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The Effects of Deposition Temperature and RF Power on the Plasma Assisted Chemical Vapor Deposition of TiCN Films (증착온도와 RF Power가 TiCN박막의 플라즈마 화학증착에 미치는 영향)

  • 김시범;김광호;김상호;천성순
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.323-330
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    • 1989
  • Wear restance titanium carbonitride (TiCN) films were deposited on the SKH9 tool steels and WC-Co cutting tools by plasma assisted chemical vapor deposition (PACVD) using a gaseous mixture of TiCl4, CH4, N2, H2 and Ar. The effects of the deposition temperature and RF(Radio Frequency) power on the deposition rate, chlorine content and crystallinity of the deposited layer were studied. The experimental results showed that the stable and adherent films could be obtained above the deposition temperature of 47$0^{\circ}C$ and maximum deposition rate was obtained at 485$^{\circ}C$. The deposition rate was much affected by RF power and maximum at 40W. The crystallinity of the deposited layer was improved with increasing the deposition temperature and RF power. The TiCN films deposited by PACVD contained much chlorine. The chlorine content in the TiCN films was affected by deposition conditions and decreased with improving the crystallinity of the deposited layer. The deposited TiCN films deposited at the deposition temperature of 52$0^{\circ}C$ and RF power of 40W had an uniform surface with very fine grains of about 500$\AA$ size. The microhardness of the deposited layer was 2,300Kg/$\textrm{mm}^2$.

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Lipid Contents Characteristics of Gene Accumulate in Rice (벼 유전자 집적에 따른 지질함량 특성)

  • 윤경민;홍순관
    • Korean Journal of Plant Resources
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    • v.15 no.3
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    • pp.177-187
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    • 2002
  • In our experiment, selected mutants were used which showed not only the phenotype of a specific unpolished rice but also phenotypes of EM 40, LO 1050, and TAL 214. Reciprocal crosses between the mutants were conducted to select strains which would have more quantity of lipids than before. The constitution of fatty acid was also tested to figure out nutritional aspects of the mutants. In the crossing between EM 40 mutants and mutants (LO 1050) having a thick aleurone layer, the expression of EM 40 mutants has no relation with the thickness of the aleurone layer. And the lipid content of new F$_2$ strains through the crossing is 4.15 %. The lipid content is larger than those of the parents including Kinmaze and in other crossings of this experiment. This is attributed to the fact that the new F$_2$ strains are the products of the crossing between genes responsible for the size of buds, where lipid is accumulated, and genes accountable for the thickness of the aleurone layer. In the crossing between EM 40 mutants and TAL 214 mutants, lipid content of the new F$_2$ strains is 3.8 %, higher than 2.92 % of TAL 214 mutants. But the degree of lipid increase is smaller than in two other crossings. This is probably because genes expressing the phenotypes of TAL 214 affect the size of EM 40, which gets smaller. The aleurone layer of the new F$_2$ strains is 12 $\mu\textrm{m}$ thicker than the layer of TAL 214 mutants, but 6 $\mu\textrm{m}$ thinner than that of parents (LO 1050) having a thick aleurone layer. This seems to be affected by the size of a microscope. The phenotype of the new F$_2$ strains appears to be similar to that of TAL 214. The lipid content of the new F$_2$ strains is 3.85 %, larger than 2.92 % of TAL 214 and 3.01 % of LO 1050. The increase may be due to the aleurone layer of LO 1050. And the size of the bud of the unpolished rice, though it is not big enough like that of LO 1050, seems to be affected by the accumulation of genes in the thick aleurone layer. The accumulation may contribute to the increase in the content of lipid. When it comes to the constitution of fatty acid, there is little difference between parents like Kinmaze and the new F$_2$ strains. But oleic acid increases while linoleic acid decreases. And the decrease in the linolenic acid seems to contribute to the increase in lipid content. This fact also raises the possibility that genes accountable for specific phenotypes could change the quality of rice if the genes are accumulated. Now, experiments on strains which have large lipid content in EM 40 type 1(ge-1, 3.68 %), EM type 2(ge-2, 2.91 %), thick aleurone layer(4.63 %), and starch layer(3.44 %) are under way to figure out the effects of gene accumulation. These experiments are likely to present the ways for increasing the lipid content.

A Study on the Measurement of Volumetric Water Content Using WCR in Final Cover Layer of Landfill (Water Content Reflectometer(WCR)을 이용한 매립지반 최종 복토층의 체적 함수비 측정에 관한 연구)

  • Kim Kyung-Chul;Hwang Koou-Ho;Lee Song
    • Journal of the Korean Geotechnical Society
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    • v.21 no.6
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    • pp.147-154
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    • 2005
  • This study deals with the calibration of low-frequency water content reflectometer for measuring the volumetric water content of soils in landfill final cover layer, and the validity of calibrations was evaluated by electrical conductivity and index properties of the soils. Linear calibrations concerning volumetric water content to WCR period provided good agreement with the data. Analysis of the calibration data indicates that the slope of the calibration decreases as the electrical conductivity of the soil increases. Lower slopes correspond to soils with greater clay content, organic content, liquid limit, and plasticity index, which typically have higher electrical conductivity. It could be well explained that WCR can operate in a lower frequency range.

Microstructure and Flexural Strength of Hardmetals

  • Hayashi, Koji
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.119-198
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    • 1994
  • The characteristics of various important microstructural factors of WC-base hard- metals (cemented carbides) such as the amount of Co metal binder phase, the carbide grain size, the microstructural defects acting as a fracture source, the solid solubility of tungsten in the binder phase affected by the carbon content, the precipitation of $Co_3W$, the domain size of binder phase, the formation of ${\beta}-free$ layer or Co-rich layer and CVD or PVD coated layer, and the effects of these factors on the flexural strength of the hardmetals are reviewed.

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Bran structure and gelatinization properties of upland waxy rice starch (밭벼 찹쌀의 겨층 구조와 전분의 호화 성질)

  • Kim, Sung-Kon
    • Applied Biological Chemistry
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    • v.34 no.1
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    • pp.75-76
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    • 1991
  • Bran structure and gelatinization property of upland and lowland japonica waxy brown rice were compared. Dimension, weight and number of aleurone layer were similar between upland(Nonglimna 1) and lowland(Shinsunchalbyeo) rices, but the aleurone layer and pericarp of upland rice were thicker. Water uptake rate of upland rice at $60^{\circ}C$ was lower than that of lowland one. There was no difference in intrinsic viscosity between two rice starches. Upland rice starch had lower onset temperature, narrower gelatinization temperature and lower water content lot gelatinization compared with lowland rice starch.

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Thermal Insulation Property due to Internal Air-layer Content of Warm Multi Layer Materials by using Numerical Analysis (수치해석을 이용한 다겹보온자재의 내부공기층 함유에 따른 보온 특성)

  • Chung, Sung-Won
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.4
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    • pp.97-103
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    • 2012
  • This study investigates thermal insulation properties of multi layer materials depending on thickness of air layers. Numerical analysis on the heat flow of different insulating materials was conducted to identify whether their temperature distributions demonstrate the reduced rate of heat transfer conclusively or not. Analytical model is divided into two categories. One is to distinguish temperature distribution of the air-layer materials from the non-air layer ones. The other is to compare the efficacy between eight-layered insulating materials with no air-layer contained and three-layered insulating materials which include an air-layer definitely. In the latter case, the identical thickness is assigned to each material. The effect of thermal insulation by including an air-layer is verified in the first analytical model. The result of the second model shows that the insulation of the eight-layered materials is coterminous at the three-layered ones with an air-layer and the thermal insulation of the two materials is imperceptible. The benefits of cost and energy saving are anticipated if air-layers are efficiently incorporated in multi layer insulating materials in a greenhouse.

Changes in Contents of Nutritional Components and Eating Quality of Brown Rice by Pericarp Milling (과피층 제거에 따른 현미의 이화학특성 및 현미밥의 식감변화)

  • Kim, Hye-Won;Oh, Sea-Kwan;Kim, Dae-Jung;Yoon, Mi-Ra;Lee, Jeong-Heui;Choi, Im-Soo;Kim, Yeon-Gyu;Cha, Kil-Nam
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.1
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    • pp.35-40
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    • 2012
  • In this study, the effect of degree of milled wax layer on compositions (protein and total dietary fiber content), Alkali Digestion Value (ADV), and texture (hardness, stickiness, toughness, and adhesiveness) with brown rice was investigated. For all the rice cultivars, $Baegjinju$, $Keunnun$, $Samkwang$, and $Seolgaeng$, protein content decreased significantly as the degree of pericarp milling increased ($p$<0.05). Total dietary fiber (TDF) content for $Keunnun$ (9.56%${\rightarrow}$8.09%) and $Samkwang$ (8.05%${\rightarrow}$7.06%) significantly decreased with the degree of removed wax layer. ADV was not affected by being removed wax layer, but ADV of $Samkwang$ was increased from 3.56 to 6.78. As the degree of removed wax layer increased (0%${\rightarrow}$10%), hardness and toughness of cooked brown rice were decreased but stickiness and adhesiveness was increased. The ratio of adhesiveness to hardness was increased with decreased wax layer of brown rice. Accordingly, It suggests that the regulation of the wax layer with brown rice was effected texture of cooked brown rice. The milling technology in wax layer of brown rice is that might be thought to be very useful in rice processing industry.

Application of Low-hydrogenated Diamond-like Carbon Film to Mo-tip Field Emitter Array (낮은 수소 함유량을 갖는 유사 다이아몬드 박막의 몰리브덴 팁 전계 방출 소자 응용)

  • Ju, Byeong-Kwon;Jung, Jae-Hoon;Lee, Yun-Hi;Kim, Hoon;Oh, Myung-Hwan
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.76-79
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    • 1999
  • Low-hydrogenated DLC films were coated on the Mo-tip FEAs by 'layer-by-layer' process based on the plasma-enhanced CVD method. The hydrogen content in the DLC film deposited by the 'layer-by-layer' process was appeared to be remarkably lowered through SIMS analysis. Also, the low-hydrogenated DLC-coated Mo-tip FEA showed good potentiality for FED applications in terms of turn-on voltage, emission current, emission stability and light emitting uniformity.

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Design of Oral Patches for the Treatment of Aphthous Stomatitis : Drug Layer (아프타성 구내염 치료용 구강 패취의 설계 : 약물층)

  • Lee, Kyu-Hyun;Park, Eun-Seok;Chi, Sang-Cheol
    • Journal of Pharmaceutical Investigation
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    • v.25 no.4
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    • pp.339-345
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    • 1995
  • For the effective treatment of aphthous stomatitis, the matrix type mucoadhesive patches containing triamcinolone acetonide have been formulated. The drug layer was obtained by drying the polymer gel which was prepared with carbomer 934P, ammoniomethacrylate copolymer, titanium dioxide and polyethylene glycol 400. The effects of the content of additives on physical characteristics of the polymer gel and the drug layer were evaluated. The addition of carbomer increased the yield point and the zero-shear viscosity of polymer gel as well as the thickness, the water absorption ratio, the adhesive time and $T_{50%}$ of drug layer. The adhesive time and the water absorption ratio of drug layer were also improved by the addition of ammoniomethacrylate copolymer, but the addition of titanium dioxide had decreased the zero-shear viscosity of polymer gel and the adhesive time of drug layer.

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Formation of Thicker hard Alloy Layer on Aluminum Alloy by PTA Overlaying with Metal Powders (플라스마 아크 紛體肉盛法에 의한 Al 合金의 硬化厚膜 合金化層의 形成)

  • ;;中田一博;松田福久
    • Journal of Welding and Joining
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    • v.11 no.2
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    • pp.74-85
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    • 1993
  • Effect of Si metal powders addition with the plasma transferred arc(PTA) overlaying process on characteristics of the alloyed layer in aluminum alloy(A5083) has been investigated. The overlaying conditions were 175-250A in plasma arc current, 500mm/min in travel speed, the 5-20g/min in powder feeding rate. Main results obtained are summarized as follows. 1)Sufficient size of molten pool on surface of base metal was required for forming an alloyed layer; in a fixed travel, the formation of alloyed layer with clear and beautiful surface depend upon the plasma arc current and powder feeding rate; the greater plasma arc current and the smaller powder feeding rate were, the better bead was formed. Optimum alloyed conditions by which an excellent alloyed bead obtained was 225A in plasma arc current. PTA process made it possible to form an alloyed layer with up to 67wt% Si. 2)Microstructure in the alloyed layer was in accord with prediction from the Al-Si phase diagram 3)The hardness of the alloyed layer increased in proportion to Si content. 4)As volume fraction of primary Si increased, the specific wearness of the alloyed layer was significantly improved. However, no further improvement was found when the volume fraction was greater than about 30%. 5)Utilizing the PTA process, a crack free alloyed layer with maximum hardness of about Hv 310 could be obtained.

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