• 전기화학회지
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• 제2권4호
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• pp.209-212
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• 1999

H-형의 분리 셀을 사용하여 중성 및 실온의 온화한 조건에서 조절 전위법 음전극 반응에 의한 nitroarene화합물들의 환원 짝지음 반응으로 높은 수율의 azobenzene유도체를 합성하였다. Pb또는 Pt cathode와 Pt anode를 사용하여 메탄을 용액 하에서 cyclic voltammetry에 근거하여 각 반응의 최적의 반응 조건을 결정한 후 반응을 실행하였으며, 대부분의 경우 환원 짝지음 반응은 치환기의 성질과 위치에 영향을 받지 않고 높은 수율로 성공적인 결과를 얻을 수 있었다.

• 한국분말재료학회지
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• 제24권5호
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• pp.351-356
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• 2017

Tin dioxide nanoparticles are prepared using a newly developed synthesis method of plasma-assisted electrolysis. A high voltage is applied to the tin metal plate to apply a high pressure and temperature to the synthesized oxide layer on the metal surface, producing nanoparticles in a low concentration of sulfuric acid. The particle size, morphology, and size distribution is controlled by the concentration of electrolytes and frequency of the power supply. The as-prepared powder of tin dioxide nanoparticles is used to fabricate a gas sensor to investigate the potential application. The particle-based gas sensor exhibits a short response and recovery time. There is sensitivity to the reduction gas for the gas flowing at rates of 50, 250, and 500 ppm of $H_2S$ gas.

• 대한화학회지
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• 제53권2호
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• pp.159-165
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• 2009

2-Amino-5-Substituted-1,3,4-Oxadiazoles의 합성은 비분활된 셀에서 포텐셜 전기분해의 제어하에 백금전극의 세미카바존 전기적 산화로부터 수행되었다. 이것은 유기화학 합성분야에서 환경적으로 양호한 방법이다. 아세트산 및 아세트니트릴, 무수용매와 리튬 과염소산염 이 전기적 산화에서 전기분해을 위하여 사용 되어졌다. 생성물은 IR, $^1H$-NMR, $^{13}C$-NMR 그리고 원소분석을 통해 구조분석 하였다.

• 대한화학회지
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• 제21권4호
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• pp.276-283
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• 1977

산성용액중에서 백금음극을 사용하여 중크롬산이온의 환원을 전위주사법 및 정전위전해에 의하여 검토하였다. 지지전해질로서 황산나트륨(pH 1.5∼4.0)을 사용한 비완충용액중의 중크롬산칼륨의 분극곡선은 3단파가 생기며 첫째파 및 둘째파의 파고는 각각 크롬(Ⅵ)농도 및 수소이온의 활동도에 비례하나 셋째파는 어느 것에도 비례하지 않았다. 첫째 및 둘째 peak이 전류는 전위주사속도(${\nu}$)에 비례하나 셋째 peak는 50mV/sec이하의 늦은 주사속도에서 ${\nu}^{1/2}$에 비례하였다. 정전위전해에 의하면, 크롬(Ⅵ)의 환원은 셋째 peak보다 더 base이고 초기 pH가 약 2.3 이상이 되면 완전히 억제되었다. 그러므로 이 세 peak는 각각 $Cr_2O_7^{\to}Cr^{3+},\;2H^+{\to}H_2$ 및 음극피막의 형성으로 간주하였다.

• 한국분말재료학회지
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• 제13권2호
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• pp.108-111
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• 2006

Aluminum hydroxides were synthesized by a simple electrolytic reaction of aluminum plates. The aluminum hydroxide, boehmite (AlO(OH)), was predominantly formed in the application of electrical potential at and above 30V, while the mixture of bayerite ($Al(OH)_3$) and boehmite (AlO(OH)) phases were formed below 20V. The boehmite has a clear fibrous structure controlled on nanometer scale. On the contrary, the bayerite consists of the typical hourglass or semi-hourglass shaped coarse crystals as a result of aggregation of various crystals stacked together. The specific surface area of the boehmite nanofiber was markedly high, approaching at about $302\;m^2/g$.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.428-429
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• 2006

Aluminum hydroxides were synthesized by a simple electrolytic reaction of aluminum plates. The aluminum monohydroxide, boehmite(AlO(OH)), was predominantly formed by the application of an electrical potential above 30V, while the mixture of the bayerite$(Al(OH)_3)$ and boehmite(AlO(OH)) phases were formed below 20V. The boehmite has a clear fibrous structure which is controlled on a nanometer scale. On the contrary, the bayerite consists of the typical hourglass or semi-hourglass shaped coarse crystals as a result of an aggregation of the various crystals stacked together. The specific surface area of the boehmite nanofiber was remarkably high, reaching about $300m^2/g$.

• 한국표면공학회지
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• 제15권3호
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• pp.146-151
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• 1982

The electrochemical reaction behavior of nickel electrode of the nickel-cadium battery system in potassium hydroxide solution has been studied by cyclic voltammetry, controlled potential electrolysis and X-ray diffraction method. It has been found that the reaction mechanism of positive nickel electrode for charging was assumed to be proten transfer step with a rate controlling diffusion process and char-ging state of positive electrode was amorphous $\beta$-NiOOH.

• 한국표면공학회지
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• 제21권3호
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• pp.95-102
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• 1988

The anodic oxidation of aniline in aqueous sulfuric acid solution on a platinum was studied. To examine of mechanism of this reaction, the date were obtained during controlled potential electrolysis, aided by computer system. The reaction mechanism was assumed the electrochemical-chemical-electrochemical(ECE) mechanism. We obtained the result that the intial charge transfer step proceeds through a radical cation, and this radical cation were bound cation led to may type of dimer in which p-aminodiphenylamine was de-electronated again to give the polymer.

• 전기화학회지
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• 제12권1호
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• pp.54-60
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• 2009

The redox characteristics of 2-arylaldehydehydrazono-3-phenyl-5-substituted-2, 3-dihydro-1, 3, 4-thiadiazoles (1a-h) have been investigated in nonaqueous solvents such as 1, 2-dichloroethane (DCE), dichloromethane (DCM), acetonitrile (AN), Tetrahydrofuran (THF), and dimethylsulfoxide (DMSO) at platinum electrode. Through controlled potential electrolysis, the oxidation and reduction products of the investigated compounds had been separated and indentified. The redox mechanism had been suggested and proved. It had been found that all the investigated compounds were oxidized in two irreversible one-electron processes following the well-known pattern of The EC-mechanism; the first electron loss gives the corresponding cation-radical which is followed by proton removal from the ortho-position in the N-phenyl ring forming the radical. The obtained radical undergoes a second electron uptake from the nitrogen in the N = C group forming the unstable intermediate (di-radical cation) which undergoes ring closure forming the corresponding cation. The formed cation was stabilized in solution through its combination with a perchlorate anion from the medium. On the other hand, these compounds are reduced in a single two-electron process or in a successive two one-electron processes following the well known pattern of the EEC-mechanism according to the nature of the substituent; the first one gives the anion-radical followed by a second electron reduction to give the dianion which is basic enough to abstract protons from the media to saturate the (C = O) bond.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.696-700
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• 1993

Gold bonding wire of 0.076 mm in diameter used in semiconductor industry, is dissoved in aqua regia. The solution is then evaporated to near dryness several times with a few drops of HCl added to prepare the final sample solution in 5% HCl. The gold matrix is separated from trace impurities by controlled potential deposition. The whole electrolysis has been carried out inside a clean bench. An optimum potential is found to be +0.25 V to give more than 99.9% Au matrix removal with better than 90 analytes remaining in the electrolyte solution. Isotope dilution calibration is employed to get the best accuracy and precision. Analytical results are presented with determination limits of the analytical method.