이환;이철효;정창규;이윤진
    • 한국환경보건학회지
    • /
    • 제29권2호
    • /
    • pp.1-6
    • /
    • 2003
  • This paper reports on a pilot scale comparison of PACS coagulation with and without pH preadjustment. The pH of the water was adjusted with carbon dioxide and sulfuric acid. Process performance was assessed on the basis of total organic carbon(TOC), UV absorbance, turbidity and disinfection by-product(DBP) precursors. Coagulation pH appeared to be a determining factor for maximum NOM removal. The optimum coagulation pH in order to decrease TOC and turbidity were pH 7. Preadjustment of pH 7 increased TOC removal to as much as 43, 47 percent with sulfuric acid and carbon dioxide. Moreover, coagulation at pH 7 caused a reduction in UV$_{254}$, THMFP and HAAFP compared to the baseline coagulation. For preadjustment of pH 7 with carbon dioxide, the percentage of TOC, UV$_{254}$, THMFP and HAAFP shows the reduction rate of 3.8, 0.5, 4.8, 9.4% comparing to the coagulation rendition using sulfuric acid. Acid addition to depress pH during coagulation decrease Langelier Saturation Index(LSI), potentially causing increase corrosion in water distribution systems. LSI for carbon dioxide and sulfuric acid at pH 6 was -2.3, -3.3. Therefore, carbon dioxide was more effective at controlling corrosion than sulfuric acid.

파일럿 규모에서 철-니켈 합금 에칭폐액 재생 (Recovery of Iron-Nickel Alloy Etching Waste Solution in Pilot Scale)

  • 채병만;김대원;황성옥;김득현;이상우
    • 청정기술
    • /
    • 제23권4호
    • /
    • pp.393-400
    • /
    • 2017
  • 본 연구에서는 염화제이철의 재생공정으로 기존 용매추출법에서 사용하고 있는 용매인 TBP 및 Alamine336 대신에 새로운 용매를 통해 용액 내에 존재하는 Ni과 Fe를 분리 및 회수하는 공정을 개발하였다. Lab 실험을 통하여 실험조건을 최적화하였으며, 이를 바탕으로 상업화를 위한 $10L\;h^{-1}$급 파일럿 설비를 구축하였다. 또한 파일럿 실험을 통하여 양산을 위한 공정 데이터를 확보하였으며, 제조된 염화제이철의 부식실험을 통하여 사용할 수 있는 제품 품질에 문제없음을 확인하였다.

Influence of Selective Oxidation Phenomena in CGLs on Galvanized Coating Defects Formation

  • Gong, Y.F.;Birosca, S.;Kim, Han S.;De Cooman, B.C.
    • Corrosion Science and Technology
    • /
    • 제7권1호
    • /
    • pp.1-5
    • /
    • 2008
  • The gas atmosphere in continuous annealing and galvanizing lines alters both composition and microstructure of the surface and sub-surface of sheet steel. The formation and morphology of the oxides of alloying elements in High Strength Interstitial Free (HS-IF), Dual Phase (DP) and Transformation-Induced Plasticity (TRIP) steels are strongly influenced by the furnace dew point, and the presence of specific oxide may result in surface defects and bare areas on galvanized sheet products. The present contribution reviews the progress made recently in understanding the selective formation of surface and subsurface oxides during annealing in hot dip galvanizing and conventional continuous annealing lines. It is believed that the surface and sub-surface composition and microstructure have a pronounced influence on galvanized sheet product surface quality. In the present study, it is shown that the understanding of the relevant phenomena requires a combination of precise laboratory-scale simulations of the relevant technological processes and the use of advanced surface analytical tools.

Ignition and flame propagation in hydrogen-air layers from a geological nuclear waste repository: A preliminary study

  • Ryu, Je Ir;Woo, Seung Min;Lee, Manseok;Yoon, Hyun Chul
    • Nuclear Engineering and Technology
    • /
    • 제54권1호
    • /
    • pp.130-137
    • /
    • 2022
  • In the geological repository of radioactive nuclear waste, anaerobic corrosion can generate hydrogen, and may conservatively lead to the production of hydrogen-air layer. The accumulated hydrogen may cause a hazardous flame propagation resulting from any potential ignition sources. This study numerically investigates the processes of ignition and flame propagation in the layered mixture. Simple geometry was chosen to represent the geological repository, and reactive flow simulations were performed with different ignition power, energy, and locations. The simulation results revealed the effects of power and energy of ignition source, which were also analyzed theoretically. The mechanism of layered flame propagation was suggested, which includes three stages: propagation into the hydrogen area, downward propagation due to the product gas, and horizontal propagation along the top wall. To investigate the effect of the ignition source location, simulations with eight different positions were performed, and the boundary of hazardous ignition area was identified. The simulation results were also explained through scaling analysis. This study evaluates the potential risk of the accumulated hydrogen in geological repository, and illustrates the layered flame propagation in related ignition scenarios.

ECR-MOCVD를 이용하여 연료 전지 분리판에 코팅된 FTO막의 특성 연구 (Characteristics of Fluorine-Doped Tin Oxide Film Coated on SUS 316 Bipolar Plates for PEMFCs)

  • 박지훈;;전법주;변동진;이중기
    • 한국수소및신에너지학회논문집
    • /
    • 제22권3호
    • /
    • pp.283-291
    • /
    • 2011
  • Polymer electrolyte membrane fuel cells (PEMFCs) use the bipolar plate of various materials between electrolyte and contact electrode for the stable hydrogen ion exchange activation. The bipolar plate of various materials has representatively graphite and stainless steel. Specially, stainless steels have advantage for low cost and high product rate. In this study, SUS 316 was effectively coated with 600 nm thick F-doped tin oxide (SnOx:F) by electron cyclotron resonance-metal organic chemical vapor deposition and investigated in simulated fuel cell bipolar plates. The results showed that an F-doped tin oxide (SnOx:F) coating enhanced the corrosion resistance of the alloys in fuel cell bipolar plates, though the substrate steel has a significant influence on the behavior of the coating. Coating SUS 316 for fuel cell bipolar plates steel further improved the already excellent corrosion resistance of this material. After coating, the increased ICR values of the coated steels compared to those of the fresh steels. The SnOx:F coating seems to add an additional resistance to the native air-formed film on these stainless steels.

폐분철을 이용한 고중량 밸러스트 콘크리트 제조 및 시공성에 관한 연구 (A Study on Constructibility of heavyweight ballast concrete with recycled iron slag)

  • 박대오;박영신;박재명
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
    • /
    • pp.785-788
    • /
    • 2008
  • 선박의 안전성을 유지하기 위하여 사용하는 밸러스트는 그 용적에 의해 적재 능력이 감소되는 문제점을 가지고 있다. 이를 해결하기 위해 선박의 밸러스트에 고중량 콘크리트를 적용하여 연구를 진행하였다. 고중량 콘크리트 제조에는 자철광, 갈철광 등 밀도가 큰 골재를 사용하는 것이 일반적이나 이러한 골재는 수급이 어렵고 고가인 단점을 가지고 있다. 이에 본 연구에서는 고중량이며 수급이 용이한 폐분철을 이용하여 고중량 밸러스트 콘크리트의 품질특성 및 주의사항을 검토하여 현장적용 타당성을 검증하고자 하였다. 고중량 밸러스트 콘크리트는 현장 특성상 압축강도의 요구치는 없으나, 밸러스트 탱크의 밀실한 채움을 위해 고유동 및 2700kg/m$^3$이상의 단위용적질량이 요구된다. 예비 실험을 통해 설계된 현장배합의 온도균열지수는 균열을 제한할 수 있는 수준으로 나타났으며, 복합부식실험 결과 염화물에 대한 저항성 측면에서 우수한 성능을 보였다. 이러한 결과로 폐분철을 이용한 고중량 콘크리트를 밸러스트의 제조 및 시공이 가능한 것으로 나타났으며, 적재 능력이 증가함으로 선박운송에 큰 도움이 될 것으로 판단된다.

  • PDF

Characteristics Comparison of Anodic Films Formed on Mg-Al Alloys by Non-chromate Surface Treatment

  • Kim, Seong-Jong;Jang, Seok-Ki;Kim, Jeong-Il
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제28권2호
    • /
    • pp.300-308
    • /
    • 2004
  • The formation mechanism of anodic oxide films on Mg alloys when anodized in NaOH solution. was investigated by focusing on the effects of anodizing potential. Al content. and anodizing time. Pure Mg and Mg-Al alloys were anodized for 10 min at various potentials in NaOH solutions. $Mg(OH)_2$ was generated by an active dissolution reaction at the surface. and the product was affected by temperature. The intensity ratio of $Mg(OH)_2$ in the XRD analysis decreased with increasing applied potential. while that of MgO increased. The anti-corrosion properties of anodized specimens at each constant potential were better than those of non-anodized specimens. The specimen anodized at an applied potential of 3 V had the best anti-corrosion property. And the intensity ratio of $Mg_{17}Al_{12}$/Mg increased with aluminum content in Mg-Al alloys. During anodizing. the active dissolution reaction occurred preferentially in ${\beta}\;phase(Mg_{17}Al_{12})$ until about 4 mins. and then the current density increased radually until 7 mins. The dissolution reaction progressed in a phase(Mg) which not formed the intermetallic compound. which had a lower Al content. In the anodic polarization test of $0.017\;mol{\cdot}dm^-3$ NaCl and $0.1\;mol{\cdot}dm^-3\;Na_2SO_4$ at 298 K. the current density of Mg-15 mass% Al alloy anodized for 10 mins increased. since the anodic film that forms on the a phase is a non-compacted film. The anodic film on the phase for 30 mins was a compact film as compared with that for 10 mins.