• Title/Summary/Keyword: Corrosion Level

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베릴륨함유 치과 주조용 비귀금속 합금의 젖산용액에 의한 금속 노출수준 평가 (Evaluation of a metal level in non-precious metal alloys dental casting having beryllium by lactic acid Solution)

  • 박수철;장은진;한석윤
    • 대한치과기공학회지
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    • 제33권2호
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    • pp.121-128
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    • 2011
  • Purpose: The purpose of this study is to investigate the level of each metal in non-precious metal alloys dental casting, still used even banned for use and trade by the law, for oral health. Methods: Two kinds of metal alloys were analyzed. One was Ticonium 100 for removable prosthesis and the other was Rexillium V for dental porcelain. Two samples of each metal alloy were made in 0.5g, 1.0g, and 1.5g. Total number of samples were 12. Two kinds of lactic acid Solution, pH7 and pH4.6, were injected into each samples. After injection, each samples had been for 21days ${\pm}$ 1 hour in the water tank of which temperature was $37^{\circ}C$. The level of metal was measured in each sample by inductively couplled plasma-atomic emission spectrometer. Results: In both metal alloys, metals, chrome, nickel, beryllium, and molybdenum, were founded. In Ticonium 1000, the highest level of nickel was 2.531ppm in 1.5g pH4.6 sample while the highest level of nickel was 4.062ppm in 1.5g pH4.6 sample of Rexillium V. In chemical composition of these methal alloys, chrome(14~17%) was much more than beryllium(1.95~1.99%) and molybdenum(5.0~9.0%) but berllium and molybdenum were founded more than chrome in samples. Therefore, chrome showed better anti-corrosion than other metal alloys. In both metal alloys, more metals were founded in higher pH level and more mass. Levels of chrome was significantly different in samples of both metal alloys in each pH level(p<0.05). Levels of nickels was significantly different in samples of both metal alloys in each pH level(p<0.05). Conclusion: For oral health, further studies are needed in nickel-chrome metal alloy and cobalt metal alloy of non-beryllium in addittion to beryllium metal alloy and also long-term studies needed in various period and other non-percious metal alloys for dental casting.

화강암지역에 고준위 원자력 폐기물 처리에 대한 안정성 평가 (Evaluation of the Safty for the Disposal of High-level Nuclear Waste in the Granite)

  • 오창환
    • 자원환경지질
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    • 제29권2호
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    • pp.215-225
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    • 1996
  • All the radionuclides in high-level nuclear waste will decay to harmless levels eventually but for some radionuclides decay is so slow that their radiation remains dangerous for times on the order of tens or hundreds of thousands of years. At the present time, the most favorite disposal plan for high-level radioactive waste is a mined geological disposal in which canister enclosing stable solid form of radioactive waste is placed in mined cavities locating hundred meters below the surface. The chief hazard in such disposal is dissolution of radionuclides from the waste in the groundwater that will eventually carry the dissolved radionuclides to surface environments. The hazard from possible escape of the radionuclides through groundwater can be delayed by engineered and geologic barriers. The engineered barriers can become useless by unexpected geologic catastrophe such as volcanism, earthquake, and tectonic movement and by fraudulent work such as careless construction, improperly welded canisters within the first few decades or centuries. As a result, dangerously radioactive waste which is still intensively radioactive is directly exposed to attack by moving groundwater. All the more, it is almost impossible to control repositories for times more than 10,000 years. Therefore, naturally controlled geologic, barriers whose properties will not be changed within 10,000 years are important to guarantee the safety of repositories of high-level radioactive waste. In Sweden and France, the suitability of granite for the mined geological disposal of high-level waste has been studied intensively. According to the research in Sweden and France, granites has the following physio-chemical characteristics which can delay the transportation of radionuclide by groundwater. First, the permeabilities of granites decreases as the depth increases and is $10^{-8}{\sim}10^{-12}m/s$ at depth below 300 m. Second, groundwater at depth below 300 m has pH=7-9 and reducing condition (Eh=-0.1~0.4). This geochemical condition is desirable to prevent both canister and solid waste from corrosion. Third most radionuclides are not transported by low solubilities and some radionuclide with high solubility such as Cs and Sr are retarded by absorption of geologic media through which ground water flows. Therefore, if high-level waste is disposed at depth below 300 m in the granite body which has a low permeability and is geologically stable more than 10,000 years, the safety of repositories from the hazard due to radionuclide escape can guaranteed for more than 10,000 years.

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IGCC 합성가스 냉각기 GRC의 열유동 및 입자거동 특성에 대한 전산해석 연구 (Numerical Simulations on the Thermal Flow and Particle Behaviors in the Gas Reversal Chamber of a Syngas Cooler for IGCC)

  • 박상빈;예인수;류창국;김봉근
    • 한국연소학회지
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    • 제18권1호
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    • pp.21-26
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    • 2013
  • In the Shell coal gasification process, the syngas produced in a gasifier passes through a syngas cooler for steam production and temperature control for gas cleaning. Fly slag present in the syngas may cause major operational problems such as erosion, slagging, and corrosion, especially in the upper part of the syngas cooler (gas reversal chamber, GRC). This study investigates the flow, heat transfer and particle behaviors in the GRC for a 300 MWe IGCC process using computational fluid dynamics. Three operational loads of 100%, 75% and 50% were considered. The gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. The heat transfer to the wall was mainly by convection which was larger on the side wall at the inlet level due to the expansion of the cross-section. In the evaporator below the GRC, the particles were concentrated more on the outer channels, which needs to be considered for alleviation of fouling and blockage.

광섬유 FBG센서를 이용한 원주형 구조물의 2차원 상대변위 모니터링기법 개발 (Development of a Convergence Monitoring Method for Cylindrical Structures by Optical Fiber Bragg Grating Sensor)

  • 노병철;김종우;강석화
    • 한국구조물진단유지관리공학회 논문집
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    • 제10권4호
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    • pp.160-166
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    • 2006
  • 본 연구에서는 광섬유 FBG 센서를 이용, 곡률반경을 고려한 이 방향 변위(Two-Way Displacement)를 측정하여 변형각을 환산함으로써 상대좌표를 구하는 알고리즘을 정립하였으며 이를 이용하면 작은 변형에 대해서도 매우정확하게 상대변위를 구할 수 있음을 알 수 있었다. 이를 확인하기 위해 4.5m높이의 H형강에 고안된 이 방향 광섬유센서를 부착하여 횡 방향으로 외력을 가해서 발생한 변위를 수준측량과 일반적인 전자식 변위계로 동시에 측정하여 각각의 측정성능을 비교분석하였다. 그 결과, 광섬유센서의 분해능은 다른 센서시스템에 비해 월등하였으며 이차원 상대좌표의 측정이 가능함을 확인하였다.

신뢰성 기반 강건 최적화를 이용한 자동채염기의 확률론적 구조설계 (Probabilistic Structure Design of Automatic Salt Collector Using Reliability Based Robust Optimization)

  • 송창용
    • 한국산업융합학회 논문집
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    • 제23권5호
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    • pp.799-807
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    • 2020
  • This paper deals with identification of probabilistic design using reliability based robust optimization in structure design of automatic salt collector. The thickness sizing variables of main structure member in the automatic salt collector were considered the random design variables including the uncertainty of corrosion that would be an inevitable hazardousness in the saltern work environment. The probabilistic constraint functions were selected from the strength performances of the automatic salt collector. The reliability based robust optimum design problem was formulated such that the random design variables were determined by minimizing the weight of the automatic salt collector subject to the probabilistic strength performance constraints evaluating from reliability analysis. Mean value reliability method and adaptive importance sampling method were applied to the reliability evaluation in the reliability based robust optimization. The three sigma level quality was considered robustness in side constraints. The probabilistic optimum design results according to the reliability analysis methods were compared to deterministic optimum design results. The reliability based robust optimization using the mean value reliability method showed the most rational results for the probabilistic optimum structure design of the automatic salt collector.

수돗물의 앙금발생규명 및 저감기술방안 (Study on the alternatives to trace the origin and to diminish the sediments of drinking water)

  • 김갑수;임병진;권은미
    • 환경위생공학
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    • 제9권1호
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    • pp.17-28
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    • 1994
  • There are many possibilities that may lead to low quality of drinking water Recently, some unknown deposits in tap water raised a lot of public concern regarding the safety of drinking water in Seoul. We analyzed the quality of tap water from several areas of Seoul, including the area where public complaints about tap water were high. The results shows that the quality of tap water in Seoul was good, well below the environmental standards. Only the tap water from the area with high public complaints showed turbidity higher than that of other area. Also, result shows that component of deposit in tap water was Al, Fe, Mn, and Zn. Based on the research result we propose several measures that might help to reduce the amount of deposit in tap water as follows : 1 Using coagulant aid when coagulating or adjusting pH when filtering. 2. Replacing old water pipeline with new corrosive- resistant one. 3. Increasing water treatment efficiency by enhancing water treatment system such as automation of water treatment system adjusting production capacity, and improving operational condition of filler basin. 4. Chlorine disinfection at the distribution reservoir would help maintaining the same pH level and chlorine concentration throughout the water pipeline and reduce corrosion of pipe.

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7175Al 대형 단조재의 미세조직과 파괴인성 (Microstructure and Fracture Toughness of 7175Al Heavy Forgings)

  • 이오연;장성환
    • 열처리공학회지
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    • 제14권2호
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    • pp.89-95
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    • 2001
  • The 7175Al alloy is particularly interesting for its high strength and sufficient ductility, fracture toughness and corrosion resistance. Currently vigorous efforts have been made to develop large rockets usable for various purposes in the space. This has created the demand of big size of 7175Al billet which would be applied to heavy forgings. The aim of this study is to investigate the quality level of big billet and the effect of billet size on the mechanical properties of large 7175Al ring roll forgings. The billets range from 370 mm to 720 mm in diameter were homogenized and forged after direct chill casting. The size and volume fraction of second phase particles In ${\Phi}720$ mm billet are larger than those of ${\Phi}370$ mm billet, and its ductility is lower for the condition of homogenization and T6 treatment. The Cu-rich phases formed in interdendritic sites are considered to provide the preferential crack path during cold upsetting. The fracture toughness of ring roll forgings which are made by ${\Phi}370$ mm billet is higher than those of ${\Phi}720$ mm billet.

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FRC를 적용한 FRP-콘크리트 합성보의 거동특성 (Behavior Characteristics of FRP-Concrete Composite Beam using FRC)

  • 조정래;조근희;김병석;진원종;김성태
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.742-745
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    • 2004
  • The FRP-concrete composite deck system has advantages of corrosion free and easy construction. The system is, however, comprised of two brittle materials, so that it suffers from inherent disadvantage of lack of ductility. In this study, some conceptual design is presented for preventing the brittle failure of FRP-concrete composite deck at ultimate load level. 4-point bending tests are performed for FRP-concrete composite beams using FRC(Fiber Reinforced Concrete). The specimens use the box-shape FRP member in the lower portion. Four types of concrete with different compressive strengths and ductilities including normal mortar and 3 FRCs are placed in the upper portion. Typical failure mode in the test is identified; Concrete compressive failure occurs first at the maximum moment region, and the interfacial debonding between FRP and concrete member proceeds. Finally, the tensile rupture of FRP member occurs. The specimen using FRC with the high compressive ductility of concrete fails with less brittle manner than other specimens. The reason is that the ductility from the concrete in compression prevents the sudden loss of load-carrying capacity after compressive concrete failure.

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금속 볼 밸브의 볼·시트 마멸 특성에 관한 실험적 연구 (Wear Characteristics of Metal Ball and Seat for Metal-Seated Ball Valve)

  • 배준호;정구현
    • Tribology and Lubricants
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    • 제32권1호
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    • pp.32-37
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    • 2016
  • The wear characteristics of metal ball and seat in a metal-seated ball valve significantly affect the performances such as leakage and valve torque. In this work, the wear characteristics of metal ball and seat are experimentally investigated. A stainless steel ball and seat with a high corrosion-resistant coating are prepared and a component level test was performed. The hardness and surface roughness of specimens cut from the metal ball and seat are measured before and after the test using a micro-Vickers hardness tester and confocal microscopy, respectively. In order to assess the wear characteristics, the surfaces of the specimens are carefully examined after the test. The confocal microscope data show that the surface roughness values of both the ball and seat increase by a factor of 3-4, which may lead to an increase in valve torque. However, the wear of the seat is found to be more significant than that of the ball. In addition, a comparison of the surfaces of the ball and seat before and after testing revealed that adhesive and abrasive wear are the major wear mechanisms. The results of this study may aid in the design of metal-seated ball valves from the tribological point of view.

원전 배관의 파손확률에 대한 검사의 영향 (Effect of Inspection on Failure Probability of Pipes in Nuclear Power Plants)

  • 박재학;최영환
    • 대한기계학회논문집A
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    • 제36권10호
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    • pp.1249-1254
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    • 2012
  • 원자력발전소의 배관에 대하여 행하는 검사는 배관의 구조건전성에 큰 영향을 미친다. 그러나 검사에는 많은 인력과 비용이 소요되므로 검사의 영향을 평가하여 최적의 검사주기와 검사품질을 결정하는 것이 중요하다. 본 논문에서는 원자력발전소 배관의 파손확률을 평가할 수 있도록 개발된 P-PIE 프로그램을 사용하여 검사의 유무, 검사주기 및 검사품질 등이 배관의 파손확률에 미치는 영향을 살펴보았다. 국내 원전의 배관 데이터를 사용하여 해석하였으며, 피로 및 부식에 의한 균열성장을 고려하였다.