• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 하계종합학술대회 논문집(2)
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• pp.185-188
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• 2001

In this study, $Al_2$O$_3$films have been deposited with Atomic Layer Deposition(ALD) for gate insulator for MPTMA and $H_2O$ at low temperature below 40$0^{\circ}C$ . Conventional methods of $Al_2$O$_3$thin film deposition have suffered from the poor step coverage due to reduction of device dimension and increasing contact/via hole aspect ratio. ALD is a self-limiting growth process with controlled surface reaction where the growth rate is only dependent on the number of growth cycle and the lattice parameter of materials. ALD growth process has many advantages including accurate thickness control, large area and large batch capability, good uniformity, and pinholes freeness.

• Korean Chemical Engineering Research
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• 제57권2호
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• pp.283-288
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• 2019

Catalytic removal of sulfur compounds from heavy naphtha (HN) was investigated using a combination of an oxidation process using hydrogen peroxide and an adsorption process using granulated activated carbon (GAC) and white eggshell (WES). This study investigated the impact of changing several operating parameters on the desulfurization efficiency. Specifically, the volume ratio of $H_2O_2$ to HN (0.01~0.05), agitation speed ($U_{speed}$) of the water bath shaker ($100-500{\pm}1rpm$), pH of sulfur solution (1~5), amount of adsorbent (0.1~2.5 g), desulfurization temperature ($25{\sim}85{\pm}1^{\circ}C$) and contact time (10~180 minutes) were examined. The results indicate that the desulfurization efficiency resulting from catalytic and adsorption processes of GAC is better than that of WES for oxidation and removing sulfur compounds from HN due to its high surface area. The desulfurization efficiency depends strongly on all investigated operating parameters. The maximum removal efficiency of GAC and WES achieved by this study was 86 and 65, respectively.

• Progress in Superconductivity
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• 제13권1호
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• pp.7-11
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• 2011

조성경사법을 이용하여 LMO/IBAD-MgO template 상에 EDDC 증착법을 이용하여 $Sm_{1+x}Ba_{2-x}Cu_{3+y}O_{7-d}$ 초전도 박막을 증착하였다. 테이프 형상의 기판상에 길이방향으로 $Sm_{1+x}Ba_{2-x}Cu_{3+y}O_{7-d}$ 박막의 조성비가 연속적으로 변하는 샘플을 얻을 수 있었고, 비접촉 Hallprobe를 이용하여 임계전류를 측정한 결과 조성비에 대응하는 연속적인 임계전류분포를 측정할 수 있었다. 본 조성비 영역 중 Sm:Ba:Cu = 1.01:1.99 :4.87의 조성비에서 최대의 임계전류를 보였다. 이 조성비에서 SmBCO 박막표면에 전체적으로 roof tile 형상의 결정립들이 관찰되었으며 국소적으로 2차상들이 관찰되었다. 조성 경사법을 이용하면 광범위한 조성비영역에서 신뢰도 높은 초전도특성, 결정배향성, 박막표면 형상 등을 조사할 수 있을 것으로 예상된다.

• Corrosion Science and Technology
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• 제12권3호
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• pp.125-131
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• 2013

The most common pipe wall thinning degradation mechanisms that can occur in the steam and feedwater systems are FAC (Flow Acceleration Corrosion), cavitation, flashing, and LDIE (Liquid Droplet Impingement Erosion). Among those degradation mechanisms, FAC has been investigated by many laboratories and industries. Cavitation and flashing are also protected on the piping design phase. LDIE has mainly investigated in aviation industry and turbine blade manufactures. On the other hand, LDIE has been little studied in NPP (Nuclear Power Plant) industry. This paper presents the development of prediction system for pipe wall thinning caused by LDIE in terms of erosion rate based on air-water ratio and material. Experiment is conducted in 3 cases of air-water ratio 0.79, 1.00, and 1.72 using the three types of the materials of A106B, SS400, and A6061. The main control parameter is the air-water ratio which is defined as the volumetric ratio of water to air (0.79, 1.00, 1.72). The experiments were performed for 15 days, and the surface morphology and hardness of the materials were examined for every 5 days. Since the spraying velocity (v) of liquid droplets and their contact area ($A_c$) on specimens are changed according to the air-water ratio, we analyzed the behavior of LDIE for the materials. Finally, the prediction equations(i.e. erosion rate) for LDIE of the materials were determined in the range of the air-water ratio from 0 to 2%.

• 상하수도학회지
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• 제34권6호
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• pp.503-512
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• 2020

Identifying the water circulation status is one of the indispensable processes for watershed management in an urban area. Recently, various water circulation models have been developed to simulate the water circulation, but it takes a lot of time and cost to make a water circulation model that could adapt the characteristics of the watershed. This paper aims to develop a water circulation state estimation model that could easily calculate the status of water circulation in an urban watershed by using multiple linear regression analysis. The study watershed is a watershed in Seoul that applied the impermeable area ratio in 1962 and 2000. And, It was divided into 73 watersheds in order to consider changes in water circulation status according to the urban characteristic factors. The input data of the SHER(Similar Hydrologic Element Response) model, a water circulation model, were used as data for the urban characteristic factors of each watershed. A total of seven factors were considered as urban characteristic factors. Those factors included annual precipitation, watershed area, average land-surface slope, impervious surface ratio, coefficient of saturated permeability, hydraulic gradient of groundwater surface, and length of contact line with downstream block. With significance probabilities (or p-values) of 0.05 and below, all five models showed significant results in estimating the water circulation status such as the surface runoff rate and the evapotranspiration rate. The model that was applied all seven urban characteristics factors, can calculate the most similar results such as the existing water circulation model. The water circulation estimation model developed in this study is not only useful to simply estimate the water circulation status of ungauged watersheds but can also provide data for parameter calibration and validation.

• 열처리공학회지
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• 제16권4호
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• pp.197-204
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• 2003

Honeycomb structure has been fabricated by brazing method using 0.1 wt%C and 1.0wt%C carbon steel core and STS304 stainless steel face sheet. Core shear strength ratio in W and L directions was 1:1.03 in 7 mm cell size, whereas 1:1.45 in 4 mm cell size. Flexural strength on face sheet was 166.4 MPa (0.1 wt%C, W direction), 171.1 MPa (0.1 wt%C, L direction), and 120.2 MPa (1.0 wt%C, W direction) in 7 mm cell size. And in 4mm cell size specimen, it was 169.2 MPa (0.1 wt%C, W direction), 224.2 MPa (0.1 wt%C, L direction). This means that flexural strength of 0.1 wt%C core material was higher than that of 1.0wt%C core material, which was contrary to expectation. SEM and EDS analysis represented that grain boundary diffusion had occurred in0.1 wt%C core, but no grain boundary diffusion in 1.0 wt%C core. And corrugated surface of 0.1 wt%C core was flat, whereas that of 1.0 wt%C core was not flat. As a result, contact area between two 1.0 wt%C cores was much less than that of 0.1 wt% cores, It is thought to be main reason for lower flexural strength of 1.0 wt%C core.

• 열처리공학회지
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• 제9권1호
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• pp.19-26
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• 1996

Melt-quenching of steels leads to various metallographic effects such as refinement of grain size, extension of the solid solubility of carbon and alloying elements, and is expected to improve the mechanical properties of conventional steels. Furthermore, this technique is a useful method for producing sheet directly from liquid state. And it will lend itself to development as a continuous cast process which offers significant savings in energy and product costs. The purpose of this study is to present the microstructures of melt-quenched austenitic stainless steels. As the results of this study, the morphology of melt-quenched microstructure show that the roll contact area is columnar structure, and the free surface area is dendrite structure. As the line speed increases, the ratio of $d_{colunnar}/d_{total}$ increases from 0.12 to 0.60, but the ribbon thickness decreases from $150{\mu}m$ to $30{\mu}m$.

• 공업화학
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• 제9권7호
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• pp.956-960
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• 1998

Cu와 Zn의 몰비가 1/2, 1/1, 2/1인 촉매를 제조하여 메탄올 수증기 개질반응의 활성을 측정하고, 가장 좋은 활성을 보이는 Cu/Zn의 몰비가 2/1인 촉매를 선정하여 $TiO_2$의 첨가량을 달리하여, 메탄올 수증기 개질반응에 대한 활성을 측정하였다. 반응의 압력은 상압, 온도는 $250^{\circ}C$, 수증기/메탄올 몰비 1.5, 접촉시간 0.1 g-cat.hr/mL-feed의 조건에서 활성을 비교한 결과, $TiO_2$의 첨가량이 3 mol%인 촉매의 경우 최대 전화율을 보였고, 전범위에서 수소로의 선택도는 매우 높았다. 촉매의 특성 분석결과 촉매의 비표면적보다는 $N_2O$흡착, 분해방법에 의한 금속구리의 비표면적의 영향이 더욱 큼을 알 수 있었고, 적정 $TiO_2$의 첨가로 금속구리의 비표면적을 높일 수 있었다. XRD, XPS분석결과 반응중에 아연의 산화상태는 달라지지 않으나, 구리는 대부분이 0가와 1가의 상태로 존재함을 확인하였다.

• 한국정밀공학회지
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• 제15권8호
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• pp.46-59
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• 1998

This paper presents shape design, surface construction, and cutting path generation for the surface of marine ship propeller blades. A propeller blade should be designed to satisfy performance constraints that include operational speed which impacts rotations per minutes, stresses related to deliverable horst power, and the major length of the marine ship which impacts the blade size and shape characteristics. Primary decision variables that affect efficiency in the design of a marine ship propeller blade are the blade diameter and the expanded area ratio. The blade design resulting from these performance constraints typically consists of sculptured surfaces requiring four or five axis contoured machining. In this approach a standard blade geometry description consisting of blade sections with offset nominal points recorded in an offset table is used. From this table the composite Bezier surface geometry of the blade is created. The control vertices of the Hazier surface patches are determined using a chord length fitting procedure from tile offset table data. Cutter contact points and path intervals are calculated to minimize travel distance and production time while maintaining a cusp height within tolerance limits. Long path intervals typically generate short tool paths at the expense of increased however cusp height. Likewise, a minimal tool path results in a shorter production time. Cutting errors including gouging and under-cut, which are common errors in machining sculptured surfaces, are also identified for both convex and concave surfaces. Propeller blade geometry is conducive to gouging. The result is a minimal error free cutting path for machining propeller blades for marine ships.

• 한국산학기술학회논문지
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• 제13권9호
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• pp.4277-4283
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• 2012

고장력볼트 마찰이음에서 접촉면의 표면상태에 따라 다양한 값을 갖는 미끄러짐계수는 볼트의 축력과 미끄러짐하중에 의해 결정되어진다. 또한 접촉면적은 미끄러짐하중에 영향을 미치게 되므로 볼트구멍에 따라 변하는 접촉면적은 미끄러짐계수와 상관관계를 갖게 된다. 본 연구에서는 부재의 종류, 볼트의 직경 및 볼트구멍의 크기에 따른 미끄러짐계수와 미끄러짐하중의 변화를 파악하기 위하여 32개의 시험편을 제작하여 휨시험 및 인장시험을 실시하였다. 과대볼트구멍으로 제작된 시험편의 미끄러짐하중은 표준볼트구멍으로 제작된 미끄러짐하중의 80%이상의 강도를 발휘하였으며 설계 미끄러짐강도를 상회하였다. 또한 과대볼트구멍으로 제작된 시험편과 표준볼트구멍으로 제작된 시험편의 순단면적비와 미끄러짐비간에는 상당한 상관성을 가지는 것으로 나타났다. 그러나 시험결과가 각 시험체에 따라 다소의 차이를 보이는 것은 미끄러짐계수의 중요한 파라메타인 고장력볼트의 도입축력이 감소하기 때문인 것으로 판단된다. 볼트구멍 크기의 증가는 미끄러짐 계수 뿐 아니라 볼트 축력의 감소를 야기시키므로 설계강도의 감소를 초래하는 것은 자명한 사실이지만 외국의 경우와 같이 구조적 안정을 위협하지 않는 범위 내에서 볼트구멍에 대한 규정에 유연성을 갖는 것도 시공성과 효율성에 긍정적인 요소가 될 것으로 기대된다.