• Title/Summary/Keyword: Coordination Number

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Structural Study of Tetragonal-Ni1-xPdxSi/Si (001) Using Density Functional Theory (DFT) (Density Functional Theory (DFT)를 이용한 Tetragonal-Ni1-xPdxSi/Si (001)의 구조 연구)

  • Kim, Dae-Hee;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.482-485
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    • 2008
  • Tetragonal-$Ni_{1-x}Pd_x$Si/Si (001) structure was studied by using density functional theory (DFT). An epitaxial interface between $2{\times}2{\times}4$ (001) tetragonal-NiSi supercell and $1{\times}1{\times}2$ (001) Si supercell was first constructed by adjusting the lattice parameters of B2-NiSi structure to match those of the Si structure. We chose Ni atoms as a terminating layer of the B2-NiSi; the equilibrium gap between the tetragonal-NiSi and Si was calculated to be 1.1 ${\AA}$. The Ni atoms in the structure moved away from the original positions along the z-direction in a systematic way during the energy minimization. Two different Ni sites were identified at the interface and the bulk, respectively. The two Ni sites at the interface have 6 and 7 coordination numbers. The Ni sites with coordination number 6 at the interface were located farther away from the interface, and were more favorable for Pd substitution.

MAC Performance Improvement by Selective Use of DCF and PCF Protocols for IEEE 802.11 Wireless LANs (무선랜에서 망 상태에 따른 DCF와 PCF 프로토콜의 선택적인 사용을 통한 MAC 성능 향상)

  • Choi, Woo-Yong
    • Journal of Korean Institute of Industrial Engineers
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    • v.37 no.2
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    • pp.89-95
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    • 2011
  • The distributed coordination function (DCF) and point coordination function (PCF) protocols are the basic MAC protocols for legacy IEEE 802.11, IEEE 802.11a, IEEE 802.11b, IEEE 802.11e, IEEE 802.11g and IEEE 802.11n wireless LANs. When the DCF protocol is used for the various versions of IEEE 802.11 wireless LANs, the MAC performance seriously degrades due to the collisions among the stations (STAs) as more and more STAs attempt to transmit their data frames. On the other hand, the PCF MAC performance becomes poor when many STAs exist in IEEE 802.11 wireless LANs, however, only small number of STAs actually attempt to transmit their data frames. In this paper, we propose the algorithm for improving the MAC performance by selectively using the DCF and PCF protocols according to the state of IEEE 802.11 wireless LANs. Numerical examples are presented to show the MAC performance improvement by the selective use of the DCF and PCF protocols according to the network state.

The First-principles View of Nanometal Alloy Catalysts

  • Ham, Hyung Chul;Hwang, Gyeong S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.129-129
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    • 2013
  • Nanometal alloy catalysts have been found to significantly increase catalytic efficiency, compared to the monometallic counterparts. This enhancement can be attributed to various alloying effects: i) the existence of uniquemixed-metal surface sites [the so called ensemble (geometric) effect]; ii) electronic state changes due to metal-metal interactions [the so called ligand (electronic) effect]; and iii) strain caused by lattice mismatch between the alloy components [the socalled strain effect]. In addition, the presence of low-coordination surface atoms and preferential exposure of specific facets [(111), (100), (110)] in association with the size and shape of nanoparticle catalysts [the so called shape-size-facet effect] can be another important factor for modifying the catalytic activity. However, mechanisms underlying the alloying effect still remain unclear owing to the difficulty of direct characterization. Computational approaches, particularly the prediction using first-principles density functional theory (DFT), can be a powerful and flexible alternative for unraveling the role of alloying effects in catalysis since those can give us quantitative insights into the catalytic systems. In this talk, I will present the underlying principles (such as atomic arrangement, facet, local strain, ligand interaction, and effective atomic coordination number at the surface) that govern catalytic reactions occurring on Pd-based alloys using the first-principles calculations. This work highlights the importance of knowing how to properly tailor the surface reactivity of alloy catalysts for achieving high catalytic performance.

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Performance Improvement Method of IEEE 802.11 WLAN DCF (IEEE 802.11 WLAN에서의 DCF 성능개선 방안)

  • Park, doo-jin;Ko, dong-yub;Lim, seog-ku
    • Proceedings of the Korea Contents Association Conference
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    • 2007.11a
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    • pp.130-134
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    • 2007
  • DCF(Distributed Coordination Function) of IEEE 802.11 WLAN(Wireless Local Area Network) MAC Layer apply to CSMA/CA(Carrier Sense Multiple Access with Collision Avoidance) for solution of collision when the station try to access at the same time. But DCF happens falling performance as increasing a number of stations. In this paper, we suggest algorithm that improved performance in congestion. And we compare DCF, DCF+ and proposed algorithm respect to saturation throughput, delay, collision rate and drop rate using NS2(Network Simulator 2) simulation tool.

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performance analysis of the CSMA/CA protocol using stop-and-wait ARQ method in iwreless LANs (무선 근거리 통신망에서의 Stop-and-wait ARQ 방식을 사용하는 충돌회피 프로토콜 성능분석)

  • 김재현;이정규
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.21 no.5
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    • pp.1208-1220
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    • 1996
  • In this paper, the performance of a Carrier Sense Multiple Access/Collision avoidance (CSMA/CA) protocol using stop-and-Wait automatic Repeat reQuest, which is adapted as a draft standard in IEEE 802.11, is analyzed using a mathematical method based on a renewal theory, and simulation checks are performed, which confirm the goodness of our anlysis. In order to anlayze of CSMA/CA, we model that network is composed of finite populationand channel is slotted. And, we consider the CSMA/CA protocol as a hybrid protocol of 1-persistent CSMA and p-persistent CSMA protocol. As resuls of analysis, we have found that the throughput is degraded and packet delay is increased as the number of stations, Acknowledgement (ACK) length and Distributed coordination function Inter Frame Space (DIFS) length are increased.

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On The performance of Coordinated Random Beamforming Schemes in A Two-Cell Symmetric Interference Channel (두 셀 대칭적 간섭 채널환경에서 협력적 불규칙 빔형성 방법의 성능에 대한 연구)

  • Yang, Jang-Hoon;Chae, Hyun-Jin;Kim, Yo-Han;Kim, Dong-Ku
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.4A
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    • pp.318-324
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    • 2011
  • In this paper, three coordinated random beamforming (CRBF) schemes are analyzed in a two-cell symmetric interference channel. A simple partial coordination of RBF with base station selection (BSS) is shown to achieve the same average sum rate performance of CRBF with joint encoding (JE). To improve the sum rate performance further, we also propose a transmission mode selection (TMS) between the BSS and JE which is shown to have additional sum rate gain for the large number of users. Simulation results verify the eectiveness of the proposed CRBF schemes and accuracy of the proposed analysis.

Qos Enhancement in PCF of IEEE 802.11 through Simulation (시뮬레이션을 통한 IEEE 802.11 PCF의 QoS 향상에 관한 연구)

  • Kim Joong-jae;Kim Seong-cheol
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.8
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    • pp.1676-1682
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    • 2005
  • PCF(Point Coordination Function) of IEEE 802.11 MAC protocol is an access method oat generally has better performance under high offered load conditions. And it is also appropriate for sending data of time-limited applications. In this paper we consider the QoS(Quality of Service) enhancement method according to the change of nodes in the IEEE 802.11 WLAN. We assume that the un consists or QoS nodes and non-QoS nodes. The QoS nodes has a mechanism to support QoS. we can find the appropriate network parameters by many simulations. And the changes of network status are considered according to the number of nodes.

APPLICATION OF MULTIVARIATE DISCRIMINANT ANALYSIS FOR CLASSIFYING PROFICIENCY OF EQUIPMENT OPERATORS

  • Ruel R. Cabahug;Ruth Guinita-Cabahug;David J. Edwards
    • International conference on construction engineering and project management
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    • 2005.10a
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    • pp.662-666
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    • 2005
  • Using data gathered from expert opinion of plant and equipment professionals; this paper presents the key variables that may constitute a maintenance proficient plant operator. The Multivariate Discriminant Analysis (MDA) was applied to generate data and was tested for sensitivity analysis. Results showed that the MDA model was able to classify plant operators' proficiency at 94.10 percent accuracy and determined nine (9) key variables of a maintenance proficient plant operator. The key variables included: i) number of years of experience as equipment operator (PQ1); ii) eye-hand coordination (PQ9); iii) eye-hand-foot coordination (PQ10); iv) planning skills (TE16); v) pay/wage (MQ1); vi) work satisfaction (MQ4); vii) operator responsibilities as defined by management (MF1); viii) clear management policies (MF4); and ix) management pay scheme (MF5). The classification procedure of nine variables formed the general model with the equation viz: OMP (general) = 0.516PQ1 + 0.309PQ9 + 0.557PQ10 + 0.831TE16 + 0.8MQ1 + 0.0216MQ4 + 0.136MF1 + 0.28MF4 + 0.332MF5 - 4.387

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Joint Operation of ABS with Power Control and Derivation of an Effective ABS Ratio for LTE Hetnet Environments (LTE-A 이종망 환경에서 ABS와 Power Control의 동시적용과 ABS 비율 도출)

  • Sung, No-Hoon;Choi, Young-June;Jang, Ji-Woong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.40 no.12
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    • pp.2381-2388
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    • 2015
  • It has been known that interference occurs between macrocell ans small-cell base stations in a heterogeneous network (HetNet) of LTE-A. For solving this problem, 3GPP suggested eICIC (Enhanced Inter Cell Interference Coordination) that includes ABS (Almost Blank Subframe) and power control. This paper proposes to use ABS with power control and derives an effective ABS ratio as a function of the number of users and HeNBs. Through simulation, we confirm that integration of ABS and power control can mitigate interference than using ABS only. Furthermore, we verify that an effective ABS ratio is different depending on the number of users and HeNBs.

Factors Influencing Utilization of the Social Services for the Elderly (노인의 사회복지서비스 이용실태와 이용에 영향을 미치는 요인 -경기도 국민기초생활보장노인을 중심으로-)

  • Park, Kyung-Sook
    • Korean Journal of Social Welfare
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    • v.55
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    • pp.283-307
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    • 2003
  • The social services for the elderly have been expending in order to respond to the rapid speed of aging. However, low utilization, exclusion and duplication have been pointed out as significant problems in service utilization of the elderly. This study tried to find out the utilization patterns of social services for the elderly: what kinds of and how many social services the elderly receive from what kinds of and how many organizations, and factors influencing utilization of the social services. It surveyed the entire population of the public assistance recipient elderlies at Kyonggi province in 1999. The results show that duplication is not so significant problem as the low utilization of social services. However, the fact that more than forty five percent of the elderly receives social services from more than two organizations requires the efforts for service linkage and coordination in social service delivery system. The factors, which have relatively big influence on the number of organizations which the elderly use for each social service, were sex and age among the predisposing factors, "living alone" and place for residency among the enabling factors and the number of illness, Activities of Daily Living, Instrumental Activities of Daily Living and inconvenience of housing among the needs factors. These results call for expansion of social services for the elderly especially in the way of achieving distribution balance between the rural and urban area and activation of case management practice and local association of social service delivery agencies for service linkage and coordination.

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