• Bulletin of the Korean Chemical Society
• /
• v.27 no.9
• /
• pp.1439-1444
• /
• 2006

A $Cu^{2+}$ ion-selective membrane microelectrode has been fabricated from poly vinyl chloride (PVC) matrix membrane containing a new symmetrical hexadentate Schiff,s base 2-{1-(E)-2-((Z)-2-{(E)-2-[(Z)-1-(2-hydroxyphenyl)ethylidene]hydrazono}-1-methylpropylidene)hydrazono]ethyl}phenol (HDNOS) as a neutral carrier, Potassium tetrakis(4-chlorophenyl) borate (KTpClPB) as an anionic excluder and o-nitrophenyloctyl ether (NPOE) as a plasticizing solvent mediator. The microelectrode displays linear potential response in the concentration range of $1.0\;{\times}\;10^{-5}-1.0\;{\times}\;10^{-11}$ M of $Cu^{2+}$. The microelectrode exhibits a nice Nernstian slope of 25.9 ${\pm}$ 0.3 mV $decade^{-1}$ in the pH range of 3.1-8.1. The sensor has a relatively short response time in whole concentration ranges ($\sim$5 s). The detection limit of proposed sensor is $5.0\;{\times}\;10^{-12}$ M (320 pg/L), and it can be used over a period of eight weeks. The practical utility of the sensor has been demonstrated by using it as an indicator electrode in the potentiometric titration of $Cu^{2+}$ with EDTA. The proposed membrane electrode was used for the direct determining of $Cu^{2+}$ content in black and red pepper, and in waste water samples.

• Journal of Magnetics
• /
• v.21 no.2
• /
• pp.255-260
• /
• 2016

The health effects of environmental and occupational exposure to steady magnetic fields is a matter of concern. The aim of this study was to evaluate the hematologic effects of exposure to steady magnetic fields at the electrolysis unit of a Copper complex. The population under study was the workers of the electrolysis unit of the copper refinery. The average steady magnetic field in the exposure group was 2.5 mT. The blood indices of workers exposure to steady magnetic fields after adjusting for confounders showed decreased white blood cells (except neutrophils) and increase in the number and volume of platelets. Red blood cells did not show any significant difference. Exposure to steady magnetic fields even in proposed safe limits may have hematologic effects on humans. There is a necessity for more research about the safe doses of exposure to magnetic fields.

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.1
• /
• pp.112-121
• /
• 2015

In this study, Copper Azole (CuAz), a domestically available wood preservative for pressure treatment, was employed to perform an experimental research on its infiltration and decay properties in Japanese Red Pine. Test specimens were pressure-injected with CuAz-2 preservative to measure its preservative effectiveness, and then its impact on weight and mass losses. Furthermore, wood specimens were treated with CuAz-2 preservatives of various concentration levels before they were decayed with brown-rot-fungi in order to observe decay properties on light microscope (LM) and field emission scanning electron microscope (FE-SEM). As a result, untreated specimen by Fomitopsis palustris showed the mass loss of more than 40%, and the value of preservative effectiveness of CuAz-2 by indoor decay was $1,73-3.32kg/m^3$. The concentration levels of CuAz-2 preservative were shown to cause significant variations in terms of decay progresses in the cross section, radial section, and tangential section. By contrast, untreated specimens had underwent serious decays in early wood, late wood, longitudinal resin canals, and ray, which led to vertical destruction of wood texture. As for the radial section, ray tracheid, ray parenchyma cell, and window like pits were decayed and destroyed. In the case of tangential section, uniseriate rays and vertical resin canals were seriously decayed. In conclusion, this study indicates that the adequacy of the current CuAz injection amount should be reviewed in the domestic environment because there are significantly different decays at different decay conditions.

• Conservation Science in Museum
• /
• v.13
• /
• pp.13-22
• /
• 2012

The patterns for Jeogui and Pyeseul (patterns of the queen's ceremonial robe worn and a belt ornament covering knees in the front) as owned by National Museum of Korea were made in the early 20th century and both of them were colored on paper. Through a non-destructive analysis on pigments and dyes used on both the patterns, it was attempted to identify the coloring materials. As for the analysis of the coloring pigments, the XRF was used. As a result of the pigment analysis on the pattern for Jeogui, it is presumed that lead white was used for obtaining the white color, ink stick for black color, orpiment for yellow color, cinnabar and red lead for red color, copper and arsenical or a mixture of copper carbonate and orpiment for green color whereas brass seems to have been used for obtaining other colors. The pigments used for obtaining the colors of white, black, yellow and green on the pattern for Pyeseul are the same as those used on the pattern for Jeogui whereas the red pigments used on each of the two patterns are seen to be different. Although it may be difficult to identify the kinds of blue pigments that were used on the patterns for Jeogui and Pyeseul, a mixture containing lead white is presumed to be used as blue pigment. Also, as a result of the UV-Vis spectroscopic analysis performed on the blue hanji (traditional Korean paper) of the pattern for Jeogui, it was presumed to have been dyed with indigo.

• Journal of Fashion Business
• /
• v.23 no.2
• /
• pp.62-76
• /
• 2019

The importance of color is increasing in modern life and we call such present age that is 'color age'. These day that all areas of life are being getting fashionize, ordinary people as well as design specialist are required of culture and knowledge about color. Color design education is important curriculum at liberal arts course and in special design trainning course. Color expresses by hue, value and chroma in Munsell color system. But design spot is using mainly hue and tone color system. Therefore it is very important that educate tone concept in color design education. When think influence that increase of color, we must develop hue and tone color system in suitable for color design education. This research designed usable 'Hue and Tone 313 Colot System' for efficeint sensual color education. Also I designed 313 color papers with attached the Munsell notation which could reappear the spare color paper when needed. The 10 hues classification of this system are Red, Yellow Red, Yellow, Green Yellow, Green, Blue Green, Blue, Purple Blue, Purple, Red Purple. The 19 tones classification of this system are vivid, light, standard, deep, pale, soft, dull, dark, very pale, light grayish, medium grayish, dark grayish, very dark, off White, off Pale, off Light Gray, off Medium Gray, off Dark Gray, off Black. The special colors of this system are gold, silver and copper.

• Journal of Sensor Science and Technology
• /
• v.6 no.5
• /
• pp.407-413
• /
• 1997

The crystallized CuPc(copper phthalocyanine) film on a p-type <100> Si substrate is prepared at the substrate temperature of $300^{\circ}C$ by thermal evaporation. X -ray diffraction analysis showed the CuPc film to have a-axis oriented structure. For the measurement of photovoltaic characteristics of the CuPc/Si film and the Si substrate, a transverse current-voltage (I-V) curve is observed. In the dark, the Au/Si junction is shown to be ohmic contact. However, under illumination, a photovoltaic effect is not observed. The I-V curve in the dark indicates that the CuPc film on Si may form an ohmic contact. Since the CuPc film is a p-type semiconductor, the CuPc/p-Si junction has no barrier at the interface. Under illumination, the CuPc/Si junction shows a large photocurrent comparing with that of the wafer. The result indicates that the CuPc layer plays an important role in the photocarrier generation under red illumination (600 nm). The CuPc/Si film shows the photo voltaic characteristics with a short-circuit photocurrent ($J_{sc}$) of $4.29\;mA/cm^{2}$ and an open-circuit voltage ($V_{oc}$) of 12 mA.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2000.06a
• /
• pp.54-61
• /
• 2000

A method and results of classification of 4 types metallic wear debris were presented by using their color features. The color image of wear debris was used (or the initial data, and the color properties of the debris were specified by HSI color model. Particle was characterized by a set of statistical features derived from the distribution of HSI color model components. The initial feature set was optimized by a principal component analysis, and multidimensional scaling procedure was used for the definition of classification plane. It was found that five features, which include mean values of H and S, median S, skewness of distribution of S and I, allow to distinguish copper based alloys, red and dark iron oxides and steel particles. In this work, a method of probabilistic decision-making of class label assignment was proposed, which was based on the analysis of debris-coordinates distribution in the classification plane. The obtained results demonstrated a good availability for the automated wear particle analysis.

• Textile Coloration and Finishing
• /
• v.6 no.2
• /
• pp.40-46
• /
• 1994

In order to study the properties of cochineal color, variation of uv, visible spectra by pH, dyeing properties on the silk in several dyeing conditions and thermodynamic parameter were investigated. Cochineal colors had an unusual to pH, especially had instability in alkali condition. An increase in the dyeing temperature and in time resulted in an increase in the dye content of silk fibers. Concentration of cochineal color in the silk fiber was related to pH and the maximum exhaustion of cochineal colors showed at about pH 3. The value of apparent diffusion coefficients and standard affinities of dyeing increased with the increase of dyeing temperature. The standard heats of dyeing(ΔH°), variation of entropy(ΔS°) and activation energy(E/sub act/) were caculated to be -1.72kcal/mo1, -3.77cal/mo1ㆍdeg and 1.26kcal/mo1, respectively. Silk fabrics were dyed bright red by tin chloride, reddish purple by copper sulfate, and bluish gray by iron sulfate, respectively. Lightfastness of silk fabrics mordanted by metal ion was weak.

• Fashion & Textile Research Journal
• /
• v.6 no.2
• /
• pp.239-244
• /
• 2004

On the whole the various medium colors were developed by repeat dyeing with different colorants after dyeing with one colorant in case of natural dyeing. In this study, in order to obtain various colors on wool fabrics with Gardenia and Sappan wood colorants, pre-mordanting and combination dyeing were carried out. Gardenia and Sappan wood used as natural colorants for combination dyeing showed good miscibility in dye bath, Metal compounds containing alum, copper and iron were used for pre-mordants. The various medium colors such as yellow-red were obtained according to various metal compounds for pre-mordants and various mixing portion of these natural colorants. The surface reflactance spectra and color characteristics of wool fabrics by mordanting and combination dyeing were investigated.

• Journal of the Korean Chemical Society
• /
• v.15 no.4
• /
• pp.183-189
• /
• 1971

Stoichiometry of hydrazine-bromate reaction has been studied in acid media of varying compositions, elucidating the effects of bromide and chloride ions in sulfuric acid, perchloric acid, hydrochloric acid, and hydrobromic acid at varying concentrations of hydrogen ion and cupric ion. The study shows that the number of red-ox equivalent consumed by one mole of hydrazine becomes practically 4.00 if the concentrations of bromide and hydrogen ions are kept higher than 0.1M and 6M, respectively. The presence of copper tends to reduce the bromate consumption by hydrazine in an irregular manner, but such an effect becomes unimportant if the concentrations of bromide and hydrogen ions are kept sufficiently high.