• 설비공학논문집
• /
• 제13권7호
• /
• pp.637-646
• /
• 2001

VOC(Volatile Organic Compound) removal characteristics in continuous flow reactors have been numerically investigated. The photocatalytic reaction have been simulated with the binding constant and the reaction rate constant obtained from experimental data for the constant-volume batch reactor, and then VOC abatement in continuous flow reactors with the same conditions as those of batch reactor has been analyzed. The standard 4\kappa-\varepsilon$ model and mass conservation equation have been employed for numerical calculation, and heterogeneous reaction rate has been used in terms of the boundary condition of the conservation equation. in the case of the continuous flow reactor, reaction characteristics have been estimated with various inlet velocities and with different number of baffles. The result shows that the concentration distribution and flow patterns are strongly affected by the inlet velocity, and that with the increased inlet velocity, VOC removal rate is increased, while removal efficiency is decreased. This result may be useful in the design of reactors with improved VOC removal efficiency.

• Bulletin of the Korean Chemical Society
• /
• 제31권1호
• /
• pp.250-252
• /
• 2010

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 2003년도 유체기계 연구개발 발표회 논문집
• /
• pp.115-120
• /
• 2003

In this work, a continuous-flow micro-PCR system is systematically designed. From the numerical simulation based on the finite volume method, adapting oneself to a new environmental temperature without an external temperature controller is shown to be possible and a cooler as well as a heater is shown to be necessary to obtain three individual temperature zones for polymerase chain reaction. In addition, appropriate geometry of a heat sink for the cooler is determined by using a compact modeling method, the porous medium approach.

• 전기학회논문지
• /
• 제56권3호
• /
• pp.561-565
• /
• 2007

We propose glass and PDMS (polydimethylsiloxane) chips for DNA amplification with continuous-flow PCR (polymerase chain reaction). The PDMS microchannel was fabricated using a negative molding method for sample injection. Three heaters and sensors of ITO (indium-tin-oxide) thin films were fabricated on glass chip. ITO heaters and sensors were calibrated accurately for the temperature control of the liquid flow. ITO heater generated stable heat versus applied power. ITO sensor resistance was changed linearly versus temperature increase as a RTD (resistance temperature detector) sensor. As a result, we enable precision temperature control of continuous-flow PCR chip. Using the continuous-flow PCR chip DNA plasmid pKS-GFP 720 bp was successfully amplified.

• 센서학회지
• /
• 제7권5호
• /
• pp.319-326
• /
• 1998

연속 기체흐름계에서 감지막으로 $Na_2CO_3$와 $MCO_3$ ($M=Cs_2,K_2,Li_2,Ca$)를 입힌 $Na^+$ 이온 전해질 센서가 $CO_2$ 가스를 감지할 때 anode반응을 도출하였다. 흔히 사용되는 전기화학 센서에 대해 일반적으로 알려진 전체 전극반응인 $MCO_3=MO+CO_2$ 반응은 위의 $Na^+$이온 전해질 센서에는 적합한 반응이 아니었다. 따라서 anode 반응은 전체cell 내의 ionic balance를 유지하기 위해 전해질과 감지막 계면에 이온교환반응을 첨가시킴으로써 도출할 수 있었으며 anode반응은 $Na_2CO_3$ 및 감지막의 금속($M^{++}$) 이온이 포함된 산화물이 참가하는 반응임을 알 수 있었다. 이와 같이 도출된 전극반응으로부터 구한 EMF와 일시 기체흐름계에서의 출력 EMF와의 차이를 아울러 검토하였다. 이러한 출력에서의 차이는 $CO_2$와 $O_2$의 분압과 분위기가스와 전극물질과의 비가역반응에 기인됨을 알았다.

• 소성∙가공
• /
• 제8권3호
• /
• pp.237-244
• /
• 1999

The purpose of this research is for the development of a new type forging equipment. H.C.G.(Hyundai Continuous Grain-Flow), by using two virtual build-up tools, rigid viscoplastic FEM and downsized plasticine experiment. This forging method consists of only vertical pressuree. Therefore, high quality crankshafts can be forged with this method as it can maintain a continuous grain flow. The factors considered in the development of equipment are die geometry for flawless deformed shape, die reaction forces, stress/strain distributions and continuous material flow. We carried out several numerical simulations and downsized plasticine experiments for the proper design of the forging equipment. The validity of those simulation results is confirmed by checking with the actual test results. Based on these simulation results, the proper design of the H.C.G. forging equipment is enabled.

• 한국환경과학회지
• /
• 제4권1호
• /
• pp.91-103
• /
• 1995

The reaction rate, equilibrium, and flow injection analysis methods were fundamentally evaluated for the determination of aqueous ammonia. The selected indophenol blue method was based on the formation of indophenol blue in which ammonium ion reacted with hypochlorite and phenol in alkaline solution. In the optimized reaction condition, the reaction followed 1st order reaction kinetics and the final product was stable. The absorbance measurements before and after the equilibrium were utilized for the reaction rate and equilibrium methods. The reaction rate methods, based on the relative analytical signals for the possibility of eliminating interferents, were shown to have good linear calibration curves but the detection limit and the calibration sensitivity were poorer than those in the equilibrium method. The detection limits were 32-49 pub and 24 pub for the reaction rate and equilibrium methods, respectively In the flow injection analysis, the absorbance was measured before the equilibrium reached and thus resulted in 30% reduction of calibration sensitivity. However, the detection limit was 11 ppb, indicating that the peak-to-peak noise for the blank was remarkably improved. Compared to the manual methods, the optimized experimental condition in a closed reaction system reduced the blank absorbance and the inclusion of ammonia from the atmosphere was prevented. In addition, highly reproducible mixing of sample and reagents and analytical data extracted from continuous recording showed excellent reproducibility.

• 한국결정성장학회지
• /
• 제27권5호
• /
• pp.268-273
• /
• 2017

In this study, nickel hydroxide crystalline powders were synthesized by continuous reaction in the taylor fluid flow using nickel chloride, nickel sulphate and sodium hydroxide as raw materials and compared with those prepared by a conventional batch type reaction. The crystallinity of nickel hydroxide prepared by the Taylor fluid flow reaction was higher than that of nickel hydroxide obtained by batch reaction. The particle size of nickel hydroxide decreased about 2.5 to 3.6 times, and the specific surface area was increased.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 1999년도 춘계학술대회논문집
• /
• pp.107-110
• /
• 1999

The purpose of this research is for the development of a new type forging equipment H.C.G(Hyundai Continuous Grain-flow) by using two virtual build-up tools rigid viscoplastic FEM and downsized plasticine experiment. This forging equipment consists of consecutive horizontal and vertical pressure while the traditional forging method consists of only vertical pressure. Using this method high quality crankshafts can be forged as it can maintain a continuous grain flow. The factors considered in the development of equipment are die geometry for flawless deformed shape die reaction forces stress/strain distributions and continuous material flow. We carried out several numerical simulations and downsized plasticine experiments for the proper design of the forging equipment. The validity of those simulation results is confirmed by checking with the actual test results. Based on these simulation results the proper design of the H.C.G for ging equipment is enabled.

• Journal of Microbiology and Biotechnology
• /
• 제17권9호
• /
• pp.1533-1537
• /
• 2007

In this study, in order to develop a continuous production process of lactosucrose in a packed-bed reactor, Sterigmatomyces elviae ATCC 18894 was selected and mutated. The mutant strain of S. elviae showed 54.3% higher lactosucrose production than the wild type. Reaction conditions such as temperature, pH, substrate concentration and flow rate were also optimized. Under optimized reaction conditions ($50^{\circ}C$, pH 6.0, 25% sucrose and 25% lactose as substrate, flow rate 1.2 ml/min), the maximum concentration of lactosucrose (192 g/l) was obtained. In a packed-bed reactor, continuous production of lactosucrose was performed using S. elviae mutant immobilized in calcium alginate, and about 180 g/l of lactosucrose production was achieved for 48 days.