• Title/Summary/Keyword: Corrosion Measurement

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An Electrochemical Evaluation on the Corrosion Resistance of Heavy Anticorrosive Paint (중방식도료의 내식성에 관한 전기화학적 평가)

  • Sung Ho-Jin;Kim Jin-Kyung;Lee Myung-Hoon;Kim Ki-Joon;Moon Kyung-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.5
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    • pp.519-525
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    • 2005
  • An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint(DFT:25um) was carried out for 5 kinds of heavy anticorrosive paints such as high solid epoxy(HE), solvent free epoxy(SE). tar epoxy(TE), phenol epoxy(PE). and ceramic epoxy(CE). Corrosion current densities obtained by Tafel extrapolation method from anodic and cathodic polarization curves didn't correspond with the values obtained by AC impedance measurement, however, the values of polarization resistance obtained from the cyclic voltammogram showed a good tendency corresponding well with the values of AC impedance measurement. Futhermore there was a good correlation against the corrosion resistance evaluation between passivity current density of the anodic polarization curve and diffusion limiting current density of the cathodic polarization curve. And corrosion resistance increased with corrosion potential shifting to noble direction. From the results discussed above. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paints.

Study on Localized Corrosion Cracking of Alloy 600 using EN-DCPD Technique (EN-DCPD 방법을 이용한 Alloy 600 재료의 국부부식균열 연구)

  • Lee, Yeon-Ju;Kim, Sung-Woo;Kim, Hong-Pyo;Hwang, Seong-Sik
    • Corrosion Science and Technology
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    • v.12 no.2
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    • pp.93-101
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    • 2013
  • The object of this work is to establish an electrochemical noise(EN) measurement technique combined with a direct current potential drop(DCPD) method for monitoring of localized corrosion cracking of nickel-based alloy, and to analyze its mechanism. The electrochemical current and potential noises were measured under various conditions of applied stress to a compact tension specimen in a simulated primary water chemistry of a pressurized water reactor. The amplitude and frequency of the EN signals were evaluated in both time and frequency domains based on a shot noise theory, and then quantitatively analyzed using statistical Weibull distribution function. From the spectral analysis, the effect of the current application in DCPD was found to be effectively excluded from the EN signals generated from the localized corrosion cracking. With the aid of a microstructural analysis, the relationship between EN signals and the localized corrosion cracking mechanism was investigated by comparing the shape parameter of Weibull distribution of a mean time-to-failure.

Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System (희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동)

  • Ha, Ji-Myung;Jin, Chung-Kuk;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.

Reliability Analysis Method for Repeated UT Measurement Data in Nuclear Power Plants (원전 배관의 반복 측정 데이터에 대한 신뢰도 분석 방법)

  • Yun, Hun;Hwang, Kyeong-Mo
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.142-148
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    • 2013
  • Safety is a major concern in Nuclear Power Plants (NPPs). Piping systems in NPPs are very complex and composed of many components such as tees, elbows, expanders and straight pipes. The high pressure and high temperature water flows inside piping components. As high speed water flows inside piping, the pipe wall thinning occurs in various reasons such as FAC (Flow Accelerated Corrosion), LDIE (Liquid Droplet Impingement Erosion) and Flashing. To inspect the wall thinning phenomenon and protect the piping from damages, piping components are checked by UT measurement in every overhaul. During every overhaul, approximately 200~300 components (40,000~60,000 UT data) are examined in NPPs. There are some methods from EPRI for evaluating wear rate of components. However, only few studies have been conducted to find out the raw data reliability for the wear rate evaluation. Securing the reliable raw data is the key factor for a reasonable evaluation. This paper suggests the reliability analysis method for the repeatedly measured data for wear rate evaluation.

Consideration on the Risk of Corrosion Assessment in Reinforced Concrete Structure by Corrosion Potential Criterion (부식전위 기준에 의한 철근콘크리트 구조물의 부식진단의 위험성에 관한 고찰)

  • Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.147-152
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    • 2015
  • Corrosion of steel reinforcement is a major factor in the deterioration of harbour and bridge structure. Steel corrosion in concrete must be checked for assessing the condition of a reinforced concrete structure. There are several ways how to measure the corrosion condition of reinforced concrete, but the corrosion potential measurement is a very simple, rapid, cost-effective and non-destructive technique to evaluate the severity of corrosion in reinforced concrete structure, therefore commonly used by engineers. However some particular situations may not relate to the reinforcement corrosion probability and a simple comparison of the corrosion potential data with the ASTM C876 Standard on steel reinforcement corrosion probability could be meaningless and not give reliable informations because of environment factors as oxygen concentration, chloride content, concrete resistance. Therefore this paper explains the risk of corrosion assessment in reinforced concrete structure and how many factors can affect the reliability of the corrosion potential data.

Effect of Pretreatments on Graphene Coated Bipolar Plate of PEMFC on Electrochemical (전처리가 그래핀을 코팅한 고체고분자 연료전지 분리판의 전기화학적 특성에 미치는 영향)

  • Cha, Seong-Yun;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.13 no.6
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    • pp.224-232
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    • 2014
  • Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC) was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL) was measured. The value of ICR decreased with an increase in compaction stress($20N/cm^2{\sim}220N/cm^2$). ICR of graphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurement results showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare 316L stainless steel. $H_2SO_4$ acid pretreatment was the most effective among various pretreatments. The lowest ICR and the corrosion current density were obtained when using $H_2SO_4$ solution pretreatment.

A Study of Non-destructive Measurement on the Reinforced Concrete Structure Damaged by Reinforcing Steel Corrosion (철근콘크리트구조물의 철근부식에 대한 비파괴 측정과 부식에 따른 균열거동)

  • 김성운;정한중;김창환;임선택
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.10a
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    • pp.80-85
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    • 1991
  • This experimental study was performed to derive the relationship between the measured values(corrosion potential) and the actual amount of corrosion products(reinforcing steel weight loss rate). Also the growth of crack due to the steel corrosion was oberved. First, the reinforcing steel of R/C specimen was corroded with chloride penetration and accelerated galvanostatic corrosion method. And then, the corrosion potential of reinforcing steel was measured with nondestructive tester.

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IBEM analyses on half-cell potential measurement for NDE of rebar corrosion

  • Kyung, Je-Woon;Tae, Sung-Ho;Lee, Han-Seung;Alver, Yalcin;Yoo, Jo-Hyeong
    • Computers and Concrete
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    • v.4 no.4
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    • pp.285-298
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    • 2007
  • Corrosion of Reinforcement (rebar) is nondestructively estimated by the half-cell potential measurement. As is the case with other nondestructive testings (NDT), understanding of the underlying principles should be clarified in order to obtain meaningful results. Therefore, the measurement of potentials in concrete is analytically investigated. The effect of internal defects on the potentials measured is clarified numerically by the boundary element method (BEM). Thus, a simplified inversion by BEM is applied to convert the potentials on concrete surface to those on rebars, taking into account the concrete resistivity. Because the potentials measured on concrete surface are so sensitive to moisture content, concrete resistivity and surface condition, an inverse procedure to convert the potentials on concrete surface into those on rebars is developed on the basis of BEM. It is found that ASTM criterion is practically applicable to estimate corrosion from the potential values converted. In experiments, an applicability of the procedure is examined by accelerated corrosion tests of reinforced concrete (RC) slabs. For practical use, the procedure is developed where results of IBEM are visualized by VRML (Virtual Reality modeling Language) in three-dimensional space.

Laser based impedance measurement for pipe corrosion and bolt-loosening detection

  • Yang, Jinyeol;Liu, Peipei;Yang, Suyoung;Lee, Hyeonseok;Sohn, Hoon
    • Smart Structures and Systems
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    • v.15 no.1
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    • pp.41-55
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    • 2015
  • This study proposes a laser based impedance measurement system and impedance based pipe corrosion and bolt-loosening monitoring techniques under temperature variations. For impedance measurement, the laser based impedance measurement system is optimized and adopted in this paper. First, a modulated laser beam is radiated to a photodiode, converting the laser beam into an electric signal. Then, the electric signal is applied to a MFC transducer attached on a target structure for ultrasonic excitation. The corresponding impedance signals are measured, re-converted into a laser beam, and radiated back to the other photodiode located in a data interrogator. The transmitted impedance signals are treated with an outlier analysis using generalized extreme value (GEV) statistics to reliably signal off structural damage. Validation of the proposed technique is carried out to detect corrosion and bolt-loosening in lab-scale carbon steel elbow pipes under varying temperatures. It has been demonstrated that the proposed technique has a potential to be used for structural health monitoring (SHM) of pipe structures.