• 설비공학논문집
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• 제5권3호
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• pp.207-216
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• 1993

Experimental investigations have been carried out to find the effect of drag reduction caused by effective polymer additives in turbulent flows. The experiments were undertaken with a test section of 9.8mm pipe diameter and 3500 mm pipe length(L/D=357) in a closed loop, and Copolymer-X and Polyacrylamide(PAAM) were used as polymer additives for comparisons. The tests were carried out under different polymer concentrations, and the temperatures of the flow considered were $26^{\circ}C$, $60^{\circ}C$ at the flow velocity of 5.3 m/s. The rate of drag reduction obtained by Copolymer-X is found to be considerably higher than that of PAAM in turbulent flows. Copolymer-X is also found to be very reliable for mechanical degradation, which has not been the case in any other additives. It is concluded that Copolymer-X is considered to be one of the most effective agents as an additive especially for long time hydraulic transports. It is also found that polymer degradation in more likely at lower polymer concentrations in the turbulent flows.

• 설비공학논문집
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• 제12권3호
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• pp.251-257
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• 2000

District heating and cooling systems offer highly efficient energy utilization and maintenance by centralizing heat management. More pumping power, however, is required because the water has to travel long distance from heat source to the users. In the present study, a trace of drag reduction additives is added to the District Cooling system to achieve a significant drag reduction and save pumping power. Water-soluble polymers, surfactants, and environment-friendly degradable polymers are used as effective drag reducing additives. Time dependent percent drag reductions are compared for various additive solutions at 100 wppm concentration for different water velocity. Without as an anionic surfactant, copolymer was most effective in percent drag reduction. It is found that there exists an optimal condition when copolymer is mixed with SDS. An environment-friendly degradable polymer, xanthan gum, is found to be a significant drag reduction additive. Ice slurry systems, can give less pressure drops compared with chilled water system for certain condtions. Drag reduction additives were also effective for the ice slurry system.

• 펄프종이기술
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• 제45권4호
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• pp.21-26
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• 2013

The effect of esterified starch as surface sizing agent for inkjet printing paper has been evaluated and compared with oxidized starch. Also the influence of various additives including cationic poly-DADMAC, stearic acrylic copolymer, calcium chloride, and GCC was examined. Results showed that starch ester gave higher ink density than oxidized starch. Addition of poly-DADMAC improved water fastness. In general, low molecular weight poly-DADMAC performed better than high molecular weight one, and it was attributed to the fact that it gave more uniform film forming characteristics in surface sizing. Use of styrene acrylic acid copolymer increased hydrophobicity of the paper surface, but it did not increase the ink density. Use of GCC and calcium chloride had only marginal effect on printing quality.

• 마이크로전자및패키징학회지
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• 제11권3호
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• pp.9-15
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• 2004

PMSSQ (Poly Methyl Silsesquioxane)-based matrix에 BTMSE (Bis Tri Methoxy Silyl Ethane) 를 첨가한 low-k물질의 전기적 특성을 조사하였다. 우리는 절연체로 copolymer를 사용하여 금속-절연체 -실리콘 구조를 만들고 BTS 실험을 통하여 누설 전류와 파괴 시간을 측정하였다. 코 폴리머의 기공이 $30\%$ 이상이 되었을 때, 파괴 시간이 급속하게 감소되어 진다. 온도에 관하여 파괴 시간으로부터 코 폴리머를 통한 구리 확산의 활성화 에너지는 1.51eV가 측정되었다.

• 설비공학논문집
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• 제13권3호
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• pp.194-199
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• 2001

The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

• 폴리머
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• 제37권3호
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• pp.294-301
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• 2013

Polymersomes made of biodegradable triblock copolymers based on poly(fumaric acid-co-sebacoyl chloride)/PEG (PEG-co-P(FA/SC)-co-PEG) were prepared and studied in aqueous solutions. TEM confirmed the formation of vesicles in aqueous media. Aggregation behavior of the copolymers was studied by fluorescence spectroscopy of 8-anilino-1-naphthalenesulfonic acid, and the critical aggregation concentration (c.a.c.) of the copolymer was found to be ${\sim}26.2{\mu}M$ indicating desirable stability of the vesicles. Dynamic light scattering revealed that the size of the vesicles was distributed within the range of 170-270 nm. Turbidity measurements confirmed the relative short-term stability of the polymersomes. Carboxyfluorescein, a hydrophilic compound, was simply encapsulated in the vesicles during polymersome preparation. The release of encapsulant from the polymersomes at 25 and $37^{\circ}C$ lasted about 3 weeks, and the rate of release followed a first-order kinetics. The release is speculated to be primarily carried out through diffusion. These results confirm that these polymersomes are promising as controlled-release carriers of various drugs.

• 한국응용과학기술학회지
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• 제5권1호
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• pp.63-70
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• 1988

The quaternized compound of the copolymer between 2-diethylaminoethyl methacrylate and stearyl methacrylate (DSACC) was chosen as the mother resin for the water repellent of acrylics. The quaternized compound of 1-lauroyl dis (amino ethyl)-2-dodecyl imidazoline (LDDIC) was used to promote softening effect and hydrostatic pressure for the water repellent. The water repellent (EDUWC) obtained from the DSACC and LDDIC blended with waxes and emulsifiers improved the properties such as the water repellency, washable, tear strength and crease recovery when it was treated on the nylon fabrics with and without the resin. The reaction mechanism between the Nylon fiber and EDLWC was examined, and EDLWC was confirmed as the durable water repellent.

• Journal of Pharmaceutical Investigation
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• 제25권4호
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• pp.339-345
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• 1995

For the effective treatment of aphthous stomatitis, the matrix type mucoadhesive patches containing triamcinolone acetonide have been formulated. The drug layer was obtained by drying the polymer gel which was prepared with carbomer 934P, ammoniomethacrylate copolymer, titanium dioxide and polyethylene glycol 400. The effects of the content of additives on physical characteristics of the polymer gel and the drug layer were evaluated. The addition of carbomer increased the yield point and the zero-shear viscosity of polymer gel as well as the thickness, the water absorption ratio, the adhesive time and $T_{50%}$ of drug layer. The adhesive time and the water absorption ratio of drug layer were also improved by the addition of ammoniomethacrylate copolymer, but the addition of titanium dioxide had decreased the zero-shear viscosity of polymer gel and the adhesive time of drug layer.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2001년도 추계학술발표논문집
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• pp.87-94
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• 2001

Scale is agglomerate or thin film compounded of soluble salts in papermaking process. It causes many problems such as closing up pipelines, contaminating wire and felt, decreasing efficiency of additives and paper quality. In this study, physical factors related to forming scale in white water are determinated and optimum conditions are proposed. To control scale, ACP(Acrylacid Copolymer) was synthesized and compared with conventional chemicals such as EDTA, DTPA and STPP.

• 통합자연과학논문집
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• 제9권1호
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• pp.16-22
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• 2016

The optical and physical and characteristics of hydrogel ophthalmic lens polymerized with addition of 2,6-difluoropyridine, SiPc(silicon 2,9,16,23-tetra-tert-butyl-29H31H-phthalocyanine dihydroxide) and nanodiamond in the basic hydrogel material were evaluated. In particular, the utility of 2,6-difluoropyridine, SiPc and nanodiamond as a hydrogel ophthalmic lens material was investigated. 2,6-difluoropyridine, SiPc and nanodiamond were used as additives. And also, 2-hydroxyethyl methacrylate, acrylic acid, methyl methacrylate and a cross-linker EGDMA were copolymerized in the presence of AIBN as an initiator. The refractive index of 1.4348~1.4361, water content of 33.30~34.02%, UV-B transmittance of 4.77~67.50%, UV-A transmittance of 1.45~89.19% and visible transmittance of 32.12~92.21% were obtained. The results of hydrogel lens containing 2,6-difluoropyridine (add 5%) showed antibiosis for staphylococcus aureus. The produced copolymer is suitable for hydrogel soft ophthalmic lenses with antibiotic and anti-UV effect.