• Title/Summary/Keyword: Contaminated site

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Low Temperature Thermal Desorption (LTTD) Treatment of Contaminated Soil

  • Alistair Montgomery;Joo, Wan-Ho;Shin, Won-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.44-52
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    • 2002
  • Low temperature thermal desorption (LTTD) has become one of the cornerstone technologies used for the treatment of contaminated soils and sediments in the United States. LTTD technology was first used in the mid-1980s for soil treatment on sites managed under the Comprehensive Environmental Respones, Compensation and Liability Act (CERCLA) or Superfund. Implementation was facilitated by CERCLA regulations that require only that spplicable regulations shall be met thus avoiding the need for protracted and expensive permit applications for thermal treatment equipment. The initial equipment designs used typically came from technology transfer sources. Asphalt manufacturing plants were converted to direct-fired LTTD systems, and conventional calciners were adapted for use as indirect-fired LTTD systems. Other innovative designs included hot sand recycle technology (initially developed for synfuels production from tar sand and oil shale), recycle sweep gas, travelling belts and batch-charged vacuum chambers, among others. These systems were used to treat soil contaminated with total petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAHs), pesticides, polychlorinated biphenyls (PCBs) and dioxin with varying degrees of success. Ultimately, performance and cost considerations established the suite of systems that are used for LTTD soil treatment applications today. This paper briefly reviews the develpoment of LTTD systems and summarizes the design, performance and cost characteristics of the equipment in use today. Designs reviewed include continuous feed direct-fired and indirect-fired equipment, batch feed systems and in-situ equipment. Performance is compared in terms of before-and-after contaminant levels in the soil and permissible emissions levels in the stack gas vented to the atmosphere. The review of air emissions standards includes a review of regulations in the U.S. and the European Union (EU). Key cost centers for the mobilization and operation of LTTD equipment are identified and compared for the different types of LTTD systems in use today. A work chart is provided for the selection of the optmum LTTD system for site-specific applications. LTTD technology continues to be a cornerstone technology for soil treatment in the U.S. and elsewhere. Examples of leading-edge LTTD technologies developed in the U.S. that are now being delivered locally in global projects are described.

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Policy Suggestions for Soil Contamination Prevention and Management of Inactive or Abandoned Metal Mines (휴.폐금속광산지역의 토양오염관리정책의 평가)

  • Park Yong-Ha;Seo Kyung-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.3
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    • pp.1-11
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    • 2006
  • Attempts were made to analyze the national policy of soil contamination prevention and management of inactive or abandoned metal (IAM) mines in Korea. This approach focused on legal systems and legislation, remediation technology development, and the arrangement or distribution of budgets pertaining to national policy since the mid 1990's. Prevention of Mining Damage and Recovery Act enacted. Defines the roles, responsibility and budget of the government when recovering mine damages. However, in 2005 there still remains to improve the national policy of soil contamination prevention and management of IAM mines. Analysis of national and industrialized foreign countries including the United States, the United Kingdom, and the Netherlands suggest the following improvements: i) arranging distinct regulations between strict and non-strict liability criteria for potentially responsible parties; limiting innocent and non-strict liability depending on the period of incurred mining activity, ii) enhancing participation of local communities by enforcing law and legislation, iii) establishing a national database system of (potentially) IAM contaminated sites based on the Website-Geographic Information System, iv) carrying out site-specific risk assessments and remediation of IAM contaminated sites, v) preparation and distribution of clean-up fund at mine sites adequately, and vi) technology development for the cleaning of IAM contaminated sites; awarding positive incentives of a legal nature for participants applying newly developed technology in IAM mines.

Case Study of Hydrochemical Contamination by Antimony Waste Disposal in Korea (국내 안티몬폐기물에 의한 수질화학적 오염 사례연구)

  • Jeong, Chan-Ho
    • The Journal of Engineering Geology
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    • v.18 no.4
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    • pp.471-482
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    • 2008
  • This study was carried out to investigate the contamination characteristics of surface water, soil water and groundwater around and in antimony waste landfill site in Wonsung-ri, Yeonki-kun, Chungnam. The waste disposed in the study was excavated and transported to the other site in several years ago. For this study, we collected 35 water samples including groundwater, soil water and surface in the study site and also collected 2 groundwater samples from a comparison site. The data of chemical analysis of soil water samples show the antimony concentration of $48.75{\sim}74.81\;ppb$, which is much higher than groundwater in a comparison site and is highly excess than regulation level for a drinking water of some advanced countries. A relatively high antimony concentration was detected in three stream water samples nearby landfill site and two groundwater samples. Fe and Mn contents in soil water and stream water were measured as maxium 6.5 mg/L and 7.3 mg/L, respectively. Although other heavy metals of water samples in the study site are higher concentration than water sample of comparison site, their absolute levels are lower than regulation level for a drinking water. The chemical data of water samples are plotted widely from Ca - $HCO_3$ type to Ca - ($Cl +SO_4+NO_3$) type. Some groundwater show high contents of potassium and nitrate, which would come from fertilizer and sewage. Conclusively, some heavy metals including antimony have been still remained under the soil surface of the landfill site in the past. These metals have leaked out into nearby stream and groundwater system, and threaten the ecology, crops and the health of residents in this site. Therefore, the government have to prepare the strategy to prevent the diffusion of heavy metals into aquatic environment and have to process the reclamation work for contaminated site. It is also necessary to make a regulation level of the antimony concentration for a drinking water and soil environment in Korea.

A Study on the Full-scale Soil Washing Process Improved by Multi-stage Continuous Desorption and Agitational Desorption Techniques to Remediate Petroleum-contaminated Soils (현장규모의 유류오염토양 세척공법에 다단연속탈착 및 교반탈착기법을 이용한 세척공정 성능향상에 관한 연구)

  • Seo, Yong-Sik;Choi, Sang-Il;Jang, Min
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.81-87
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    • 2008
  • In accompany with the transfer of US army bases, recent surveys reported serious contamination of soils by the release of petroleum from storage facilities and heavy metals accumulated in rifle-ranges. These problems have made an increased concerns of cleanup technology for contaminated soils. In this study, a full-scale soil washing process improved by multistage continuous desorption and agitational desorption techniques was examined for petroleum-contaminated soils obtained from three different remedial sites that contained 29.3, 16.6, and 7.8% of silt and clay, respectively. The initial concentrations of total petroleum hydrocarbon (TPH) were 5,183, 2,560, and 4,860 mg/kg for each soil. Pure water was applied to operate washing process, in which water used for washing process was recycled 100% for over 6 months. The results of full-scale washing tests showed that the TPH concentrations for soils (> 3.0 mm) were 50${\sim}$356 mg/kg (85.2${\sim}$98.2% removal rates), regardless of the contents of silt and clay from in A, B and C soil, when the soils were washed at 3.0 kg/$cm^2$ of injection pressure with the method of wet particle separation. Based on the initial TPH concentration, the TPH removal rates for each site were 85.2, 98.2 and 89.9%. For soils in the range of 3.0${\sim}$0.075 mm, the application of first-stage desorption technique as a physical method resulted 834, 1,110, and 1,460 mg/kg of TPH concentrations for each soil, also additional multi-stage continuous desorption reduced the TPH concentration to 330, 385, and 245 mg/kg that were equivalent to 92.4, 90.6, and 90.1% removal rates, respectively. The result of multi-stage continuous desorption for fine soil (0.075${\sim}$0.053 mm) were 791, 885, and 1,560 mg/kg, and additional agitation desorption showed 428, 440, and, 358 mg/kg of TPH concentrations. Compared with initial concentration, the removal rates were 92.0, 93.9 and 92.9%, respectively. These results implied we could apply strategic process of soil washing for varies types of contaminated soils to meet the regulatory limit of TPH.

A Study on Transport Characteristics of MTBE(Methyl Tertiary Butyl Ether) in Soil (MTBE(Methyl Tertiary Butyl Ether)의 토양내 이동특성에 관한 연구)

  • Cho, Ki-Chul;Park, Chang-Woong;Choi, Won-Joon;Kang, Seung-Yub;Hwang, Jong-Hyun;Kim, Youn-Soo;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.2
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    • pp.190-198
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    • 2008
  • In this stduy, the column experiments were carried out assuming the soil was contaminated by leakage of gasoline containing MTBE from USTs and pipes around gas stations. Then, characteristics of MTBE transport in the soil were investigated using CXTFIT program. The column experiments with different soil properties, moisture content, organic matter content and flow rate were carried out. Some parameters(D, R, $\beta$, $\omega$) used in two-site non-equilibrium adsorption model were obtained from measuring the MTBE concentration in injection-liquid and in effluent and using CXTFIT program. In addition, The characteristics of MTBE transport in the soil was found using BTCs and obtained parameters. Consequently, the advection decreased as the increase of the content of fine particle and organic, while the MTBE transport by advection was enhanced as increasing flow rate and moisture content.

Monitoring canopy phenology in a deciduous broadleaf forest using the Phenological Eyes Network (PEN)

  • Choi, Jeong-Pil;Kang, Sin-Kyu;Choi, Gwang-Yong;Nasahara, Kenlo Nishda;Motohka, Takeshi;Lim, Jong-Hwan
    • Journal of Ecology and Environment
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    • v.34 no.2
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    • pp.149-156
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    • 2011
  • Phenological variables derived from remote sensing are useful in determining the seasonal cycles of ecosystems in a changing climate. Satellite remote sensing imagery is useful for the spatial continuous monitoring of vegetation phenology across broad regions; however, its applications are substantially constrained by atmospheric disturbances such as clouds, dusts, and aerosols. By way of contrast, a tower-based ground remote sensing approach at the canopy level can provide continuous information on canopy phenology at finer spatial and temporal scales, regardless of atmospheric conditions. In this study, a tower-based ground remote sensing system, called the "Phenological Eyes Network (PEN)", which was installed at the Gwangneung Deciduous KoFlux (GDK) flux tower site in Korea was introduced, and daily phenological progressions at the canopy level were assessed using ratios of red, green, and blue (RGB) spectral reflectances obtained by the PEN system. The PEN system at the GDK site consists of an automatic-capturing digital fisheye camera and a hemi-spherical spectroradiometer, and monitors stand canopy phenology on an hourly basis. RGB data analyses conducted between late March and early December in 2009 revealed that the 2G_RB (i.e., 2G - R - B) index was lower than the G/R (i.e., G divided by R) index during the off-growing season, owing to the effects of surface reflectance, including soil and snow effects. The results of comparisons between the daily PEN-obtained RGB ratios and daily moderate-resolution imaging spectroradiometer (MODIS)-driven vegetation indices demonstrate that ground remote sensing data, including the PEN data, can help to improve cloud-contaminated satellite remote sensing imagery.

A Study on the Effectiveness and the Distribution of Isolated Strains by Sputum Collection Methods

  • Seong, Hee-Kyung;Lee, Jeong-Nyo
    • Biomedical Science Letters
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    • v.8 no.2
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    • pp.63-69
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    • 2002
  • This study was performed to investigate the effectiveness of the aspiration trap method for collection of sputum by comparing with the conventional method which was collecting specimens at canular cap swab. In this study, the author tested by two methods to collect specimens from 46 patients who were cared with tracheostomy and intubation at the intensive care unit of an university hospital in Pusan, and investigated the incidence of the lower respiratory tract infection, the consistency between the two methods, the level of specimen contamination. Major results were as follows: Among the patients, 35 were cared with tracheostomy and 11 were cared with intubation. In clinical diagnosis we were classified the subjects in to two group, 17 of pneumonia group and 29 of non-pneumonia group. A total of 247 strains were isolated. Among them, most three strains were Serratia marcescens (62 strains; 25.1%), Pseudomonas aeruginosa (52 strains; 21.1%), and Acinetobacter baumannii (19 strains; 7.8%). Out of total, 188 (76.1%) strains were Gram negative bacilli. The isolated strains by the aspiration trap method were the average 2.1 strains, but by the canular cap swab method were 1.6 strains. In spite of the high contaminated possibility from the incision site and the oral cavity swab, the low isolated rates of the canular cap may be the dried environment of the canular of cap area. But the contamination rates were 57.2% of the canular cap, 51.5% of the oral swab and 50.5% of the incision site swab, respectively. The consistency of predominant microorganisms according to collection method were 86.7% of aspiration, 78.3% of canular, 74.3% of incision, and 63.6% of oral. In conclusion, the aspiration trap method fur the sputum collection from the patients with intubation of tracheostomy showed the lower contamination rate of the specimens and it was helpful for rapid, accurated interpretation of the lower respiratory tract infection and hospital infection.

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Factors Influencing Airborne Concentration of Fungi, Bacteria and Gram Negative Bacteria in Kindergarten Classroom (유치원 교실에서 공기 중 박테리아와 곰팡이 발생에 영향을 미치는 요인)

  • Park Donguk;Jo Kyunga;Yoon Chungsik;Han Inyoung;Park Dooyong
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.440-448
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    • 2004
  • Airborne bacteria, gram negative bacteria (GNB) and fungi were measured in 70 class of 17 kindergartens. The objective of this study is to identify the factors influencing airborne concentrations of bacteria, GNB and fungi using multiple regression analysis. The average concentrations of bacteria and fungi exceeded $1,000\;CFU/m^3$. The average of GNB was $3.7{\times}10^2\;CFU/m^3$. This results indicated that air of kindergartens was contaminated with microbes such as bacteria and fungi. ANOVA test found that the concentrations of bacteria, GNB and fungi were significantly different by the characteristics of weather (rain, after rain, sunny) sampling date (July, August, September and October), the location of sampling site (ground level and basement) and the location of toilet (inside class, nearby class and away class). Multiple regression tests concluded that sampling date, the scale of city where kindergartens are located, the location of sampling site and ventilation efficiency can significantly affect the airborne concentration of bacteria, GNB and fungi. Most of these factors could be related moisture. Environmental factors that can cause the increment of moisture should be controlled in order to reduce airborne concentration of bacteria, GNB and fungi. Legal actions concerning prohibition on the presence of toilet inside class and ventilation criteria should be taken.

Hydrogeology and Water Chemistry of the Friar Tuck Abandoned Coal Mine Site, Indiana, USA (미국 인디아나주 Friar Tuck 폐탄광의 수리지질 및 수질)

  • Park, Jung-Chan
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.2
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    • pp.70-79
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    • 1996
  • The Friar Tuck Abandoned Coal Mine site is one of the most complexly disturbed areas in the midwestern United States. The deposits of gob and tailings contain high concentrations of pyrite, whose oxidation contributes to the acidification of soil and water and prevents the growth of vegetation. In an effort to quantitatively evaluate the effects of reclamation techniques, detailed monitoring program was performed. Water samples were collected from surface water, groundwater, and pore water from the unsaturated zone during a period of five years. According to the results, The spoil deposits are a relatively minor source of contamination and gob piles are the source of severe contamination to surface water and groundwater. But, loess and till beneath the gob piles effectively prevent the contaminated water migration from the source. Surface layers of the gob piles and the tailing deposits are less toxic than the interior of the deposits as a consequence of weathering over several decades. Acid mine drainage is in a post-peak stage and acid formation potential is probably situated in the unsaturated zone of refuse.

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Investigation of Seasonal Characteristics of Contaminants and Hydrochemical Factors in an Aquifer for Application of In Situ Reactive Zone Technology (원위치 반응존 공법 적용을 위한 대수층내 오염물질 및 환경영향인자의 계절 특성 평가)

  • Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Jun, Seong-Chun;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.192-203
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    • 2016
  • A field investigation was conducted on an aquifer contaminated with trichloroethylene (TCE) for application of in situ reactive zone treatment using nanosized zero-valent iron (NZVI). The aquifer was an unconfined aquifer with a mean hydraulic conductivity of $5.14{\times}10^{-4}cm/sec$, which would be favorable for NZVI injection. Seasonal monitoring of TCE concentration revealed a presence of non-aqueous phase liquid form of TCE near IW (injection well). The hydrochemical data characterized the site groundwater to be a $Ca-HCO_3$ type. The average value of Langelier Saturation Index of the groundwater was -1.33, which implied that the site was favorable for corrosion of NZVI. Dissolved oxygen (DO) concentration varied between 2.5~11.5 mg/L, which indicated that DO would greatly compete with TCE as an electron acceptor. The hydrogeological and hydrochemical characterization reveals that the time around November would be appropriate for NZVI injection when water level and temperature are relatively high and DO concentration is low.