• Journal of Photoscience
• /
• 제10권1호
• /
• pp.9-20
• /
• 2003

Recent studies on the photoreactivity of l,4-unsaturated systems have changed some ideas that were firmly established in this area of research for many years. Thus, we have described the first examples of 2-aza-di-$\pi$-methane (2-ADPM) rearrangements promoted by triplet-sensitization and by single electron transfer (SET) using electron-acceptor sensitizers. These reactions afford N-vinylaziridine and cyclopropylimine photoproducts in the first examples of di-$\pi$-methane processes that yield three-membered ring heterocycles. l-Aza-1,4-dienes also undergo SET-promoted l-aza-di-$\pi$-methane (l-ADPM) rearrangements via radical-cation intermediates using electron acceptor sensitizers. In some cases, alternative cyclizations yielding different carbocycles and heterocycles have been observed. The l-ADPM and di-$\pi$-methane (DPM) reactions also occur via radical-anion intermediates on irradiation using electron donor sensitizers. On the other hand, the photoreactivity reported for $\beta$,${\gamma}$-unsaturated aldehydes for many years was decarbonylation to the corresponding alkenes. However, our studies demonstrate that these compounds undergo the oxa-di-$\pi$-methane (ODPM) rearrangement with high chemical and quantum efficiency. A comparison of the photochemical reactivity of $\beta$,${\gamma}$-unsaturated aldehydes and corresponding methyl ketones has shown that the ketones do not undergo the ODPM rearrangement while the corresponding aldehydes are reactive by this pathway. Monosubstituted $\beta$,${\gamma}$-unsaturated aldehydes at C-2 undergo the ODPM rearrangement yielding the corresponding cyclopropane carbaldehydes diastereoselectively. Finally, we have described the first examples of reactions, similar to the well know Norrish Type I process, which take place in the triplet excited state of $\beta$,${\gamma}$-unsaturated carbonyl compounds by excitation of the C-C double bond instead of the carbonyl group.

• Journal of Astronomy and Space Sciences
• /
• 제31권4호
• /
• pp.335-340
• /
• 2014

There have been many suggestions and much debate about climate variability during the Holocene. However, their complex forcing factors and mechanisms have not yet been clearly identified. In this paper, we have examined the Holocene climate cycles and features based on the wavelet analyses of $^{14}C$, $^{10}Be$, and $^{18}O$ records. The wavelet results of the $^{14}C$ and $^{10}Be$ data show that the cycles of ~2180-2310, ~970, ~500-520, ~350-360, and ~210-220 years are dominant, and the ~1720 and ~1500 year cycles are relatively weak and subdominant. In particular, the ~2180-2310 year periodicity corresponding to the Hallstatt cycle is constantly significant throughout the Holocene, while the ~970 year cycle corresponding to the Eddy cycle is mainly prominent in the early half of the Holocene. In addition, distinctive signals of the ~210-220 year period corresponding to the de Vries cycle appear recurrently in the wavelet distribution of $^{14}C$ and $^{10}Be$, which coincide with the grand solar minima periods. These de Vries cycle events occurred every ~2270 years on average, implying a connection with the Hallstatt cycle. In contrast, the wavelet results of $^{18}O$ data show that the cycles of ~1900-2000, ~900-1000, and ~550-560 years are dominant, while the ~2750 and ~2500 year cycles are subdominant. The periods of ~2750, ~2500, and ~1900 years being derived from the $^{18}O$ records of NGRIP, GRIP and GISP2 ice cores, respectively, are rather longer or shorter than the Hallstatt cycle derived from the $^{14}C$ and $^{10}Be$ records. The records of these three sites all show the ~900-1000 year periodicity corresponding to the Eddy cycle in the early half of the Holocene.

• Asian Pacific Journal of Cancer Prevention
• /
• 제15권3호
• /
• pp.1387-1390
• /
• 2014

Background: The aim of this study was to evaluate trends in incidence of breast cancer in women less than 40 years in Asia. Materials and Methods: Registered cases of female breast cancer age less than 40 years and corresponding person years were ascertained from the CI5plus for 10 registries in Asia for the duration of 1970- 2002. Cases were categorized into three age groups: 16-40, 16-29, and 30-40. The 16-40 age group was adjusted to world age population structure. Joinpoint regression analysis was conducted to determine the annual percent of change (APC) and the average annual percent of change (AAPC) for each age group. Results: A total of 23,661 cases of breast cancer occurred in the 10 registries during the 32 years (1970-2002) of follow-up. The overall age adjusted (16-40 group) breast cancer incidence rate increased from 2.28-4.26 cases per 100,000 population corresponding to an AAPC of 2.6% (95%CI 2.1, 3.0). The trend in incidence for the age group 16-29 increased from 0.45-1.07 corresponding to an AAPC of 2.8% (95%CI 1.9, 3.7). In age group 30 to 40, the incidence ranged from 13.3 in year 1970 to 24.8 in year 2002 corresponding to an AAPC of 2.7% (95% CI 2.3, 3.1). There were two statistically significant changing points in the regression line for the age groups 30-40 and 16-40: one point in the year 1975 with an APC of 6.1 (5.1, 7.1), and the other in 1985 with an APC of 0.4% (0.01, 0.8). Conclusions: Our study proved that: 1) the incidence of breast cancer in young women has increased in Asian population during the study period; 2) the rate of increase was very high during the period of 1980-1990.

• Structural Engineering and Mechanics
• /
• 제65권3호
• /
• pp.315-325
• /
• 2018

This paper predicts the flexural behaviour of reinforced concrete (RC) beams strengthened with a precast strip of ultra-high performance fiber-reinforced concrete (UHPFRC). In the first phase, ultimate load capacity of preloaded and strengthened RC beams by UHPFRC was predicted by using various analytical models available in the literature. RC beams were preloaded under static loading approximately to 70%, 80% and 90% of ultimate load of control beams. The models such as modified Kaar and sectional analysis predicted the ultimate load in close agreement to the corresponding experimental observations. In the second phase, the famous fatigue life models such as Papakonstantinou model and Ferrier model were employed to predict the number of cycles to failure and the corresponding deflection. The models were used to predict the life of the (i) strengthened RC beams after subjecting them to different pre-loadings (70%, 80% and 90% of ultimate load) under static loading and (ii) strengthened RC beams after subjecting them to different preloading cycles under fatigue loading. In both the cases precast UHPFRC strip of 10 mm thickness is attached on the tension face. It is found that both the models predicted the number of cycles to failure and the corresponding deflection very close to the experimental values. It can be concluded that the models are found to be robust and reliable for cement based strengthening systems also. Further, the Wang model which is based on Palmgren-Miner's rule is employed to predict the no. of cycles to failure and it is found that the predicted values are in very good agreement with the corresponding experimental observations.

• Asian-Australasian Journal of Animal Sciences
• /
• 제7권3호
• /
• pp.357-362
• /
• 1994

Five adult sheep were exposed to intermittent cold for 12 h (18:00-06:00) at an air temperature of $5{\pm}1^{\circ}C$ followed by 12 h (06:00-18:00) at $25{\pm}2^{\circ}C$ over a period of 8 days continuously. Carotid artery blood (Tc), mean skin (Ts) and mean body (Tb = 0.86 Tc + 0.14 Ts) temperatures, heat production rate (HP), respiratory evaporative heat loss, respiration rate (RR) and volume were measured before and after exposure. Tc during the 12 h cold period of intermittent cold exposure was similar to that during the corresponding period in the warm environment, while Tc in the $25^{\circ}C$ of intermittent cold was higher (p < 0.05) than that in the corresponding period in the warm environment. Ts during the cold period markedly decreased (p < 0.001) by about $9^{\circ}C$ when compared with that in the corresponding time period in the warm environment, while Ts during the $25^{\circ}C$ period of intermittent cold recovered to a similar level to that in the warm environment. Tb was lower (p < 0.001) during the cold period of intermittent cold, whereas a slight increase in Tb during the $25^{\circ}C$ period of intermittent cold was significant (p < 0.05) when compared with the value during the similar period in the warm environment. HP was greatly increased (p < 0.001) by cold exposure, followed by an immediate decrease during the first one hour of the 12 h warm period, reaching a similar level to that in the warm environment. A lower (p < 0.05) RR was observed during both the cold and $25^{\circ}C$ period of intermittent cold than during the corresponding periods in the warm environment. The results of the present investigation clearly show that the body temperature of sheep increased during a 12 h warm period following 12 h of exposure to cold. These results suggest that during a warm period of an intermittent cold exposure cycle, heat could be shored in the animal body.

• 한국수산과학회지
• /
• 제53권5호
• /
• pp.681-687
• /
• 2020

Physicochemical properties of fucoidan and alginate extracted from Sargassium horneri were investigated. The alginates were extracted and purified via three different routes (CaCl₂, HCl and ethanol routes), and their rheological properties at various concentrations and temperatures were determined. The yield of fucoidan was 3.08%, and it was mainly composed of fucose and galactose. Fourier-transform infrared spectrum of fucoidan showed strong absorption band at 1,254 and 827 cm^-1 corresponding to the sulfate group. Flow behavior of the alginate solution was characterized using the power-law model. The consistency index increased with increasing concentrations. The sodium alginate solution (1.5%) exhibited Newtonian behavior when extracted via the CaCl₂ and HCl routes, while it exhibited pseudoplastic behavior when extracted via the ethanol route. The effect of temperature on the flow behavior was investigated in terms of the activation energy (E_a), which was obtained using the Arrhenius equation. The E_a value corresponding to the alginate solution decreased with increasing shear rates. The E_a values corresponding to the alginate solutions purified via the CaCl₂, HCl, and ethanol routes were 13.54-18.64 kJ/mol, 13.42-19.21 kJ/mol, and 9.51-10.67 kJ/mol, respectively. The low E_a values corresponding to the solutions extracted via the ethanol route suggest that the flow behavior does not depend significantly on temperature.

• 정보처리학회논문지B
• /
• 제19B권2호
• /
• pp.77-82
• /
• 2012

본 논문에서는 다양한 생체신호 중 영상 및 음성 신호에 대한 분석 파라메터들을 적용한 실험 방법을 통해 폐 수혈 상응점 자극에 따른 효과성을 입증하는 연구를 수행하였다. 이를 위해 20대 남성 25명을 대상으로 폐와 연관된 수혈 상응점 자극 전과 후의 얼굴 영상 및 음성을 수집하였다. 또한, 수집된 자료를 기반으로 한의학적 진단 이론에서 제시하고 있는 폐와 관련된 우측 뺨 영역의 색상 변화와 음성 에너지 크기 및 발화속도의 변화를 측정, 분석하였다. 결과적으로 폐 수지침 요법을 수행한 후에 우측 뺨 영역의 L값이 평균 2.33감소하였으며 a값과 b값이 평균 0.76, 0.97증가하였다. 또한, 음성에너지 크기는 평균 0.42증가하였으며 발화속도는 평균 0.07감소하였다. 즉, 폐 수지침 요법을 통해 폐 기능이 향상되는 효과를 나타낸 것으로 분석되었다.

• 말소리와 음성과학
• /
• 제3권3호
• /
• pp.35-47
• /
• 2011

The purpose of this study is to examine the influence of Chinese high and level vs. rising tone on the pitch pattern of corresponding Sino-Korean words delivered by Chinese learners of Korean and to examine the aspects how these two tones of corresponding Chinese words affect the pitch patterns of Sino-Korean words. Scope of this research is limited to the Chinese learners of Korean, especially when they pronounce same-form-same-meaning Sino-Korean words. In this study, Chinese learners pronounced both Chinese words and corresponding Sino-Korean words. By using the software learners' pitch pattern were recorded, analyzed, and compared with the tone of corresponding Chinese words. Experimental results showed that Sino-Korean words were affected by Chinese 'high and level tone - high and level tone', 'high and level tone - rising tone', 'high and level tone - falling-rising tone', 'high and level tone - falling tone' and 'rising tone - falling tone' when they started with lenis sounds. On the other hand when Sino-Korean words started with aspirated sounds they were affected by Chinese 'rising tone - high and level tone', 'rising tone - rising tone', 'rising tone - falling-rising tone', 'rising tone - falling tone'. In conclusion, the Chinese learners' pitch patterns of Sino-Korean words are affected by both Chinese high and level & rising tone, especially when Sino-Korean words started with lenis sounds they were more affected by Chinese high and level tone, on the other hand Chinese rising tone influence Sino-Korean words more when they were started with aspirated sounds.

• 말소리와 음성과학
• /
• 제4권2호
• /
• pp.21-31
• /
• 2012

The purpose of this study is to find the influence of Chinese falling-rising tone on the pitch pattern of corresponding partly-different-form-same-meaning Sino-Korean words delivered by Chinese learners of Korean and to examine how the falling-rising tone of corresponding Chinese words affects the pitch patterns of Sino-Korean words. The scope of this research is limited to Chinese learners of Korean, especially on two groups of Sino-Korean words - AB:CB type and AB:AC type that the are second-most frequently occuring different-form-same-meaning Sino-Korean words. In this study, Chinese learners pronounced both Chinese words and corresponding Sino-Korean words. Learners' pitch patterns were recorded and analyzed using software and compared with the tone of corresponding Chinese words. Experimental results showed that AB:CB type Sino-Korean words were not affected by Chinese 'falling-rising tone - high and level tone'. As well as AB:CB type, experimental results showed there were no significant influence on the pitch pattern of AB:AC type Sino-Korean words by Chinese falling-rising tone. But it was clear that Chinese learners' made pitch errors on both AB:CB type and AB:AC type Sino-Korean words. In conclusion, the Chinese learners' pitch patterns of partly-different-form-same-meaning Sino-Korean words are different from Korean native speakers', but their pitch errors cannot be attributed to Chinese falling-rising tone.

• 대한전자공학회논문지SP
• /
• 제44권5호
• /
• pp.35-44
• /
• 2007

넓은 시야각을 갖는 전방향(omnidirectional) 카메라 시스템은 적은 수의 영상으로도 주변 장면에 대해 많은 정보를 취득할 수 있는 장점으로 카메라 교정(calibration), 공간의 3차원 재구성(reconstruction) 등에 널리 응용되고 있다. 실 세계에 존재하는 직선 성분들은 전방향 카메라 모델에 의해 컨투어로 사영(projection)되기 때문에, 영상간에 대응되는 컨투어 성분은 카메라의 회전 및 이동 등의 추정에 효과적으로 활용될 수 있다. 본 논문에서는 전방향 카메라의 변환 파라미터를 추정하기 위한 2단계 최소화 알고리즘이 제안된다. 제안된 알고리즘은 컨투어를 이루는 대응점에 대한 에피폴라(epipolar) 평면과 3차원 벡터간의 각도 오차함수 및 사영된 컨투어의 거리 오차를 단계별로 최소화하는 카메라 파라미터를 계산한다. 등거리(equidistance) 사영된 합성영상과 어안렌즈(fisheye lens)로 취득한 실제 영상을 대상으로 제안된 알고리즘이 카메라의 위치 정보를 정확하게 추정함을 확인하였다.