• 제목/요약/키워드: Conversion Factor

검색결과 976건 처리시간 0.027초

High Efficient and Stable Dye-sensitized Solar Cells (DSSCs) with Low Melting Point Glass Frits

  • 김종우;김동선;김형순
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.42.2-42.2
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    • 2011
  • $TiO_2$ films were modified by adding a glass frit as a light scattering particle and applied to an anode electrode in dye-sensitized solar cells (DSSCs) to enhance the adhesion between $TiO_2$ and fluorine doped transparent oxide (FTO). Low melting point glass frits at contents of (3 to 7wt%) were added to the nano crystalline $TiO_2$ films. The light scattering properties, photovoltaic properties and microstructures of the photo electrodes were examined to determine the role of the low glass transition temperature ($T_g$) glass frit. Electrochemical impedance spectroscopy, Brunauer-Emmett-Teller method and scratch test were conducted to support the results. The DSSC with the $TiO_2$ film containing 3wt% low Tg glass frit showed optimal performance (5.1%, energy conversion efficiency) compared to the $TiO_2$-based one. The photocurrent density slightly decreased by adding 3wt% of the frit due to its large size and non conductivity. However, the decrease of current density followed by the decrease of electron transfer due to the large frit in $TiO_2$ electrode was compensated by the scattering effect, high surface area and reduced the electron transfer impedance at the electrolyte-dye-$TiO_2$ interface. The stability of the photo electrodes was improved by the frit, which chemically promoted the sintering of $TiO_2$ at relatively low temperature ($450^{\circ}C$).

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저온에서 Hydropolymer를 이용한 ZnO 나노입자 염료 감응형 태양전지 (ZnO Nanoparticle Based Dye-Sensitized Solar Cells Devices Fabricated Utilizing Hydropolymer at Low Temperature)

  • 권병욱;손동익;박동희;양정도;최원국
    • 한국재료학회지
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    • 제20권9호
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    • pp.483-487
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    • 2010
  • To fabricate $TiO_2$ nanoparticle-based dye sensitized solar cells (DSSCs) at a low-temperature, DSSCs were fabricated using hydropolymer and ZnO nanoparticles composites for the electron transport layer around a low-temperature ($200^{\circ}C$). ZnO nanoparticle with 20 nm and 60 nm diameter were used and Pt was deposited as a counter electrode on ITO/glass using an RF magnetron sputtering. We investigate the effect of ZnO nanoparticle concentration in hydropolymer and ZnO nanoparticle solution on the photoconversion performance of the low temperature fabricated ($200^{\circ}C$) DSSCs. Using cis-bis(isothiocyanato)bis(2,20 bipyridy1-4,40 dicarboxylato) ruthenium (II) bis-tetrabutylammonium (N719) dye as a sensitizer, the corresponding device performance and photo-physical characteristics are investigated through conventional physical characterization techniques. The effect of thickness of the ZnO photoelectrode and the morphology of the ZnO nanoparticles with the variations of hydropolymer to ZnO ratio on the photoconversion performance are also investigated. The morphology of the ZnO layer after sintering was examined using a field emission scanning electron microscope (FE-SEM). 60 nm ZnO nanoparticle DSSCs showed an incident photon-to-current conversion efficiency (IPCE) value of about 7% higher than that of 20 nm ZnO nanoparticle DSSCs. The maximum parameters of the short circuit current density ($J_{sc}$), the open circuit potential ($V_{oc}$), fill factor (ff), and efficiency ($\eta$) in the 60 nm ZnO nanoparticle-based DSSC devices were 4.93 mA/$cm^2$, 0.56V, 0.40, and 1.12%, respectively.

X-treeDiff+ 기반의 프로그램 복제 탐지 (Program Plagiarism Detection based on X-treeDiff+)

  • 이석균
    • 전자공학회논문지CI
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    • 제47권4호
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    • pp.44-53
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    • 2010
  • 컴퓨터 프로그래밍 교육에서 프로그램 복제는 프로그래밍 학습 효율을 저해하는 심각한 요인이다. 본 논문에서는 학생들이 프로그래밍 과제의 무분별한 복제를 방지하기 위해 유사 또는 동일 프로그램을 탐지하는 기법을 제안한다. 지문법이나 스트링 매칭을 기반으로 하는 기존의 탐지 기법과는 달리, 우선 C 프로그램을 파싱하여 문법요소를 엘리먼트로 하는 XML 문서로 변화시킨 후 XML 문서의 변화탐지 알고리즘인 X-treeDiff+를 실행시켜 그 차이를 분석하는 방법을 취한다. 이때 대응의 정도를 나타내는 유사도와 두 문서의 차이로 제시되는 일련의 편집연산인 편집스크립트를 프로그램 복제의 관점에서 분석하여 복제 여부에 대한 판단을 하게 된다. 편집스크립트의 분석은 두 프로그램 간의 변환 과정을 유추할 수 있게 하여 기존 방법들과는 달리 사용자는 과제의 성격이나 복제의 정도를 고려한 정성적인 판단이 가능하다는 장점이 있다.

An Evaluation of the Repetitive Tooth Bleaching with Nonthermal Atmospheric Pressure Plasma

  • Nam, Seoul Hee;Kim, Gyoo Cheon;Hong, Jin Woo
    • International Journal of Oral Biology
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    • 제41권4호
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    • pp.243-251
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    • 2016
  • This study was undertaken to achieve a high bleaching efficacy with plasma, through longer application and reparative bleaching processes, by different shade evaluation methods. Extracted human teeth were divided into 6 groups (n=10). All teeth were treated in pairs. Low concentration of 15% carbamide peroxide (CP) was applied, with and without plasma, for 10, 20, and 30-min tooth bleaching, respectively. The bleaching procedure was repeated once daily for four days. The teeth were maintained in a moist environment provided by artificial saliva. The Vitapan Classical shade guide and Commission Internationale de L'Eclairage (CIELAB) color system were collectively used to measure the bleaching efficacy. Color evaluation was statistically analyzed using Student t-test and one-way analysis of variance (ANOVA) complemented by Tukey's test. Combining the plasma with 15% CP showed significantly greater color changes compared to bleaching without plasma (p<0.05). A high bleaching efficacy with plasma is proportional to the repetitive application and the treatment time. A 30-min application with plasma provided the best bleaching. Repetitive bleaching showed lower probability of color relapse of the bleached tooth. The color change by shade guide correlated with the changes in CIELAB color system. A value of 1 color change units (CCU) conversion factor for overall color change (${\Delta}E$) values comparisons was 3.724 values. The two measuring methods provide a more accurate correspondence of color change. The repetitive and longer application for tooth bleaching, combined with plasma, has a strong bleaching effect and produces whiter teeth.

다결정 실리콘 태양전지 구조 최적화에 관한 연구 (A Study on the Optimization of Polysilicon Solar Cell Structure)

  • 이재형;정학기;정동수;이종인
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2011년도 춘계학술대회
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    • pp.702-705
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    • 2011
  • 고효율 다결정 태양전지 제작의 방향을 제시하기 위해 PC1D 프로그램을 이용하여 전, 후면 재결합 속도, 소수 캐리어 확산거리, 접합깊이, 에미터 층 면저항, 후면 전계층이 미치는 영향을 조사하였다. 최적화된 전지 파라미터는 후면 재결합 속도 1000 cm/sec, 베이스 층에서의 소수 캐리어 확산거리 50 [${\mu}m$], 전면 재결합 속도 100 [cm/sec], 에미터 층 면저항 $100{\Omega}/\Box$, 후면 전계층 두께 및 도핑 농도는 각각 0.5 [${\mu}m$]와 $5{\times}10^{19}\;cm^{-3}$로 조사되었다. 특히 19.8% 이상의 변환효율을 얻기 위해서는 베이스층의 확산거리가 가장 중요한 파라미터임을 알 수 있었다.

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TiO2/ITO 나노구조체 광전극의 합성 및 염료감응 태양전지에의 적용 (Synthesis of TiO2/ITO Nanostructure Photoelectrodes and Their Application for Dye-sensitized Solar Cells)

  • 김대현;박경수;최영진;최헌진;박재관
    • 한국세라믹학회지
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    • 제48권1호
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    • pp.94-98
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    • 2011
  • A Sn-doped $In_2O_3$ (ITO) nanowire photoelectrode was produced using a simple metal evaporation method at low synthesis temperature (< $540^{\circ}C$). The nanowire electrodes have large surface area compared with that of flat ITO thin film, and show low electrical resistivity of $5.6{\times}10^{-3}{\Omega}cm$ at room temperature. In order to apply ITO nanowires to the photoelectrodes of dye-sensitized solar cell (DSSC), those surfaces were modified by $TiO_2$ nanoparticles using a chemical bath deposition (CBD) method. The conversion efficiency of the fabricated $TiO_2$/ITO nanostructure-based DSSC was obtained at 1.4%, which was increased value by a factor of 6 than one without ITO nanowires photoelectrode. This result is attributed to the large surface area and superior electrical property of the ITO nanowires photoelectrode, as well as the structural advantages, including short diffusion length of photo-induced electrons, of the fabricated $TiO_2$/ITO nanostructure-based DSSC.

KVN 관측모드별 대전상관기의 상관결과 고찰 (A STUDY ON THE RELIABILITY OF THE DAEJEON HARDWARE CORRELATOR FOR THE KVN OBSERVATION MODES)

  • 오세진;노덕규;염재환;오충식;이상성;정동규;김효령;정현수
    • 천문학논총
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    • 제31권2호
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    • pp.11-19
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    • 2016
  • This paper presents the results of test observations toward a point source, 4C39.25, for observation modes with various bandwidths and numbers of IF streams in order to examine a reliability of the Daejeon hardware correlator performance for correlating VLBI (Very Long Baseline Interferometry) data obtained with the several observation modes of the KVN (Korean VLBI Network). We used a DiFX software correlator (DiFX) as a reference, for investigating the output visibilities from the Daejeon corelator. It is found that the band shapes of the output visibilities from two correlators are similar to each other and the correlated flux density for each baseline obtained from the Daejeon hardware correlator is lower by 3 - 7% than that from the DiFX. The flux difference is attributed to the limitation of FPGA resources and the difference of fringe rotation algorithm of the Daejeon hardware correlator. The conversion factor, 0.93 ~ 0.97, is proposed for future correlation with the Daejeon hardware correlator.

필름 및 tissue equivalent 팬톰을 이용한 NEC LINAC 6 MVX 소조사면에 대한 선량분포 측정 (Measurement of Dose Distribution in Small Fields of NEC LINAC 6 MVX Using Films and Tissue Equivalent Phantoms)

  • Suh, Tae-Suk;Park, Dong-Rak;Choe, Bo-Young;Yoon, Sei-Chul;Jang, Hong-Seok;Park, Il-Bong;Kim, Moon-Chan;Bahk, Yong-Whee;Shin, Kyung-Sub
    • 한국의학물리학회지:의학물리
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    • 제4권2호
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    • pp.9-17
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    • 1993
  • 본 논문의 목적의 NEC LINAC 6 MVX 선의 소조사면에 대한 선량분포를 복잡한 물팬톰 및 ion chamber대신 film 및 고체 물팬톰을 이용하여 간단히 측정하고 분석하는 시스템을 개발하는 데 있다. 단일 선속측정을 위하여 필름과 고체 물팬톰이 이용되었으며, 측정된 데이타는 percent depth dose (PDD), off-axis ratio (OAR) 등을 포함하며, 한변이 1, 2, 3cm의 정사각형 소조사면에 대하여 측정이 이루어 졌다. 또한 Output factor측정은 ion chamber로 측정되었으며, 필름에 의하여 측정된 PDD, OAR 등은 ion chamber측정기로 측정된 값과 비교 검토되었다. 필름으로 부터 측정된 PDD값으로 부터 환산식을 이용하여 tissue maximum ratio (TMR) 값을 얻었으며, 본 실험에서 얻어진 TMR, OAR 값들은 같은 에너지를 나타내는 Philips LINAC의 선량 데이타와 유사한 결과를 보여주었다. 고체 물팬톰 및 필름을 이용한 소조사면 측정은 간편하고도 유용한 방법이었으며, 특히, 자체 개발된 필름팬톰은 뇌정위적 방사선 수술을 위한 OAR 선량을 측정하는 데 유용하였다.

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제3세대 LPLI 엔진 연소실내 스월유동 및 희박연소 특성 해석 (Analysis of Cylinder Swirl Flow and Lean Combustion Characteristics of 3rd Generation LPLI(Liquid Phase LPG Injection) Engine)

  • 강건용;이진욱
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권1호
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    • pp.26-33
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    • 2007
  • The intake swirl motion, as one of dominant effects for an engine combustion. is very effective for turbulence enhancement during the compression process in the cylinder of 2-valve engine. Because the combustion flame speed is determined by the turbulence that is mainly generated from the mean flow of the charge air motion in intake port system. This paper describes the experimental results of swirl flow and combustion characteristics by using the oil spot method and back-scattering Laser Doppler velocimeter (LDV) in 2-valve single cylinder transparent LPG engine using the liquid phase LPG injection. For this. various intake port configurations were developed by using the flow box system and swirl ratios for different intake port configurations were determined by impulse swirl meter in a steady flow rig test. And the effects of intake swirl ratio on combustion characteristics in an LPG engine were analyzed with some analysis parameters that is swirl ratio. mean flow coefficient, swirl mean velocity fuel conversion efficiency. combustion duration and cyclic variations of indicated mean effective pressure(IMEP). As these research results, we found that the intake port configuration with swirl ratio of 2.0 that has a reasonable lean combustion stability is very suitable to an $11{\ell}$ heavy-duty LPG engine with liquid phase fuel injection system. It also has a better mean flow coefficient of 0.34 to develope a stable flame kernel and to produce high performance. This research expects to clarify major factor that effects on the design of intake port efficiently with the optimized swirl ratio for the heavy duty LPG engine.

일차 배양한 백서 피부섬유아세포에서 Paraquat 독성에 미치는 SOD 와 Catalase 의 영향 (Effects of Copper / Zinc-Containing Superoxide Dismutase (Cu, Zn-SOD) and Catalase on Paraquat-Induced Injury in Primary Cultured Rat Skin Fibroblast)

  • 차종희;유의경
    • 대한화학회지
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    • 제38권1호
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    • pp.74-79
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    • 1994
  • Cu, Zn-SOD 억제제인 diethyldithiocarbamate(DDC)가 paraquat(PQ)에 의한 세포독성에 미치는 영향을 배양한 백서 섬유아세포에 DDC(30 mM)를 전처치하여 PQ를 100${\mu}M$이 되게 첨가해 배양하여 생존한 세포를 Carmichael 등의 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-tetrazolium bromide(MTT)법에 의해 측정한 결과 DDC 전처치 대조군과 DDC 전처치 PQ 첨가군 사이에 유의한 세포생존율의 차이는 없었다. Catalase 억제제인 3-amino-1,2,4-triazol(AT)를 전처치하여 PQ를 100${\mu}$M을 첨가하고 배양한 섬유아세포의 생존율을 MTT법에 의해 측정한 결과 AT 전처치 PQ 첨가군에서 유의한 세포생존율의 감소를 나타냈다. 섬유아세포를 PQ(200${\mu}$M)로 처치한 후 Cu, Zn-SOD를 첨가하여 생존한 세포수를 각각 MTT법에 의해 측정한 결과 Cu, Zn-SOD 첨가로 인한 세포생존율의 유의한 변화는 없었다. PQ 처치군에 catalase 첨가로 PQ처리 대조군에 비하여 생존한 세포수가 유의하게 증가되었다. 이상의 실험결과 일차배양한 백서 섬유아세포를 AT로 전처리하면 PQ독성이 증가되고, catalase 첨가로 독성이 감소되며, DDC전처치나 Cu, Zn-SOD첨가로 PQ에 의한 세포생존에 미치는 영향이 적은 점으로 미루어, PQ 독성은 surperoxide보다 과산화수소농도와 더 밀접한 연관성이 있는 것으로 추정된다.

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