• Title/Summary/Keyword: Core polymer distribution

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Preparation and Characterization of Low Infrared Emissivity Bicomponent Fibers with Radar Absorbing Property (레이더 흡수특성이 있는 저적외선 방출 복합섬유의 제조 및 특성 연구)

  • Yu Bin;Qi Lu
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.124-128
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    • 2006
  • Heavy weight of the camouflage materials was always the main problem. To solve it, the low infrared emissivity fibers with the radar absorbing property (LIFR) were prepared. The low infrared emissivity fibers (LIF) were firstly melt-spun by co-extrusion of polypropylene (PP) and PP/various fillers master-batches using general conjugate spinning. The infrared emissivity of LW with AA and ZnO was decreased respectively compared with that of pure polypropylene fibers. The infrared emissivity of LIF with 15 wt% Al and 2 wt% ZnO in the sheath-part can reach 0.58. To improve LIF radar absorbing property, LIFR was prepared by filling the 50 wt% ferrite and bronze in the core-part of LIF. The radar absorbing efficacy of LIFR was good and the infrared emissivity was low. For the characterization, fiber electron intensity instrument and differential scanning calorimetry (DSC) were used for the analysis of mechanical properties, thermal and crystallization behavior of the spun-fibers. Scanning electron microscopy (SEM) was carried out to observe the particle distribution of the bicomponent fibers.

Nonlinear finite element solutions of thermoelastic flexural strength and stress values of temperature dependent graded CNT-reinforced sandwich shallow shell structure

  • Mehar, Kulmani;Panda, Subrata K.
    • Structural Engineering and Mechanics
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    • v.67 no.6
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    • pp.565-578
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    • 2018
  • This research article reported the nonlinear finite solutions of the nonlinear flexural strength and stress behaviour of nano sandwich graded structural shell panel under the combined thermomechanical loading. The nanotube sandwich structural model is derived mathematically using the higher-order displacement polynomial including the full geometrical nonlinear strain-displacement equations via Green-Lagrange relations. The face sheets of the sandwich panel are assumed to be carbon nanotube-reinforced polymer composite with temperature dependent material properties. Additionally, the numerical model included different types of nanotube distribution patterns for the sandwich face sheets for the sake of variable strength. The required equilibrium equation of the graded carbon nanotube sandwich structural panel is derived by minimizing the total potential energy expression. The energy expression is further solved to obtain the deflection values (linear and nonlinear) via the direct iterative method in conjunction with finite element steps. A computer code is prepared (MATLAB environment) based on the current higher-order nonlinear model for the numerical analysis purpose. The stability of the numerical solution and the validity are verified by comparing the published deflection and stress values. Finally, the nonlinear model is utilized to explore the deflection and the stresses of the nanotube-reinforced (volume fraction and distribution patterns of carbon nanotube) sandwich structure (different core to face thickness ratios) for the variable type of structural parameter (thickness ratio, aspect ratio, geometrical configurations, constraints at the edges and curvature ratio) and unlike temperature loading.

Preparation and Characterization of Polyurethane Microcapsules Containing Functional Oil (기능성 오일을 함유하는 폴리우레탄 마이크로캡슐의 제조 및 분석)

  • 김인회;서재범;김영준
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.400-409
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    • 2002
  • Polyurethane microcapsules containing functional oil (citronella oil) were successfully prepared by conventional interfacial polymerization of tolulene 2,4-diisocyanate (TDI) and ethylene glycol (EG) and characterized by Fourier transform (FT-IR) spectroscopy, Ultraviolet spectroscopy, particle size analysis, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Tile effects of polymerization variables, such as surfactant concentration and agitation speed, on the particle size and particle size distribution were investigated. FT-IR spectroscopic data showed that citronella oil was successfully encapsulated in the microcapsule. Thermogravimetric analysis data showed that the microcapsule was thermally stable up to $220^{\circ}C$. The controlled release of the citronella oil present in the microcapsule core in a methanol medium was demonstrated by ultraviolet spectroscopy showing that the amount of released citronella oil was increased with increasing time. It was observed that the amount of released citronella oil was increased with increasing stirring speed and emulsifier concentration in the rnicrocapsule preparation step. Polyurethane microcapsules containing citronella oil showed excellent anti-moth property.

A study on the core technologies for industrial type digital 3D SFF system

  • Kim, Dong-Soo;An, Young-Jin;Kim, Sung-Jon;Choi, Byung-Oh;Lim, Hyun-Eui
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2170-2174
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    • 2005
  • Selective Laser Sintering (SLS) is a useful rapid prototyping technique for the manufacture of three dimensional (3D) solid objects directly from a scanning data. A new approach called a Selective Multi-Laser Sintering (SMLS) system has been developed at Korea Institute Machinery & Materials (KIMM) as an industrial type SFFS. This SMLS machine is built with a frame, heaters, nitrogen supply part, laser system. This system uses the dual laser and 3D scanner made in $Solutionix^{TM}$ to improve the precision and speed for large objects. The three-dimensional solid objects are made of polyamide powder. The investigation on each part of SMLS system is performed to determine the proper theirs design and the effect of experimental parameters on making the 3D objects. The temperature of the system has a great influence on sintering the polymer. Because the stability of the powder temperature prevents the deformation of each layer, the controls of the temperature in both the system and the powders are very important during the process. Therefore, we simulated the temperature distribution of build room using the temperature analysis with ANSYS program. Selected radiant heater is used to raise temperature of powder to melting point temperature. The laser parameters such as scan spacing, scan speed, laser power and laser delay time affect the production the 3D objects too. The combination of the slow scan speed and the high laser power shows the good results without the layer curling. The work is under way to evaluate the effect of experimental parameters on process and to produce the various objects. We are going to experiment continuously to improve the size accuracy and surface roughness.

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Estimation of Friction Coefficient Using Smart Strand

  • Jeon, Se-Jin;Park, Sung Yong;Kim, Sang-Hyun;Kim, Sung Tae;Park, YoungHwan
    • International Journal of Concrete Structures and Materials
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    • v.9 no.3
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    • pp.369-379
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    • 2015
  • Friction in a post-tensioning system has a significant effect on the distribution of the prestressing force of tendons in prestressed concrete structures. However, attempts to derive friction coefficients using conventional electrical resistance strain gauges do not usually lead to reliable results, mainly due to the damage of sensors and lead wires during the insertion of strands into the sheath and during tensioning. In order to overcome these drawbacks of the existing measurement system, the Smart Strand was developed in this study to accurately measure the strain and prestressing force along the strand. In the Smart Strand, the core wire of a 7-wire strand is replaced with carbon fiber reinforced polymer in which the fiber Bragg grating sensors are embedded. As one of the applications of the Smart Strand, friction coefficients were evaluated using a full-scale test of a 20 m long beam. The test variables were the curvature, diameter, and filling ratio of the sheath. The analysis results showed the average wobble and curvature friction coefficients of 0.0038/m and 0.21/radian, respectively, which correspond to the middle of the range specified in ACI 318-08 in the U.S. and Structural Concrete Design Code in Korea. Also, the accuracy of the coefficients was improved by reducing the effective range specified in these codes by 27-34 %. This study shows the wide range of applicability of the developed Smart Strand system.

A GMDH-based estimation model for axial load capacity of GFRP-RC circular columns

  • Mohammed Berradia;El Hadj Meziane;Ali Raza;Mohamed Hechmi El Ouni;Faisal Shabbir
    • Steel and Composite Structures
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    • v.49 no.2
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    • pp.161-180
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    • 2023
  • In the previous research, the axial compressive capacity models for the glass fiber-reinforced polymer (GFRP)-reinforced circular concrete compression elements restrained with GFRP helix were put forward based on small and noisy datasets by considering a limited number of parameters portraying less accuracy. Consequently, it is important to recommend an accurate model based on a refined and large testing dataset that considers various parameters of such components. The core objective and novelty of the current research is to suggest a deep learning model for the axial compressive capacity of GFRP-reinforced circular concrete columns restrained with a GFRP helix utilizing various parameters of a large experimental dataset to give the maximum precision of the estimates. To achieve this aim, a test dataset of 61 GFRP-reinforced circular concrete columns restrained with a GFRP helix has been created from prior studies. An assessment of 15 diverse theoretical models is carried out utilizing different statistical coefficients over the created dataset. A novel model utilizing the group method of data handling (GMDH) has been put forward. The recommended model depicted good effectiveness over the created dataset by assuming the axial involvement of GFRP main bars and the confining effectiveness of transverse GFRP helix and depicted the maximum precision with MAE = 195.67, RMSE = 255.41, and R2 = 0.94 as associated with the previously recommended equations. The GMDH model also depicted good effectiveness for the normal distribution of estimates with only a 2.5% discrepancy from unity. The recommended model can accurately calculate the axial compressive capacity of FRP-reinforced concrete compression elements that can be considered for further analysis and design of such components in the field of structural engineering.

Preparation of Isophorone Diisocyanate-loaded Microcapsules and Their Application to Self-healing Protective Coating (Isophorone Diisocyanate 함유 마이크로캡슐의 제조와 자기치유형 보호코팅재에의 응용)

  • Lim, Ye-Ji;Song, Young-Kyu;Kim, Dong-Min;Chung, Chan-Moon
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.56-63
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    • 2015
  • The object of this study is to prepare microcapsules containing a diisocyanate compound, apply them to self-healing protective coating, and evaluate the self-healing capability of the coating by atmospheric moisture. Isophorone diisocyanate (IPDI) polymerized under humid atmosphere, indicating that IPDI can be used as a healing agent. Microencapsulations of IPDI were conducted via interfacial polymerization of a polyurethane prepolymer with diol compounds. The formation of microcapsules was confirmed by Fourier-transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy. The mean diameter, size distribution, morphology and shell wall thickness of microcapsules were investigated by optical microscopy and scanning electron microscopy (SEM). The properties of microcapsules were studied by varying agitation rates and diol structure. The self-healing coatings were prepared on test pieces of CRC board. When scratch was generated in the coatings, the core material flew out of the microcapsules and filled the scratch. The self-healing coatings were damaged and healed under atmosphere with 68~89% relative humidity for 48 h, and SEM and impermeability test for the specimens showed that the scratch could be healed by atmospheric moisture.