• Title/Summary/Keyword: Corrosion Condition

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Anticorrosive Monitoring and Complex Diagnostics of Corrosion-Technical Condition of Main Oil Pipelines in Russia

  • Kosterina, M.;Artemeva, S.;Komarov, M.;Vjunitsky, I.;Pritula, V.
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.208-211
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    • 2008
  • Safety operation of main pipelines is primarily provided by anticorrosive monitoring. Anticorrosive monitoring of oil pipeline transportation objects is based on results of complex corrosion inspections, analysis of basic data including design data, definition of a corrosion residual rate and diagnostic of general equipment's technical condition. All the abovementioned arrangements are regulated by normative documents. For diagnostics of corrosion-technical condition of oil pipeline transportation objects one presently uses different methods such as in-line inspection using devices with ultrasonic, magnetic or another detector, acoustic-emission diagnostics, electrometric survey, general external corrosion diagnostics and cameral processing of obtained data. Results of a complex of diagnostics give a possibility: $\cdot$ to arrange a pipeline's sectors according to a degree of corrosion danger; $\cdot$ to check up true condition of pipeline's metal; $\cdot$ to estimate technical condition and working ability of a system of anticorrosive protection. However such a control of corrosion technical condition of a main pipeline creates the appearance of estimation of a true degree of protection of an object if values of protective potential with resistive component are taken into consideration only. So in addition to corrosive technical diagnostics one must define a true residual corrosion rate taking into account protective action of electrochemical protection and true protection of a pipeline one must at times. Realized anticorrosive monitoring enables to take a reasonable decision about further operation of objects according to objects' residual life, variation of operation parameters, repair and dismantlement of objects.

An Electrochemical Property Stud on the Corrosion Behavior of Welding Part of RE36 Steel for Marine Structure (해양구조물용 RE36강의 용접부 부식거동에 관한 전기화학적 특성 연구)

  • 김성종;김진경;문경만
    • Journal of Welding and Joining
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    • v.18 no.5
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    • pp.70-76
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    • 2000
  • The effect of Post Weld Heat Treatment(PWHT) of RE36 steel for marine structure was investigated with parameters such as micro-vickers hardness, corrosion potential and corrosion current density of weld metal(WM), base metal(BM) and heat affected zone(HAZ), and both Al alloy anode generating current and Al alloy anode weight loss quantity etc. Hardness of post-weld heat treated BM, WM and HAZ is lower than that of As-welded condition of each region. However, hardness of HAZ was the highest among those three parts regardless of PWHT temperature and corrosion potential of WM was the highest among those three parts without regard to temperature and corrosion potential of WM was the highest among those three parts without regard to PWHT temperature. The amplitude of corrosion potential difference of each other three parts at PWHT temperature $550^{\circ}C$, $650^{\circ}C$ are smaller than that of three parts by As-welded condition and corrosion current density obtained by PWHT was also smaller than that of As-welded condition. Eventually, it was known that corrosion resistance was increased by PWHT. However both Al anode generating current and anode weight loss quantity were also decreased by PWHT compare to As-welded condition when RE36 steel is cathodically protected by Al anode. Therefore, it is suggested that the optimum PWHT temperature with increasing corrosion resistance and cathodic protection effect is $550^{\circ}C$.

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Effect of Boundary Conditions on Failure Probability of Corrosion Pipeline (부식 배관의 경계조건이 파손확률에 미치는 영향)

  • 이억섭;편장식
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.873-876
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    • 2002
  • This paper presents the effect of internal corrosion, external corrosion, material properties, operation condition, earthquake, traffic load and design thickness in pipeline on the failure prediction using a failure probability model. A nonlinear corrosion is used to represent the loss of pipe wall thickness with time. The effects of environmental, operational, and design random variables such as a pipe diameter, earthquake, fluid pressure, a corrosion rate, a material yield stress and a pipe thickness on the failure probability are systematically investigated using a failure probability model for the corrosion pipeline.

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Effect of Boundary Conditions on failure Probability of Corrosion Pipeline (부식 배관의 경계조건이 파손확률에 미치는 영향)

  • 이억섭;편장식
    • Proceedings of the Korean Reliability Society Conference
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    • 2002.06a
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    • pp.403-410
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    • 2002
  • This paper presents the effect of internal corrosion, external corrosion, material properties, operation condition, earthquake, traffic load and design thickness in pipeline on the failure prediction using a failure probability model. A nonlinear corrosion is used to represent the loss of pipe wall thickness with time. The effects of environmental, operational, and design random variables such as a pipe diameter, earthquake, fluid pressure, a corrosion rate, a material yield stress and a pipe thickness on the failure probability are systematically investigated using a failure probability model for the corrosion pipeline.

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Consideration on the Risk of Corrosion Assessment in Reinforced Concrete Structure by Corrosion Potential Criterion (부식전위 기준에 의한 철근콘크리트 구조물의 부식진단의 위험성에 관한 고찰)

  • Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.147-152
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    • 2015
  • Corrosion of steel reinforcement is a major factor in the deterioration of harbour and bridge structure. Steel corrosion in concrete must be checked for assessing the condition of a reinforced concrete structure. There are several ways how to measure the corrosion condition of reinforced concrete, but the corrosion potential measurement is a very simple, rapid, cost-effective and non-destructive technique to evaluate the severity of corrosion in reinforced concrete structure, therefore commonly used by engineers. However some particular situations may not relate to the reinforcement corrosion probability and a simple comparison of the corrosion potential data with the ASTM C876 Standard on steel reinforcement corrosion probability could be meaningless and not give reliable informations because of environment factors as oxygen concentration, chloride content, concrete resistance. Therefore this paper explains the risk of corrosion assessment in reinforced concrete structure and how many factors can affect the reliability of the corrosion potential data.

Corrosion Behavior of Nickel-Plated Alloy 600 in High Temperature Water

  • Kim, Ji Hyun;Hwang, Il Soon
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.61-67
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    • 2008
  • In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 were investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application.

The influence of the hollow and solid shaft cross sectionof SM 30 C steel on corrosion fatigue strength (SM 30 C강의 중공 중실축 단면변화 부식피로강도에 미치는 영향)

  • 신규동;장백선;김웅집
    • Journal of Ocean Engineering and Technology
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    • v.11 no.2
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    • pp.28-38
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    • 1997
  • The corrosion fatigue test was conducted in air to investigate the corrosion fatigue strength of SM 30 C steel by which was corroded in the under sea and surface in the conditions of 3.0% NaCl salt solution. The fatigue tests were carried out on a rotary bending testing machine of cantilever type. The corrosion effect of the sea surface conditionwas served more than that of the under sea condition which was due ti the periodic contact of air thus accelerate the corrosion. The difference of the fatgue strength between sea surface and under sea conditions decreased with increase of stree level and corroded period. Inthe case of the solid shaft and thickness 2mm of hollow shaft, the difference of corrosion fatigue strength decreased as stress level and corrosion periodic increasing. Onthe contrary in the case of thickness 1mm of hollow sgaft, the difference of it increased as stress level, corrosionn periooodic increasing and also the condition of corrosion chaanged. The main factors affecting the degradation of fatigue strength due to corrosion were the reduction of sectional area and the increase of surface roughness. The interference phenomenon increase with stress level got higher.

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Experimental Studies on Comparison of Stress Corrosion Cracking Generation Due to Pipe Material Degradation in the Primary Stage of the Nuclear Power Plant (원전 1차 측 배관재질의 열화에 따른 응력부식균열 발생 비교 실험 연구)

  • Park, Kwang-Jin;Lee, Gyu-Young;Bae, Dong-Ho
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.108-113
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    • 2007
  • In this report, stress corrosion cracking generation due to pipe material degradation in the primary stage of the nuclear power plant was investigated. Firstly, after artificially degrading the CF8A steel during 2, 4, and 6 months in actual temperature, $400^{\circ}C,$ assessed corrosion susceptibility of the degraded material following ASTM G5 standard. And next, the S.C.C. tests for the degraded material were conducted under the condition of $60^{\circ}C,$ 2wt.% H2BO3+Li70H solution, 0.8 oy. From the results, Corrosion rates linearly increased with degradation period and solution temperature increase. And both the raw material and the degraded materials were not failed in the S.C.C. test condition. In spite of long time test (about 3,900 hrs) under S.C.C. condition, surface pits or surface corrosion by the electro chemical reaction were not observed. And also, even though the nondestructive DCPD and ACPD methods were applied to on-line monitor the S.C.C. failure processes it was impossible because the surface pits and cracks were not generated.

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Effect of operating conditions on carbon corrosion in High temperature polymer electrolyte membrane fuel cells (HT-PEMFCs) (고온형 고분자 전해질막 연료전지(HT-PEMFC) 구동환경에 따른 탄소 담지체 부식 평가)

  • Lee, Jinhee;Kim, Hansung
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.89.1-89.1
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    • 2011
  • The influence of potential and humidity on the electrochemical carbon corrosion in high temperature polymer electrolyte membrane fuel cells(HT-PEMFCs) is investigated by measuring $CO_2$ emission at different potentials for 30 min using on-line mass spectrometry. These results are compared with low tempterature polymer electrolyte membrane fuel cells(LT-PEMFCs) operated at lower temperature and higher humidity condition. Although the HT-PEMFC is operated at non humidified condition, the emitted $CO_2$ in the condition of HT-PEMFC is more than LT-PEMFC at the same potential in carbon corrosion test. Thus, carbon corrosion shows a stronger positive correlation with the cell temperature. In addition, the presence of a little amount of water activate electrochemical carbon corrosion considerably in HT-PEMFC. With increased carbon corrosion, changes in fuel cell electrochemical characteristics become more noticeable and thereby indicate that such corrosion considerably affects fuel cell durability.

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Effect of Niobium on Corrosion Fatigue Properties of High Strength Steel

  • Cho, Young-Joo;Cho, Sang-Won;Kim, Jung-Gu
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.81-89
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    • 2018
  • In this study, the effect of Nb alloying element on the corrosion fatigue properties of high strength steel is investigated by conducting fatigue experiments under corrosive condition and hydrogen induced condition, potentiodynamic polarization test, tensile test and surface analyses. Nb element is added to enhance the mechanical property of medium carbon steel. This element forms MX-type phases such as carbides and nitrides which are playing an important role in the grain refinement. The grain refinement is one of the effective way to improve mechanical property because both tensile strength and toughness can be improved at the same time. However, MX-type phase precipitates can be a susceptible site to localized corrosion in corrosive environment due to the potential difference between matrix and precipitate. The obtained results showed that Nb-added steel improved corrosion fatigue property by grain refinement. However, it is degraded for hydrogen-induced fatigue property due to Nb, Ti-inclusions acting as a stronger trap.