• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.618-625
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• 2018

With the passing of time, exposed concrete structures are affected by a range of environmental, chemical, and physical factors. These factors seep into the concrete and have a deleterious influence compared to the initial performance. The importance of identifying and preventing further performance degradation due to the occurrence of deterioration has been greatly emphasized. In recent years, evaluations of the target life have attracted increasing interest. During the freezing-melting effect, a part of the concrete undergoes swelling and shrinking repeatedly. At these times, chloride ions present in seawater penetrate into the concrete, and accelerate the deterioration due to the corrosion of reinforced bars in the concrete structures. For that reason, concrete structures located onshore with a freezing-melting effect are more prone to this type of deterioration than inland structures. The aim of this study was to develop a high performance mortar mixed with a mineral admixture for the durability properties of concrete structures near sea water. In addition, experimental studies were carried out on the strength and durability of mortar. The mixing ratio of the silica fume and meta kaolin was 3, 7 and 10 %, respectively. Furthermore, the ultra-fine fly ash was mixed at 5, 10, 15, and 20%. The mortar specimens prepared by mixing the admixtures were subjected to a static strength test on the 1st and 28th days of age and degradation acceleration tests, such as the chloride ion penetration resistance test, sulfuric acid resistance test, and salt resistant test, were carried out at 28 days of age. The chloride diffusion coefficient was calculated from a series of rapid chloride penetration tests, and used to estimate the life time against corrosion due to chloride ion penetration according to the KCI, ACI, and FIB codes. The life time of mortar with 10% meta kaolin was the longest with a service life of approximately 470 years according to the KCI code.

• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.491-497
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• 2014

The corrosion of steel reinforcement in reinforced concrete bridge decks significantly affects the degradation of the capacity. Due to the advantageous characteristics such as high tensile strength and non-corrosive property, fiber reinforced polymer (FRP) has been gathering much interest from designers and engineers for possible usage as a alternative reinforcement for a steel reinforcing bar. However, its application has not been widespread, because there data for short- and long-term performance data of FRP reinforced concrete members are insufficient. In this paper, seven full-scale decks with dimensions of $4000{\times}3000{\times}240mm$ were prepared and tested to failure in the laboratory. The test parameter was the bottom reinforcement ratio in transverse direction. The decks were subjected to various levels of concentrated cyclic load with a contact area of $577{\times}231mm$ to simulate the vehicle loading of DB-24 truck wheel loads acting on the center span of the deck. It was observed that the glass FRP (GFRP) reinforced deck on a restraint girder is strongly effected to the level of the applied load rather than the bottom reinforcement ratio. The study results showed that the maximum load less than 58% of the maximum static load can be applied to the deck to resist a fatigue load of 2 million cycles. The fatigue life of the GFRP decks from this study showed the lower and higher fatigue performance than that of ordinary steel and CFRP rebar reinforced concrete deck. respectively.

• Journal of Conservation Science
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• v.32 no.2
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• pp.203-213
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• 2016

Conservation treatment of modern cultural heritage rickshaw from National Museum of Korean Contemporary History were carried out. The Rickshaw is divided into three parts which are chair part, sun-block cover part, wheels part. Treatment was referred to analysis results of P-XRF, species identification, FT-IR and microscope observation on Rickshaw. Outer films of rickshaw were chipped off. Therefore, conservation and restoration treatment were carried out in the damaged area. Degradation in armrest, saddle and backside of chair may cause serious problem. Therefore, the reinforcement were carried out with similar materials. Dry and wet cleaning were performed in sun-block cover to remove white stain and corrosion contaminant. Furthermore, reinforcement and restoration were performed in damaged area. Rickshaw from National Museum of Korean Contemporary History was made with various materials. This research result expects to be a great example of conservation treatment for modern cultural heritage which is made of various materials and to be used as useful data for conservation and restoration in modern cultural heritage.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.11
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• pp.810-816
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• 2017

This study investigates the relationship between the damage patterns and structural performance levels of a multi-strand 7-wire strand that is used as an important member of stay cables. Stay cables are continuously damaged after completion, and corrosion is the main cause. However, it is difficult to check the damage pattern inside the cable due to its structural characteristics, and it is difficult to evaluate the degradation level of the damage quantitatively. This study derives the relationship between the damage pattern and the performance level of the stranded wire by comparing results and analyzing them through an indoor experiment and finite element analysis. In order to simulate the damage of a 7-wire strand, artificial damage was applied by mechanical precision machining to perform a performance evaluation. The results of the analysis show that regardless of the damage size of the strand, the structural performance deteriorated immediately after the damage. It was experimentally and analytically deduced that the type and amount of damage should be considered as a parameter for evaluating the performance level of the strand. This information can be used for the safety management of a cable stayed bridge by constructing a database according to the pattern and amount of damage.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.4
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• pp.403-409
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• 2017

For dry storage of the spent nuclear fuel (SNF) stored in the storage pool of a nuclear power plant, essentially all moisture must be removed to prevent corrosion of the assembly and canister internals and/or degradation of fuel cladding integrity after SNF canister loading operation. R&D work is now in progress on a forced gas drying system that can be used to remove residual water in canisters. In this work, preliminary design is performed to manufacture the forced gas drying system. This process includes a case study of dry methods for canister moisture removal, relative codes and standards, confirmation of adequate dryness, needs analysis at plant sites, and characteristics of SNF stored in pools. Through this preliminary design work, we obtained a conceptual flow diagram and preliminary P&ID of the forced gas drying system. The results of this study can be used to determine details of the design to manufacture the forced gas drying system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.4013-4018
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• 2014

A 0.45 $cm^2$ DSSC device with a glass/FTO/blocking layer/$TiO_2$/N719(dye)/electrolyte/50 nm-Pt/50 nm-Au/FTO/glass was prepared to examine the stability of the Au/Pt bilayered counter electrode (CE) with electrolyte and the energy conversion efficiency (ECE) of dye-sensitized solar cells (DSSCs). For comparison, a 100 nm-thick Pt only CE DSSC was also prepared using the same method. The photovoltaic properties, such as the short circuit current density ($J_{sc}$), open circuit voltage ($V_{oc}$), fill factor (FF), and ECE, were checked using a solar simulator and potentiostat with time after assembling the DSSC. The microstructure of the Au/Pt bilayer was examined by optical microscopy after 0~25 minutes. The ECE of the Pt only CE-employed DSSC was 4.60 %, which did not show time dependence. On the other hand, for the Au/Pt CE DSSC, the ECEs after 0, 5 and 15 minutes were 5.28 %, 3.64 % and 2.09 %, respectively. The corrosion areas of the Au/Pt CE determined by optical microscopy after 0, 5, and 25 minutes were 0, 21.92 and 34.06 %. These results confirmed that the ECE and catalytic activity of Au/Pt CE decreased drastically with time. Therefore, a Au/Pt CE-employed DSSC may be superior to the Pt only CE-employed one immediately after integration of the device, but it would degrade drastically with time.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.307-314
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• 2017

Concrete is a durable and cost-benefit construction material, however performance degradation occurs due to steel corrosion exposed to chloride attack. Penetration of chloride ion usually decreases due to hydrates formation and reduction of pores, and the reduced chloride behavior is considered through decreasing diffusion coefficient with time. In the work, HPC (High Performance Concrete) samples are prepared with 3 levels of W/B (water to binder) ratios of 0.37, 0.42, and 0.27 and 3 levels of replacement ratios of 0%, 30% and 50%. Several tests containing chloride diffusion coefficient, passed charge, and compressive strength are performed considering age effect of 28 days and 180 days. Chloride diffusion is more reduced in OPC concrete with lower W/B ratio and GGBFS concrete with 50% replacement ratio shows significant reduction of chloride diffusion in higher W/B ratio. At the age of 28 days, GGBFS concrete with 50% replacement ratio shows more rapid reduction of chloride diffusion than strength development, which reveals that abundant GGBFS replacement has effective resistance to chloride penetration even in the early-aged condition.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.4
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• pp.2037-2042
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• 2013

A TCO-less palladium (Pd) catalytic layer on the glass substrate was assessed as the counter electrode (CE) in a dye sensitized solar cell (DSSC) to confirm the stability of Pd with the $I^-/I_3{^-}$electrolyte on the DSSC performance. A 90nm-thick Pd film was deposited by a thermal evaporator. Finally, DSSC devices of $0.45cm^2$ with glass/FTO/blocking layer/$TiO_2$/dye/electrolyte(10 mM LiI + 1 mM $I_2$ + 0.1 M $LiClO_4$ in acetonitrile solution)/Pd/glass structure was prepared. We investigated the microstructure and photovoltaic property at 1 and 12 hours after the sample preparation. The optical microscopy, field emission scanning electron microscopy (FESEM), cyclic voltammetry measurement (C-V), and current voltage (I-V) were employed to measure the microstructure and photovoltaic property evolution. Microstructure analysis showed that the corrosion by reaction between the Pd layer and the electrolyte occurred as time went by, which led the decrease of the catalytic activity and the efficiency. I-V result revealed that the energy conversion efficiency after 1 and 12 hours was 0.34% and 0.15%, respectively. Our results implied that we might employ the other non-$I^-/I_3{^-}$electrolyte or the other catalytic metal layers to guarantee the long term stability of the DSSC devices.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.1
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• pp.200-214
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• 1993

This paper presents the results of fluidelastic instability analysis performed for the U-tube bundle of a Westinghouse model 51 steam generator, one of the recirculating types designed at an early stage, in which the principal region of external cross-flow is associated with the U-bend portion of tube. The prerequisites for this analysis are detailed informations of the secondary side flow conditions in the steam generator and the free vibration behaviours of the U-tubes. In this study, the three-dimensional two-phase flow field in the steam generator has been calculated employing the ATHOS3 steam generator two-phase flow code and the ANSYS engineering analysis code has been used to calculate the free vibration responses of specific U tubes under consideration. The assessment of the potential instability for the suspect U-tubes, which is the final analysis process of the present work, has been accomplished by combining the secondary side velocity and density distributions obtained from the ATHOS3 prediction with the relative modal displacement and natural frequency data calculated using the ANSYS code. The damping of tubes in two-phase flow has been deduced from the existing experimental data by taking into account the secondary side void fraction effect. In operation of the steam generator, the tube support conditions at the tube-to-tube support plate intersections due to either tube denting degradation or deposition of tube support plate corrosion products or ingression of dregs. Thus, various hypothetical cases regarding the tube support conditions at the tube-to-tube support plate intersections have been considered to investigate the clamped support effects on the forced vibration response of the tube. Also, the effect of anti-vibration bars support in the curved portion of tube has been examined.

• Journal of Life Science
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• v.21 no.3
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• pp.444-450
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• 2011

Perchlorate ($ClO_4^-$) is a contaminant found in surface water and soil/ground water. Autotrophic perchlorate-reducing bacteria (PRB) use hydrogen gas ($H_2$) as an electron donor to remove perchlorate. Since iron corrosion can produce $H_2$, feasibility of autotrophic perchlorate-removal using zero-valent iron (ZVI) was examined in this study using activated sludge that is easily available from a wastewater treatment plant. Batch test showed that activated sludge microorganisms could successfully degrade perchlorate in the presence of ZVI. The perchlorate biodegradation was confirmed by molar yield of $Cl^-$ as perchlorate was degraded. Scanning electron microscope revealed that rod-shaped microorganisms on the surface of iron particles used for the autotrophic perchlorate-removal, suggesting that iron particles could serve as supporting media for the formation of biofilm as well. DGGE analyses revealed that microbial profile of the inoculum (activated sludge) was different from that of biofilm sample obtained from the ZVI-added enrichment culture used for $ClO_4^-$-degradation. A major band of the biofilm sample was most closely related to the class Clostridia.