• Title/Summary/Keyword: Copper alloy

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Effect of Additional Ag Layer on Corrosion Protection of Cu-Electrodeposited AZ31 Mg Alloy

  • Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.97-97
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    • 2017
  • This study investigated the corrosion protection by electrodeposited copper layer on AZ31 Mg alloy with and without additional silver layer by immersion test, salt spray test, OCP transient and potentiodynamic polarization experiment. The single electrodeposited Cu layer on AZ31 Mg alloy showed a nodular structure with many imperfections of crevices between the nodules, which resulted in the fast initiation of pitting corrosion within first few hours of immersion. Double-layer coating of Cu and outer Ag layer slightly increased the initiation time for pitting corrosion. Triple-layer coatings of Cu/Ag/Cu exhibited the most efficient corrosion protection of AZ31 Mg alloy, compared to the single- and double-layer coatings. Surface morphology of the outer Cu layer in the triple-layer was changed from the nodular structure to fine particle structure with no crevices due to the presence of an additional Ag layer. Thus, the improved corrosion resistance of AZ31 Mg alloy by electrodeposited Cu/Ag or Cu/Ag/Cu layers is readily ascribed to the decreased number of imperfections in the electrodeposited layers due to the additional silver layer. It is concluded that the additional silver layer provides many nucleation sites for the second Cu plating, resulting in the formation of finer and denser structure than the first Cu electrodeposit.

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Effects of Added Cr Element on the Tensile Strength and Electrical Conductivity of Cu-Fe Based Alloys (Cu-Fe계 합금의 강도 및 전기전도도에 미치는 Cr 원소첨가의 영향)

  • Kim, Dae-Hyun;Lee, Kwang-Hak
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.60-64
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    • 2010
  • This study looked at high performance copper-based alloys as LED lead frame materials with higher electrical-conductivity and the maintenance of superior tensile strength. This study investigated the effects on the tensile strength, electrical conductivity, thermal softening, size and distribution of the precipitation phases when Cr was added in Cu-Fe alloy in order to satisfy characteristics for LED Lead Frame material. Strips of the alloys were produced by casting and then properly treated to achieve a thickness of 0.25 mm by hot-rolling, scalping, and cold-rolling; mechanical properties such as tensile strength, hardness and electrical-conductivity were determined and compared. To determine precipitates in alloy that affect hardness and electrical-conductivity, electron microscope testing was also performed. Cr showed the effect of precipitation hardened with a $Cr_3Si$ precipitation phase. As a result of this experiment, appropriate aging temperature and time have been determined and we have developed a copper-based alloy with high tensile strength and electrical-conductivity. This alloy has the possibility for use as a substitution material for the LED Lead Frame of Cu alloy.

Study on Optimization of Dissimilar friction Welding of Nuclear Power Plant Materials (Cu Alloy/STS316L) and Its Real Time AE Evaluation (원자력 발전소용 이종재(Cu 합금/STS316L) 마찰용접의 최적화와 AE에 의한 실시간 평가에 관한 연구)

  • 유인종;권상우;황성필;공유식;오세규
    • Journal of Ocean Engineering and Technology
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    • v.15 no.2
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    • pp.88-93
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    • 2001
  • In this paper, joints of Cu-1Cr-0.1Zr alloy to STS316L were performed by friction welding method. Particularly, Cu-1Cr-0.1Zr alloy is attractive candidate as nuclear power plant material and exibit the best combination of high strength and good electrical and thermal conductivity of any copper alloy examined. The stainless steel is a structural material while copper alloy acts as a heat sink material for the surface heat flux in the first wall. So, in this paper, not only the development of optimizing of friction welding with more reliability and more applicability but also the development of in-process real-time weld quality (such as strength and toughness) evaluation technique by acoustic emission for friction welding of such nuclear reactor component of Cu-1Cr-0.1Zr alloy to STS316L steel sere performed.

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Formability Evaluation of a Copper Alloy for Regenerative Cooling Thrust Chamber (재생냉각 연소기 챔버 제작용 구리합금의 성형성 평가)

  • Ryu, Chul-Sung;Lee, Keum-Oh;Choi, Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.9
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    • pp.939-945
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    • 2009
  • The dome stretching tests and tension tests have been performed to obtain a forming limit curve(FLC) for the copper alloy which is used for manufacturing the regenerative cooling thrust chamber. For experimental investigation of the forming limit curve, we have used in-plane tension specimen to obtain tension-compression strain state as well as out-of-plane specimen to obtain tension-tension strain state through dome stretching test. All specimens were divided into longitudinal and transverse directions according to the orientation of test specimen. The test results showed that in the tension-tension region, copper alloy revealed a maximum major strain of 62.3% and a maximum minor strain of 58.6%. In the tension-compression region, the maximum major strain and the maximum minor strain were measured to be 60.5% and 25.8%, respectively.

A New Process for Liquid Phase Sintering of W-Cu Composite; Fluidized Beds Reductio Method (W-Cu 합금의 액상소결을 위한 새로운 공정의 개발:유동층 환원법)

  • Ihn, Tae-Hyoung;Lee, Seok-Woon;Joo, Seung-Ki
    • Korean Journal of Materials Research
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    • v.4 no.4
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    • pp.393-400
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    • 1994
  • A new process for uniform coating of copper to submicron tungsten powder has been developed. W-Cu alloy where copper can be uniformly distibuted has been made by the liquid phase sintering of thus prepared tungsten powder. It has been found that copper content can be lowered less than IOwt. % in our new process, maintaining the uniform distribution of copper in W-Cu alloy. Relative density above 96% was obtained after the liquid phase sintering when small amount of cobalt was added. It was revealed that the rapid increase of densification rate was due to the enhancement of wettability between tungsten particle and liquid copper.

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Surface Treatment Technology for Metal Corrosion Layer Focusing on Copper Alloy

  • Yang, Eun-Hee;Han, Won-Sik;Choi, Kwang-Sun;Lee, Young-Hoon;Ham, Chul-Hee;Hong, Tae-Kee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.176-182
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    • 2014
  • Using alkali treatment solution, neutrality treatment solution and acid treatment solution, the surface corrosion layer of copper plates and bronze plates that have been artificially corroded using HCl, $H_2SO_4$ and $HNO_3$ solutions were removed. In the case of alkali treatment solution, only air oxidation in the form of black tenorite and white cuproous chloride remained without being removed. In the case of using a neutrality treatment solution, a anhydrous type layer of reddish brown cupric chloride remained without being removed, together with this black and white corrosion substance. In the case of using an acid treatment solution, this red corrosion substance also remained, but all of the oxide was removed on the surface of the specimen that was treated by alternatively using alkali treatment solution and acid treatment solution. In the case of this treatment solution with the order of alkali-acid, oxidation no longer proceeded only through the distilled water cleaning process after treatment, thereby showing that oxidation from the cleaning solution no longer proceeded.

Change of Hematological Characteristic and Heavy Metal Concentration on Rockfish (Sebastes schlegeli) Rearing in the Copper Alloy Mesh (동합금 가두리 망 사육어류, 조피볼락(Sebastes schlegeli)의 혈액 성상과 중금속 축적률)

  • Yang, Sung-Jin;Jun, Je-Cheon;Park, Jung-Jun;Myeong, Jeong-In;Shin, Yun-Kyung
    • Korean Journal of Ichthyology
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    • v.26 no.3
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    • pp.159-170
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    • 2014
  • The effect of substances discharged from copper alloy mesh on the survival rate, growth, and health status of Sebastes schlegeli was investigated. Survival rate of experimental group was 10% higher than control group. There was no significant difference in weight gain and SGR between control group and experiment group (P<0.05). Glucose concentration was lower in the experimental group than that in the control group. GOT and GPT contents did not show significant difference during experiment except for the early three months of experiment (P<0.05). Ammonia concentration had not significantly changed in the experimental group, but it had increased until four months of experiment and then decreased afterwards in the control group. TCHO had decreased in the experiment group compared with that of control group. Copper and zinc contents had increased as compared with those in the initial stage of experiment with no significant difference between experiment group and control group (P<0.05). Histological analysis for the liver revealed that liver tissues were not particularly different from those in control group. There were no significant differences in survival rate, growth, and hematological characteristic between control group and experiment group (P<0.05). Though copper and zinc were accumulated as compared with those during the initial stage of experiment, the levels were lower than permissible levels for copper and zinc. As a result, copper alloy mesh would not adversely affect on the survival rate, growth, and health status of fishes.

Bending Fatigue Life Evaluation of Pure Copper and Copper Alloy Contact Wire (동 전차선(Cu) 및 동합금 전차선(CuSn)의 굽힘피로 수명 평가)

  • Kim, Yongseok;Li, Haochuang;Kang, Minsung;Koo, Jae-Mean;Seok, Chang-Sung;Lee, Kiwon;Kwon, Sam-Young
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.12
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    • pp.1346-1350
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    • 2012
  • Contact wire is one of the most important components supplying electricity to railroad cars. At the beginning of the research on contact wire, wear problem caused by friction between contact wire and pantograph was considered even more important issue for the failure of contact wire. However, since several fatigue fractures were reported from Shinkansen in Japan, fatigue fracture has become another important issue for the failure of contact wire. Despite of its importance, standard of the fatigue test of contact wire has not been established yet. Thus, fatigue characteristics of contact wire is very difficult issue to evaluate quantitatively. Hence, in this study, test method simulating operating conditions of contact wire by Minsung Kang and etc. is used to evaluate the fatigue characteristics of copper alloy contact wire. Also, test results is compared with the result of Minsung Kang's research on pure copper contact wire.

Cladding of Cu and Bronze/Al Alloy by $CO_2$ Laser (고출력 $CO_2$레이저빔에 의한 구리, 청동/알루미늄 합금 클래딩)

  • 강영주;김재도
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.109-115
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    • 1997
  • Laser cladding is a technique for modification of metal surface. In this laser cladding experiment a metal powder feeding system was developed for more efficient laser cladding. This system can reduce processing time and be used simpler than the conventional method. The feeding of metal powder has given a rise to the process for sequential buildup of bulk rapidly solidified materials in the form of fine powder stream to the laser cladding process. The parameters of laser cladding have been investigated using this experimental equipment. Bronze on aluminum alloy and copper on aluminum alloy were experimented by using defocused beam, powder feeding system, and gas shielding. Good cladding was achieved in the range of beam travel speed of 2.25m/min. In the case of copper/aluminum and bronze/aluminum substrate, the absorption of laser beam was too high to produce low diluted clad. In the case of copper/1050 aluminum, the optimal laser cladding condition was of laser power of 2.8kW, powder feed rate of 0.31g/s and beam travel speed of 2.25m/min. In the case of bronze/aluminum the optimal condition is of laser power of 2.5kW, powder feed rate of 0.31g/s, and beam travel speed of 2.36m/min.

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Compatibility Assessment of Copper Alloy and Hydrocarbon Fuel for Regeneratively Cooled Combustion Chamber (재생냉각 연소기용 구리합금과 연료 적합성 검증시험)

  • Lim Byoung-Jik;Kim Jong-Gyu;Kang Dong-Hyuk;Kim Hong-Jip;Kim Hui-Tae;Han Yeoung-Min
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.100-109
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    • 2006
  • In the regeneratively cooled combustion chambers using hydrocarbon fuels, coking occurs as the wall temperature increases which generates compounds deposition on the wall. This phenomenon reduces cooling capability of the coolant, finally it can cause damage to combustor by overheating of chamber wall. In this paper electrical heating equipment which is used for the coking experiments and the test results are introduced. The compatibilities of copper alloy with let A-1 were assessed at each condition based on the test results.

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