• Title/Summary/Keyword: Copper(II)

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A Study on Finned Tube Used in Turbo Refrigerator(II) - on boiling heat transfer - (터보 냉동기용 핀 튜브에 관한 연구(II) - 비등 열전달에 관하여 -)

  • Han, Kyu-Il;Kim, Si-Young;Cho, Dong-Hyun
    • Journal of Fisheries and Marine Sciences Education
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    • v.5 no.2
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    • pp.119-127
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    • 1993
  • This work studies for heat transfer and pressure drop performance of integral inner and outer fin tubes, designed to enhance the heat transfer performance of smooth tubes for in recipro and turbo refrigerator or high performance compact heat exchangers. Eight different inner spiral fin copper tubes with integral fin at outside surfaces were employed to improve boiling heat transfer coeffcient. For comparison, tests were made using a plain tube having the inside diameter and an outside diameter equal to that at the root of the fins for the finned tubes. Pool boiling heat transfer is investigated experimentally and theoretically on single tube arrangement. The refrigerant evaporates at a saturation state of 1 bar on the outside tube surface heated by hot water. The refrigerant R11 ($CFCl_3$) was used at a pressure of $P_s=1bar$ as a convenient test fluid with a boiling temperature of $T_s=23.6^{\circ}C$. The observed heat transfer enhancement of boiling for finned tubes significantly exceeded that to be expected on grounds of increased area. The maximum Vapor - side enhancement(i.e., vapor - side heat transfer coefficient of finned tube/vapor - side coefficient for plain tube) was found to be around 4 at 1299fpm - 30grooves tube.

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Mineralogy and Iron Chemistry of Garnets and Clinopyroxenes in the Skarn Deposits, the Hambaek Geosyncline Belt, Korea (함백지향내의 스카른광상에서 산출되는 석류석과 단사휘석의 광물학과 철화학)

  • 최진범;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.2
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    • pp.119-128
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    • 1991
  • In the southern limb of the Hambaek geosyncline belt, large-scaled skarn deposits are developed in the Cambro-Ordovician sedimentary rocks of the Chosun Supergroup. They are the Sangdong tungsten deposit, Geodo iron-copper deposit, Yeonhwa I and II lead-zinc deposits, and Ulchin zinc-lead deposit, all of which are associated with various skarn minerals. Though different occurrences and paragenesis are found in different deposits, most skarn deposits always have skarns of garnet (andradite-grossular series) and clinopyroxene(heden-bergite-diopside series). Andradite and hedenbergite are Fe-dominant members, but show different oxidation states, that is, Fe3+ for andradite and Fe2+ for hedenbergite. According to iron chemistry and log([Fe/Al]gd/[Fe/Mg]cpx) derived from equilibrium reactions, the diopside-andradite and hedenbergite-grossular pairs suggest the oxidized state (dian type) and reduced state (hegro type), respectively. Among skarn deposits developed in the Hambaek geosynline, it can be classified that the Geodo and Yeonhwa I skarns are of dian type, while the Sangdong, Yeonhwa II, and Ulchin deposits are of hegro type. This classification is not applicable to all kinds of skarn deposits, but may be applicable to such deposits as are more controlled by oxygen fugacity than composition of skarn fluid.

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A Study on the Initial Maximum Value of Heat Flux, $q_{max}$ of Wool Fabrics (Part II) - The correlation between $q_{max}$ and chracteristic values - (양모 복지의 초기열류속최대치($q_{max}$)에 관한 연구(II) -직물 표면 형태 인자와의 상관성을 중심으로 -)

  • Choi Suk Chul;Jung Jin Soun;Chun Tae il
    • Journal of the Korean Society of Clothing and Textiles
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    • v.15 no.4 s.40
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    • pp.373-380
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    • 1991
  • In the previous paper, we already discussed about the factor effected upon the initial maximum value of heat flux ($q_{max}$). Thermal conductivity, thermal transmittance and surface air cavity of wool fabrics were examind and their correlation to the $q_{max}$ was also studied In this study, the other factor was examined which had on effect upon the qmaf of an objective measure of warm/cool feeling. It was studied that the qmax correlated to the surface sturucture parameters (compression, friction, smoothness, roughness, thickness and weight). It was concerned to the degree of warm/cool feeling when we touched hand on fabrics. We selected twenty sorts of pure wool woven fabrics for men's fall-winter cloth (all Wool). The conclusions are as follow; 1. There was a good correlation between the $q_{max}$ and the compression property. 2. The surface structure parameters, smoothness and roughness, made various effects on the $q_{max}$, when the samples touched on a thin copper plate. So, there was not a certain correla-tion to the $q_{max}$.

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Dyeing with Natural Dye (II) ―Dyeing of Silk with Sappan Wood― (천연염료에 의한 염색(II) ―소목에 의한 견염색―)

  • Nam, Sung Woo;Chung, In Mo;Kim, In Hoi
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.87-96
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    • 1995
  • Colorant concentrates are prepared by use of concentration method of colorants extracted from Sappan wood using met hanol. Dyeabilities and fastness properties of silk fabrics dyed with concentrate of Sappan wood are investigated.The results obtained are as follows; 1. The storage stability of colorant concentrate is poor as concentration is excess. 2. Because the colors of dyeings are different with mordants, aluminium acetate, copper acetate, chromium alum and tin chloride are used in order to obtain reddish color. 3. The optimum dyeing temperature and dyeing time are 6$0^{\circ}C$ and 60 min, respectively. 4. Dry cleaning fastness is very good, and light fastness and washing fastness are low. 5. The dyeing method is simple owing to usehess of colorant concentrate prepared without extraction of colorant every time.

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Wall-rock Alteration Relating to Tungsten-Tin-Copper Mineralization at the Ohtani Mine, Japan (대곡(大谷) W-Sn-Cu 광상(鑛床)의 열수변질작용(熱水變質作用))

  • Kim, Moon Young
    • Economic and Environmental Geology
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    • v.21 no.3
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    • pp.209-221
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    • 1988
  • The ore deposit of the Ohtani mine is one of repesentatives of plutonic tungsten-tin veins related genetically to acidic magmatism of Late Cretaceous in the Inner zone of Southwest Japan. Based on macrostructures of vein filling on the order of ore body, three major mineralization stages, called stage I, stage II, and stage ill from earliest to latest, are distinguished by major tectonic breaks. The alteration zories are characterized by specific mineral associations in pseudomorphs after biotite. The alteration zones can be divided into two parts, i. e. a chlorite zone and a muscovite zone, each repesenting mineralogical and chemical changes produced by the hydrothermal alteration. The chloritic alteration took place at the beginning of mineralization, and muscovite alteration in additions to chloritic alteration took place at stage II and ill. The alteration zones are considered to be formed by either of two alteration mechanism. 1) The zones are formed by reaction of the rock with successive flows of solution of different composition and different stage. 2) The zones are formed contemporaneously as the solution move outward. Reaction between the solution and the wall-rock results in a continuous change in solution chemistry. The migration of the successive replacement of the fresh zone$\rightarrow$the chlorite zone$\rightarrow$the muscovite zone may have transgressed slowly veinward, leaving metasomatic borders between the different zones.

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Metal Vapor Laser Research II. (금속증기레이저 연구 II)

  • 이재경;정환재;임기건;이형종;정창섭;김진승
    • Korean Journal of Optics and Photonics
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    • v.3 no.3
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    • pp.178-182
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    • 1992
  • An air-cooled discharge-heated copper-vapor laser system with its inter-electrode distance of 45 cm has been developed by utilizing an alumina ceramic plasma tube of 1.6 cm in diameter and 50 cm in lengih. For operating the laser, a dc high voltage power supply with output rating of 6 kV and 500 mA, a resonant charging circuitry consisting partly of an 1.8 H inductor assembly and a 5 nF storage capacitor, and a thyratron driver operating up to 7 kHz have also been developed. The present laser system starts lasing at the tube temperature of about $1350^{\circ}C$ and an maximum average output power of 0.7 W has been obtained at 12 kV, 4.5 kHz. 50 mbar of Ne buffer gas pressure, and at the tube temperature of $1460^{\circ}C$.

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Effect of medium coarse aggregate on fracture properties of ultra high strength concrete

  • Karthick, B.;Muthuraj, M.P.
    • Structural Engineering and Mechanics
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    • v.77 no.1
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    • pp.103-114
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    • 2021
  • Ultra high strength concrete (UHSC) originally proposed by Richards and Cheyrezy (1995) composed of cement, silica fume, quartz sand, quartz powder, steel fibers, superplasticizer etc. Later, other ingredients such as fly ash, GGBS, metakaoline, copper slag, fine aggregate of different sizes have been added to original UHSC. In the present investigation, the combined effect of coarse aggregate (6mm - 10mm) and steel fibers (0.50%, 1.0% and 1.5%) has been studied on UHSC mixes to evaluate mechanical and fracture properties. Compressive strength, split tensile strength and modulus of elasticity were determined for the three UHSC mixes. Size dependent fracture energy was evaluated by using RILEM work of fracture and size independent fracture energy was evaluated by using (i) RILEM work of fracture with tail correction to load - deflection plot (ii) boundary effect method. The constitutive relationship between the residual stress carrying capacity (σ) and the corresponding crack opening (w) has been constructed in an inverse manner based on the concept of a non-linear hinge from the load-crack mouth opening plots of notched three-point bend beams. It was found that (i) the size independent fracture energy obtained by using above two approaches yielded similar value and (ii) tensile stress increases with the increase of % of fibers. These two fracture properties will be very much useful for the analysis of cracked concrete structural components.

Effects of Antibiotics, Copper Sulfate and Probiotics Supplementation on Performance and Ammonia Emission from Slurry in Growing Pigs (사료에 대한 항생제, 황산동 및 생균제 첨가가 육성돈의 생산성 및 슬러리의 암모니아 발생에 미치는 영향)

  • Han, Y.K.;Shin, H.T.
    • Journal of Animal Science and Technology
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    • v.47 no.4
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    • pp.537-546
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    • 2005
  • An experiment was conducted to determine the effect of supplementation of chlortetracycline (CTC,110ppm), copper sulfate(Cu, 125ppm) and two levels of probiotics(Prob I, 0.04%, Prob II, 0.1%), Bacillus licheniformis and Bacillus subtilis) on growth performance, nutrient digestibility and manure characteristics in growing pigs. A total of 50 pigs that averaged 20.78$\pm$0.35kg BW and 50$\pm$2.3d age were allocated in a randomized block design with two pigs per pen and 5 pens per treatment. Pigs and feeders were weighed 10-days interval for the 40-d trials to determine ADG, ADFI and feed:gain ratio(F:G). Average daily gain, feed intake, feed/gain and nutrient digestibility were not improved(P>0.10) by the supplementation of CTC, Cu and two levels of probiotics. There were significant(P<0.05) Cu effects on digestibility of crude protein, and probiotics effects on digestibilities on organic matter, crude protein and energy between first 20 days and subsequent 20 days. Fecal concentrations of copper were highly increased(P<0.001) by the copper supplementation. Total bacteria and coliform counts were not altered by the supplementation of CTC, Cu and two levels of probiotics. Ammonia emission from slurry, measured during first 3 weeks, was reduced (P<0.001) in pigs fed diet with 125 ppm copper from copper sulfate. Results indicate that CTC, Cu and Probiotics supplementation had a little or not positive effect on grower pig performance under sound environmental conditions. Further studies may be warranted to investigate the effects of dietary copper-either reduced or in combination with dietary ammonia control agents-on the ammonia emission characteristics of swine manure.

Composting Methods for Pig Sludge and the Stabilized Investigation of Crop Cultivation (돈분의 자원화 퇴비 제조 방법 및 작물 재배 안전성 검정)

  • Oh, Tae-Seok;Kim, Chang-Ho
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.29 no.1
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    • pp.51-62
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    • 2009
  • This study was carried out development a new composting system to lower copper and zinc concentration in plg sludge compost and conduct an inquiry into the possibility of crop cultivation. The concentrations of nitrogen, phosphorus and pH averaged 4.4%, 6.3% and 7.57, respectively, which were higher concentrations than in commercial organic fertilizers, and the concentrations of copper and zinc averaged 805 and 1,704 mg/kg, respectively, which were beyond the heavy metal concentration limit in byproduct compost. Hydrated citric acid I lowered the concentrations of copper and zinc by 58% and 97%, respectively and hydrated oxalic acid II lowered the concentrations of copper and zinc by 48% and 56%, respectively in pig sludge compost. Lower concentrations of copper and zinc in pig sludge resulted from the enhanced hydrated-citric acid concentration in organic acid solution mixed with distilled water. The concentrations of copper and zinc were 330, and 41 mg/kg in the pig sludge treated with 100% hydrated citric acid. Agitation composting system stabilized the compost earlier than the stationary composting system, in which the stabilization condition was confirmed by higher temperature by $4^{\circ}C$ at highest temperature and 7 days earlier cooling down after highest temperature. The levels of germination index (G.I) 80 were obtained 15 and 20 days after composting in agitation and stationary composting system, respectively. The concentrations of copper and zinc were 2.4 and 4.26 mg/kg respectively in soils amended with pig sludge compost after removing process of heavy metals by citric acid, but 8.0 and 22.37 mg/kg, respectively in soils amended with Pig Sludge. The concentrations of heavy metals was highest in com cultivated in soils amended with pig sludge. The copper and zinc concentrations In corn leaves were 75.2 and 50.56 mg/kg respectively, which were 4 and 2 fold higher than the com cultivated in soils amended with pig sludge compost after heavy metal removing process by hydrated citric acid.

Selective determination of mercury (II) ion in aqueous solution by chemiluminescence method (화학발광법에 의한 수용액 중의 선택적 수은(II) 이온 정량)

  • Kim, Kyung-Min;Jang, Taek-Gyun;Kim, Young-Ho;Oh, Sang-Huyb;Lee, Sang-Hak
    • Analytical Science and Technology
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    • v.24 no.4
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    • pp.243-248
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    • 2011
  • A selective determination method of mercury (II) ion in aqueous solution by luminol-based chemiluminescence system (luminol CL system) has been developed. Determination of metal ions such as copper (II), iron (III), chromium (III) ion in solution by the luminol CL system using its catalytic role in the reaction of luminol and hydrogen peroxide has been reported by several groups. In this study, the catalytic activity of mercury (II) ion in the reaction of luminol and hydrogen peroxide was observed by the enhanced CL intensity of the luminol CL system. Based on this phenomenon, experimental conditions of the luminol CL system were investigated and optimized to determine mercury (II) ion in aqueous solution. While mercury (II) ion in mixed sample solution containing mercury (I) and (II) ions highly enhanced the CL intensity of the luminol CL system, the mercury (I) ion could not enhanced the CL intensity. Thus selective determination of the mercury (II) ions in a mixture containing mercury (I) and (II) ions could be achieved. Each concentration of mercury (I) and (II) ions in aqueous solution can be obtained from the results of the CL method that give the concentration of only mercury (II) ion and the inductively coupled plasma (ICP) method that give the total concentration of mercury ions. On the optimized conditions, the calibration curve of mercury (II) ion was linear over the range from $1.25{\times}10^{-5}$ to $2.50{\times}10^{-3}M$ with correlation coefficient of 0.991. The detection limit of mercury (II) ion in aqueous solution was calculated to be $1.25{\times}10^{-7}M$.