Biological oxygen demand (BOD) as a stream water quality indicator was monitored monthly in the Mankyeong and Dongjin river basins from June 2001 to October 2002 to evaluate water qualitied as well as to get the information on the water quality management strategy in Semangeum reclamation areas. BOD in the Mankyeong river was 5.4mg/L in average during the survey and increased after the inflow of Iksan tributary, which was contaminated with livestock wastewater. BOD of Iksan tributary was maintained at 5.4 mg/L before joining the Wanggung tributary, however, that in the downstream was increased to 13.6 mg/L in average due to the inlet of the livestock wastewater. Meanwhile, BOD of Dongjin river was the average of 2.8 mg/L during the survey periods but it showed 3.5 mg/L when Jungeup tributary which was contaminated with sewage and industrial wastewater joined into the main stream. BOD in both Mankyeong and Dongjin rivers decreased in 2002 as compared to that in 2001.
The water quality at the Nakdong River stream was surveyed for 3 years from 1978 to 1980 at quarterly intervals of January, April, June and October at 12 sites along the main stream from Sangju to Imhaejin and at 2 sites of Geumho and Nam River tributaries. The overall results are summarized as follows: 1) The levels of dissolved oxygen in the Geumho River tributary on the basis of three-year average were 0.7 ppm in January, 1.3 ppm in April, 4.0 ppm in July and 0.8 ppm in October. BOD concentrations in the same period were 91 ppm in January, 37 ppm in April, 6 ppm in July and 24 ppm in October. The water of Geumho River was so highly contaminated that the water seems to be unsuitable for any type of water use. 2) The relatively clean water in the upstream of the main Nakdong River was rapidly polluted by the highly contaminated water of Geumho tributary. That is, dissolved oxygen and BOD at Hwawon site right after junction of the tributary were 10.4, 8.8 ppm in January, 5.8, 6.5 ppm in April, 6.3, 3.2 ppm in July and 7.0, 5.3 ppm in October, respectively. The values of turbidity, ammoniacal nitrogen and electrical conductivity were also observed to be quite high.
This study was investigated the pollutant load, contamination properties, pollution condition of the fine parts of tributary, the influence of Nakdong river watershed and etc. in the tributaries. The contaminated tributaries were that among the Kumho and Nam river or were too far from site of water quality monitoring stations, regularly. As a result, the water quality level was almost similar between Nam and Kumho River, except for certain parameter including TN(Total Nitrogen), Chl-a(Chlorophyll-a) and SS(Suspended Solid) in which Kumho river were 20~120%. The point discharge load(kg/day) and load density ($kg/day/km^2$) of tributaries were different the pollution level according to the flow-rate ($m^3/sec$) and stream influence area($km^2$), and the difference of these was observed highly at Nam river. Specific contamination investigation of tributaries in Nam and Kumho river watershed was conducted from two to nine points of the fine parts of tributaries depending on the confluence sites and shapes. This result observed high at the Dalseocheon and Uriyeongcheon, respectively. Beside, the pollutant load contribution rate of Nakdong watershed was high about 10% at the Dalseocheon and Uiryeongcheon. This was due to the differences of the environments about the industrial complex, metropolis residence property, agricultural cultivation, livestock pen and the downstream of non-point source.
Kim, Youn-Tae;Kim, Yu Lee;Woo, Nam-Chil;Hyun, Seung Gyu
Journal of Korean Society on Water Environment
/
v.22
no.4
/
pp.666-671
/
2006
Effects of a rainfall event (July 28, 2005) on the hydrochemical characteristics of the Jungrang river, the biggest tributary of the Han river, was investigated. Significant spatial variations in the hydrochemical characteristics were observed. At JR2 location, concentrations of T-N and T-P were relatively low indicating occurrence of active oxidation in the stepped drop structure. At JR3 location, concentrations of Na, K, Cl, $NH_4-N$ and EC were elevated suggesting increased discharge from the nearby waste-water treatment plant and tributaries. The rain event diluted major dissolved ion concentrations in the river by 12~52%. The $NO_3-N$ levels were preserved during the rain then increased about twofold after rainfall, suggesting increased discharge of nitrate-contaminated groundwater. Heavy metals including Cd, Co, Cr, Cu and Pb were not detected in all water samples and the leachates from surface sediment samples. Concentrations of Fe, Mn, Al and Zn were below the Korean Drinking Water Guideline. Results of this study suggested that establishment of water-quality monitoring protocols describing temporal and spatial variations in parameters sensitive to rainfall events, relatively steady factors, and contaminant sources is required.
The Dalsung copper-tungsten mine in the Taegu area, Korea was closed in 1975 and may be the sources of the heavy metal contamination in the tributary system and soil-plant system due to the mine drainage derived from the mine wastes and tailings. To examine the degree and extent of heavy metal contamination in the vicinity of Dalsung mine area, stream water and soil samples were taken and analyzed for heavy metals by ICP-AES and AAS. Highly contaminated soils are found near the Lower Tunnel No.0 ranging up to $1760{\mu}g/g$ As, $2060{\mu}g/g$ Cu, $1120{\mu}g/g$ Pb and 346 ${\mu}g/g$ Zn. From the results of the sequential extraction methods for the metal speciation, the heavy metals in soils may be derived from soil parent materials and acid mine drainage. With the processes for the heavy metal removal, most of the heavy metal ions in the acid mine drainage are removed by being exchanged with Ca ions held by the bentonite, hydroxyapatite and calcium hydoxide.
Ham, Jong-Hwa;Yoon, Chun-G.;Koo, Won-Seok;Kim, Hyung-Chul;Shin, Hyun-Bhum
Journal of The Korean Society of Agricultural Engineers
/
v.46
no.5
/
pp.141-153
/
2004
Wetland system is widely accepted as one of natural water purification systems around the world for nonpoint sources pollution control. Constructed wetlands have become a popular technology for treating contaminated surface and waste water. In this study, the field experiment to reduce nonpoint source pollution loadings from polluted stream waters using wetland system was performed from June 2002 to March 2004. Four wetlands were used and the size of each one was 0.8ha. Water of Dangjin stream flowing into Seokmun estuarine reservoir was pumped into wetlands. Inflow and hydraulic residence time of the system was 500 $m^3$/day∼1,500 $m^3$/day, 2∼5 days, respectively. After 2 year operation, plant-coverage of the wetlauds was about 70% from bare soil surface at initial stage . Average water quality of the influent was $BOD_5$ 4.17 mg/L, TSS 18.45 mg/L, T-N 4.32 mg/L, and T-P 0.30 mg/L. The average removal rate of $BOD_5$, TSS, T-N and T-P during the study period was 5.6%, 46.6%, 45.7%, and 54.8%, respectively. Organic ($BOD_5$) removal rate was low and the reason might be low influent concentration. Wetland removal rate of T-P was about 10% higher than T-N. Performance of the experimental system was compared with existing data base (NADB), and it was within the range of general system performance. Overall, the wetland system was found to be adequate for treating polluted water stream with stable removal efficiency even during the winter period. Most of the nonpoint source pollutions from watershed are transported by streams or ditches, and they could be controled by constructed wetland system before entering the lake or reservoir.
An abnormal mono-specific bloom of the cyanobacterium Microcystis aeruginosa had developed at a specific location (transitional zone, monitoring station of Hoenam) in Daecheong Reservoir from middle of July to early August, 2001. The maximum cell counts during the peak bloom reached 1,477,500 cells/mL, which was more than 6~10 times greater than those at other monitoring sites. The hypothesis of this study is that the timing and location of the algal bloom was highly correlated with the local environmental niche that was controled by physical processes such as hydrodynamic mixing and pollutant transport in the reservoir. A three-dimensional, coupled hydrodynamic and ecological model, ELCOM-CAEDYM, was applied to the period of development and subsequent decline of the bloom. The model was calibrated against observed water temperature profiles and water quality variables for different locations, and applied to reproduce the algal bloom event and justify the limiting factor that controled the Microcystis bloom at R3. The simulation results supported the hypothesis that the phosphorus loading induced from a contaminated tributary during several runoff events are closely related to the rapid growth of Microcystis during the period of bloom. Also the physical environments of the reservoir such as a strong thermal stratification and weak wind velocity conditions provided competitive advantage to Microcystis given its light adaptation capability. The results show how the ELCOM-CAEDYM captures the complex interactions between the hydrodynamic and biogeochemical processes, and the local environmental niche that is preferable for cyanobacterial species growth.
Physicochemical Properties of acid mine water of the Chonam-ri Creek and the Sagok-ri Creek in the Kwangyang Au-Ag mine area were determined using geochemical approaches. Metal contamination (Cd, Cu, Pb, Zn) is more serious in the Chonam-ri Creek than in the Sagok-ri Creek. However, the contents of Al and Fe is higher in the Sagok-ri Creek. Such differences between the two creeks probably reflect the abundance and composition of ore minerals. The attenuation processes for acid mine water in both creeks were investigated. In the Chonam-ri Creek, a small retention pond which contains limestone plays an important role in the removal of heavy metals by adsorption or coprecipitation due to increase of pH. The capacity of metal scavenging in this pond depends on the seasonal variation of inflow volume. Reddish yellow precipitates sampled in the Chonam-ri Creek were analyzed by XRD, SEM-EDS, EPMA, and chemical decomposition. The precipitates mainly consist of goethite and are also enriched in Al, Mn, Cu and Zn. This inditates that precipitation of goethite is important for scavenging those trace elements, possibly due to adsorption or coprecipitation. In the Sagok-ri Creek, on the other hand, hydrologic mixing of uncontaminated tributaries results in removal of heavy metals with iron hydroxides precipitation due to the pH increase. The mechanisms proposed for metal attenuation at the confluence between contaminated mine water and uncontaminated tributary water are also explained by the property-property plots.
Kim, Shin;Ahn, Jungmin;Kim, Hyounggeun;Kwon, Heongak;Kim, Gyeonghoon;Shin, Dongseok;Yang, Deukseok
Journal of Environmental Science International
/
v.27
no.6
/
pp.411-423
/
2018
To investigate the distribution characteristics of grain size and organic matter of surface sediments from the Nakdong-Goryeong Mid-watershed, surface sediments were collected and analyzed. The samples were collected from six sited at four different times between May 2013 and May 2014. The were analyzed for grain size, water content, ignition loss, chemical oxygen demand, total organic carbon and total nitrogen. The surface sediments were mainly composed of medium sand (mean 44.7%) and coarse sand (mean 32.8%) and became coarser in May 2014. Fine sediments at the site NG-2 were poorly sorted and positively skewed, and occur in a tributary environment that is relatively low-energy compared with the other sites. The water content at the studied sites (15.3 ~ 34.9%) averaged 20.25%, and ignition loss (0.4 ~ 5.8%) and total nitrogen (274 ~ 2493 mg/kg) averaged 1.33% and, 696 mg/kg, respectively. These values indicated that the sediments were not seriously contaminated when compared with the sediment pollution evaluation standard of the National Institute of Environmental Research. The chemical oxygen demand (mean 0.17%) was at the non-polluted level compared with United States Environmental Protection Agency sediment quality standards. The total organic carbon (mean 0.18%) at all sites except site NG-2 (lowest effect level) was the no effect level of the Ontario sediment quality guidelines. The COD/IL (0.02 ~ 0.20) and C/N (0.73 ~ 6.76) were less than 1 and 10, respectively. Organic matter in the study area produced naturally from aquatic organisms. Results of principal component analysis showed that fine sediments (very fine sand and silt) were significantly affected by organic matters (ignition loss, chemical oxygen demand, total organic carbon and total nitrogen). In addition, the highest organic matters content in the study area occurred at the site with the finest sediments (NG-2).
Na, Seungmin;Kwon, Heongak;Shin, Sang Min;Son, YoungGyu;Shin, Dongseok;Im, Tae Hyo
Journal of Wetlands Research
/
v.18
no.3
/
pp.301-312
/
2016
This study has performed comparative analysis on characteristics of contaminated 35 tributaries on seasonal variation/point discharge load/pollutant distribution of water quality factors(8) in order to understand the effect of the watershed in Nakdong River Basin. As a results, the water quality of $BOD_5$(Biochemical Oxygen Demand), Chl-a(Chlorophyll a) and Fecal E. Coli shows II grade at tributaries of more than 50% without COD(Chemical Oxygen Demand), TP(Total Phosphate), TOC(Total Oxygen Carbon) and TN(Total Nitrogen) factors. The specific discharge(Q) were occupied about 54.4% (19 sites) as $0.05m^3/sec/km^2$ value. Among these results, the contaminant level of Dalseocheon, Hyeonjicheon, Seokkyocheon 1, Uriyeongcheon and Dasancheon was also high, which has to consider a discharged pollutant load(kg/day). The 35 major tributaries of Nakdong River were included in 7 mid-watershed, such as Nakdong Waegwan, Geumho River, Nakdong Goryung, Nakdong Changnyung, Nam River, Nakdong Milyang, Nakdong River Hagueon. Especially, the discharged pollutant load of Nam River and Geumho River also was high according to the amount of discharge such as Kachang dam, Gongsan dam and Nam river dam. Seasonal difference of the water quality factors such as $BOD_5$, TN, SS and Q was observed largely, on the other hand the TP and Chl-a was not. This is guessed due to the precipitation effect of site, biological and physicochemical degradation properties of pollutant and etc. The co-relationship between the seasonal difference and water quality factors was observed using a Pearson correlation coefficients. Besides, the Multiple Regression analysis using a Stepwise Regression method was conducted to understand the effect between seasonal difference and water quality factors/regression equations. As a result, the Multiple Regression analysis was adapted in the spring, summer and autumn without the winter, which was observed high at spring, summer and autumn in the order COD/TP, Chl-a/TOC, TOC/COD/$BOD_5$ water quality factors, respectively.
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