• 한국재료학회지
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• 제23권7호
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• pp.399-403
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• 2013

The purpose of this study is to investigate the coloration characteristics by identifying the factor affecting red coloration of copper red glaze in traditional Korean ceramics. This study analyzed the characteristics of the reduction-fired copper red glaze by using XRD, Raman spectroscopy, EDX and UV-vis spectroscopy. As a result of XRD analysis, the glaze completely melted and amorphous glass appeared overall, and the characteristic peak of metal Cu was shown together. In addition, as a result of Raman analysis, the characteristic bands of CuO and $Cu_2O$ were shown together. The distribution of component elements was observed by EDX. As a result, copper(Cu) were distributed throughout the glaze. Thus, it was shown that copper red glaze appeared the best red coloration because metal Cu, CuO and $Cu_2O$ evenly existed throughout glaze in particle colloidal state. The chroma value of the copper red glaze was CIE $L^*$ 30.07, $a^*$ 13.65, $b^*$ 3.72. Wine-Red Solution was shown by Dark Graish Red coloration.

• 한국세라믹학회지
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• 제50권6호
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• pp.518-522
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• 2013

This study investigatesthe coloration mechanism by identifying the factor that affects thered coloration of copper red glazesin traditional Korean ceramics. The characteristics of the reduction-fired copper red glaze's sections are analyzed using an optical microscope, Raman spectroscopy, scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). The sections observed using an optical microscope are divided into domains of surface, red-bubble, and red band. According to the Raman micro spectroscopy analysis results, the major characteristic peak is identified as silicate in all three domains, and the intensity of $Cu_2O$ increases toward the red band. In addition, it is confirmed that the most abundant CuO exists in the glaze bubbles. Moreover, CuO and $Cu_2O$ exist as fine particles in a dispersed state in the surface domain. Thus, Cu combined with oxygen is distributed evenly throughout the copper red glaze, and $Cu_2O$ is more concentrated toward the interface between body and glaze. It is also confirmed that CuO is concentrated around the bubbles. Therefore, it is concluded that the red coloration of the copper red glaze is revealed not only through metallic Cu but also through $Cu_2O$ and CuO.

• 보존과학회지
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• 제27권1호
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• pp.31-40
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• 2011

동화(진사)는 구리를 원료로 하는 우리나라 고유의 적색 무기안료로써 고려와 조선시대에 도자기 채회 안료로 사용되었으나 생산과 발색이 어려워 소량의 작품만 전해진다. 조선시대의 고문헌에 의하면 동광석의 산지는 한국 전역에 걸쳐 수많은 지역이 알려져 있으며, 일부는 오늘날까지 가행 중이다. 한국에서 산출되는 가장 흔한 동광석 광물은 황동석($CuFeS_2$)과 공작석($Cu_2CO_3(OH)_2$)이며 지역에 따라 지표에서 쉽게 채취할 수 있는 곳도 많다. 따라서 우리나라는 과거에 동화 원료를 수급하는데 자원환경적 및 지리적인 이점을 확보했던 것으로 판단된다. 이 원광석을 대상으로 발색실험을 수행한 결과, 두 광석광물 모두 적색 발색력이 우수하였다. 중요한 발색원소는 구리이며, 구리 입자는 유약층에서 대부분 $5{\mu}m$ 미만의 입자 크기를 갖는 미세하고 균질한 분산 상태를 보인다. 또한 동화안료 내의 구리 함량과 입도 크기에 따른 분산특성은 선명한 적색도와 높은 투명도를 제어하는 가장 중요한 요소인 것으로 밝혀졌다.

• 자원환경지질
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• 제7권4호
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• pp.157-173
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• 1974

The Red Hill deposit of the Dongjom Copper Mine is the most promising deposit of the mine and under intensive exploration at present although there are eight more deposits of vein type. With total 2160m drilling of 9 holes completed and 400m drilling on two holes underway, the nature of the Red Hill deposit has come more clear. The copper content in the whole ore body is meager so far as the exploration done up to present indicates, but there are evidences that mineralization covers all over the granodiorite cupola at the Red Hill area. The petrological work and assay on the samples taken by the writers indicate that granodiorite rocks can be divided into fresh zone and alteration zone. Alteration zone consists of potassic and argillic zones accompanyied by silicification zone on basis of Lowell and Guilbert model Argillic zone has closely related with a mineralization in the Red Hill deposit. It has been cleared that the alteration acompanyied with the mineralization took place not only &long vertical fissures but also in the irregular lateral zone, the nature of which is unknown. Judging from the results of exploration and petrochemical study on the Red Hill deposit which is imbedded in a southern part of the granodiorite cupola, it can be concluded by the writer's opinion that the Red Hill deposit is possibly a porphyry copper deposit, because the shape of the ore body, mineral zoning and paragenesis and wall rock alteration resemble to those of typical porphyry copper deposits. It is the writers' opinion that more exploration work is required so as to evaluate the deposit.

• 자원환경지질
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• 제30권4호
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• pp.379-393
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• 1997

Geology of the Zbezkazgan copper deposit in Kazhkstan is mainly composed of Permian and Carboniferous sedimenary rocks in which copper minerals are mainly contained in grey sandstone of Carboniferous age. There are 28 layers of copper ore bodies in Zbezkazgan suite. Thickness of the ore bodies ranges from one to 35 meters, grade of the crude ore ranges from 2 to 5 wt % Cu and the extension of the orebodies is 5 to 7 km. Microscopic study on specimens from the Zbezkazgan ore deposit has exposed clues to understand the origin of this deposit. Alternatively deposited grey sandstone and red sandstone are mainly composed of quartz and feldspar grains. A big difference between the grey sandstone and the red sandstone is in grain size, the former is larger than the latter. Chalcocites as main copper minerals have cemented through grain boundary. It is assumed that quartz, feldspar and copper were derived from granitoid in which copper mineralization had taken place before exposing to weathering. The chalcocites were precipitated by a sudden change of geochemical condition (Eh, pH, temperature, etc.) of fluid which had carried quartz, feldspars, copper ions and sulphate during formation of grey sandstones. The copper ions and sulphate were stable in fluid during sedimentation of oxidation environment, however, the copper ions were no more stable at the reduced environment and changed to stable forms to precipitate copper minerals by reaction of copper ions and hydrogen sulfides. This chemical precipitation of copper minerals in the sandstone attributes to the assumption of hydrothermal origin on this sedimentary origined deposit.

• 한국임상수의학회지
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• 제15권2호
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• pp.455-459
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• 1998

Ten sheeps from one farm had sudden onset of anorexia, jaundice and hemoglobinuria and died within 3 days after showing clinical signs during 3 months period. Postmortom examination was performed on one case and copper concentrations in the livers kidney and serum of the necmpsied minim were analysed. Grossly, the conjunctive, subcutaneous tissue and abdominal fat were generally icteric. The liver was enlarged with yellowish orange in color. The kidney was enlarged with dark red in color and the urinary bladder was filled with dark red urine. Histopathologically, centrilobular hepatocellular necrosis, neutrophilic infiltrations bile stasis and aggregation of fine granules-laden macrophages in the portal area were noted in the liver. Most of the Bowman's spaces and renal tubules were filled with homogenous eosinophilic fluid. Extramedullary hematopoiesis was noted in the submandibular lymph node. Copper concentrations in serum, liver and kidney of the necropsied animal were 25.0, 2732.8 and 471.3 ppm respectively. Based on the gross and histopathological findings and the high copper concentrations in the organs, this case was diagnosed as chronic copper toxicosis. Possible etiology on this outbreak is also discussed.

• 자원환경지질
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• 제44권1호
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• pp.11-20
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• 2011

페루 남중부 아방까이 일대 수빠라우라 지역 산화동 산출지의 주변지질, 광상조사를 실시했다. 조사지역은 중생대 백악기의 석회암과 사암층을 기반암으로 하여 신생대 제 3기 화강섬록암, 토날라이트, 안산암질 반암 등이 기반암을 관입하고 있다. $N70^{\circ}W$ 주향과 $60^{\circ}NE$ 경사의 적색 사암 층리변을 따라 최대 30 cm 폭의 동광화작용이 관찰된다. 이는 반암형 시스템에서 일반적으로 발달하는 동광화작용과는 완전히 다른 변질작용, 광물조합, 산출특성 등을 가지며, 미시시피 밸리 유형에 해당하는 층준큐제형 퇴적암-모암 동광상 (Stratiform Sediment-hosted Copper deposits: SSC)에 대비될 수 있을 것으로 사료된다.

• Journal of Microbiology and Biotechnology
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• 제31권2호
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• pp.233-239
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• 2021

Cyanobacteriochromes (CBCRs) are phytochrome-related photoreceptor proteins in cyanobacteria and cover a wide spectral range from ultraviolet to far-red. A single GAF domain that they contain can bind bilin(s) autocatalytically via heterologous recombination and then fluoresce, with potential applications as biomarkers and biosensors. Here, we report that a novel red/green CBCR GAF domain, SPI1085g2 from Spirulina subsalsa, covalently binds both phycocyanobilin (PCB) and phycoerythrobilin (PEB). The PCB-binding GAF domain exhibited canonical red/green photoconversion with weak fluorescence emission. However, the PEB-binding GAF domain, SPI1085g2-PEB, exhibited an intense orange fluorescence (λabs.max = 520 nm, λfluor.max = 555 nm), with a fluorescence quantum yield close to 1.0. The fluorescence of SPI1085g2-PEB was selectively and instantaneously quenched by copper ions in a concentration-dependent manner and exhibited reversibility upon treatment with the metal chelator EDTA. This study identified a novel PEB-binding cyanobacteriochrome-based fluorescent protein with the highest quantum yield reported to date and suggests its potential as a biosensor for the rapid detection of copper ions.

• Journal of Biosystems Engineering
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• 제28권3호
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• pp.209-216
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• 2003

Red pepper calyx cutting devices using a impacting force by a rotational cutter were devised and tested to obtain the fundamental data for development of a calyx removal unit. Fresh red peppers with 80∼87%(w.b.) of initial moisture contents were used as experimental materials. Square and wire type of rotational cutters were used to cut the red pepper calyx and the fresh red peppers were fed into the device both manually and automatically. Three rotational speeds of 250, 500, 700rpm were selected for a square, and 1000, 1500, 1800rpm for a wire type cutter respectively. Four types of red pepper fixing unit were used in manual feeding. The cutting rate of the square type cutter was over 50% regardless the shape and specification of the cutter. For the wire type cutter, the copper wire and nylon chord could not be applied to cut the red pepper calyx because of the low cutting rate. But for the fine wire, the cutting rate was higher and the cutting mechanism was more steady than copper wire and nylon chord. The cutting rate of automatic feeding and wire type cutting unit was about 70% for all levels of the rotational speed. The cutting rate was highly related to the impacting point of red pepper in carrier box. To increase the cutting rate using the rotational cutter, a proper device and mechanism was required to keep the impacting point consistently.

• Journal of Microbiology and Biotechnology
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• 제24권4호
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• pp.534-544
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• 2014

The effects of microbial iron reduction and oxidation on the immobilization and mobilization of copper were investigated in a high concentration of sulfate with synthesized Fe(III) minerals and red earth soils rich in amorphous Fe (hydr)oxides. Batch microcosm experiments showed that red earth soil inoculated with subsurface sediments had a faster Fe(III) bioreduction rate than pure amorphous Fe(III) minerals and resulted in quicker immobilization of Cu in the aqueous fraction. Coinciding with the decrease of aqueous Cu, $SO_4{^{2-}}$ in the inoculated red earth soil decreased acutely after incubation. The shift in the microbial community composite in the inoculated soil was analyzed through denaturing gradient gel electrophoresis. Results revealed the potential cooperative effect of microbial Fe(III) reduction and sulfate reduction on copper immobilization. After exposure to air for 144 h, more than 50% of the immobilized Cu was remobilized from the anaerobic matrices; aqueous sulfate increased significantly. Sequential extraction analysis demonstrated that the organic matter/sulfide-bound Cu increased by 52% after anaerobic incubation relative to the abiotic treatment but decreased by 32% after oxidation, indicating the generation and oxidation of Cu-sulfide coprecipitates in the inoculated red earth soil. These findings suggest that the immobilization of copper could be enhanced by mediating microbial Fe(III) reduction with sulfate reduction under anaerobic conditions. The findings have an important implication for bioremediation in Cu-contaminated and Fe-rich soils, especially in acid-mine-drainage-affected sites.