• Title/Summary/Keyword: Copper Phthalocyanine

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Properties of FET using Activative Materials with F16CuPc (F16CuPc를 활성층으로 사용한 FET의 특성 연구)

  • Lee, Ho-Shik;Park, Young-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.43-44
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    • 2009
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

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Threshold Voltage Properties of OFET with CuPc Active Material

  • Lee, Ho-Shik;Kim, Seong-Geol
    • Journal of information and communication convergence engineering
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    • v.13 no.4
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    • pp.257-263
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    • 2015
  • In this study, organic field-effect transistors (OFETs) using a copper phthalocyanine (CuPc) material as an active layer and SiO2 as a gate insulator were fabricated with varying active layer thicknesses and channel lengths. Further, using a thermal evaporation method in a high-vacuum system, we fabricated a CuPc FET device of the top-contact type and used Au materials for the source and drain electrodes. In order to discuss the channel formation and FET characteristics, we observed the typical current-voltage characteristics and calculated the threshold voltage of the CuPc FET device. We also found that the capacitance reached approximately 97 pF at a negative applied voltage and increased upon the accumulation of carriers at the interface of the metal and the CuPc material. We observed the typical behavior of a FET when used as an n-channel FET. Moreover, we calculated the threshold voltage to be about 15-20 V at VDS = -80 V.

The Preparation of Polyaniline Electrode Modified by Copper Phthalocyanine on Supporting Carbon Paper

  • Park, Jin-Seok;Kim, Jeong-Soo
    • Macromolecular Research
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    • v.9 no.3
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    • pp.179-183
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    • 2001
  • Cathode materials for the polymer electrolyte membrane fuel cell was prepared by electropoly-merization of aniline at carbon paper in the presence of copper tetrasulfonato-phthalocyanine (CuTsPc) and their electrocatalytic behavior was studied. The amount of polyaniline and CuTsPc in the carbon paper was determined by UV spectroscopy of residual solution in electrochemical cell. The redox process of the prepared electrodes was investigated with cyclic voltammetry. The highest reversible current density was observed at the electrode that contains 27.6 wt% of polyaniline and 19.7 wt% of CuTsPc. The morphology of composite electrode from SEM showed the presence of large cluster of polyaniline with CuTsPc, which should be more finely interpenetrated into macropores of carbon for the better electrocatalytic activity.

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Electrical Properties of FET using F16CuPc (F16CuPc를 이용한 FET의 전기적 특성 연구)

  • Lee, Ho-Shik;Park, Young-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.504-505
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    • 2008
  • We fabricated organic field-effect transistors (OFETs) based a fluorinated copper phthalocyanine ($F_{16}CuPc$) as an active layer. And we observed the surface morphology of the $F_{16}CuPc$ thin film. The $F_{16}CuPc$ thin film thickness was 40nm, and the channel length was $50{\mu}m$, channel width was 3mm. We observed the typical current-voltage (I-V) characteristics and capacitance-voltage (C-V) in $F_{16}CuPc$ FET and we calculated the effective mobility.

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Influence of Exchange-Correlation Functional in the Calculations of Vertical Excitation Energies of Halogenated Copper Phthalocyanines using Time-Dependent Density Functional Theory (TD-DFT)

  • Lee, Sang Uck
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2276-2280
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    • 2013
  • The accurate prediction of vertical excitation energies is very important for the development of new materials in the dye and pigment industry. A time-dependent density functional theory (TD-DFT) approach coupled with 22 different exchange-correlation functionals was used for the prediction of vertical excitation energies in the halogenated copper phthalocyanine molecules in order to find the most appropriate functional and to determine the accuracy of the prediction of the absorption wavelength and observed spectral shifts. Among the tested functional, B3LYP functional provides much more accurate vertical excitation energies and UV-vis spectra. Our results clearly provide a benchmark calibration of the TD-DFT method for phthalocyanine based dyes and pigments used in industry.

A Study of the High Sensitive Nonsilver Halide Imaging Material( II ) - Study of the aqueous coating mechanism and washing effect of the CGL in the $\varepsilon$-CuPc/PVK double-layered organic photoconductor - (고감도 비은염 화상재료 개발연구 ( II ) - Copper Phthalocyanine/PVK 전자사진감광체의 CGL의 수성 coating mechanism과 세정효과에 관한 연구 -)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.27-44
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    • 1991
  • In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

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Tunneling Spectra in Organic Cu-Pc/$Bi_2Sr_2CaCu_2O_{8+\delta}$ Tunnel Junctions

  • Kim, Sunmi;E, Jungyoon;Lee, Kiejin;Ishbas, Takayuki;Lee, Yang-San
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.41-44
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    • 2001
  • We report the current transport properties of a normal metal/organic conductor/ superconductor tunnel junction as a novel high- $T_{c}$ superconducting three terminal device. The organic copper (II) phthalocyanine (Cu-Pc) layer was used far a polaronic quasiparticle (QP) injector. The injection of polaronic QP from the Cu-Pc interlayer into a superconductor $Bi_2$$Sr_2$$CaCu_2$ $O_{8+}$ $\delta$/(BSCCO) thin film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. The tunneling spectroscopy of an Au/cu-PC/BSCCO junction exhibited a zero bias conductance peak which may be due to Andreev reflection at a Cu-Pc/d-wave superconductor junction.n..

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