• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2371-2376
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• 2009

Three phenoxazine-based conjugated polymers, namely, the aryl substituted phenoxazine homopolymer (P1) as well as the dimeric phenoxazine-fluorene (P2) and phenoxazine-bithiophene (P3) copolymers, were synthesized via the Ni(0) mediated Yamamoto reaction and the palladium-catalyzed Suzuki coupling reaction. The weight-averaged molecular weights ($M_w$) of P1, P2, and P3 were found to be 27,000, 22,000, and 15,000, respectively, and their polydispersity indices were 3.6, 1.8, and 2.1. All the polymers were soluble in common organic solvents such as chloroform, toluene, and so on. The UV-visible absorption maxima for P1, P2, and P3 in the film state were located at 421, 415 and 426 nm, respectively, and the ionization potentials of the polymers ranged between 4.90 and 5.12 eV. All the studied phenoxazine-based polymers exhibited amorphous behavior, as confirmed by X-ray diffraction (XRD) and atomic force microscopy (AFM) studies. Thin film transistors were fabricated using the top-contact geometry. P1 showed much better thin-film-transistor performance than P2 or P3: A thin film of P1 gave a saturation mobility of 0.81 ${\times}\;10^{-3}\;cm^2V^{-1}s^{-1}$ and an on/off ratio of about $10^2$.

• Journal of Hydrogen and New Energy
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• v.22 no.5
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• pp.599-608
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• 2011

The Ni-Al anodes of the molten carbonate fuel cell (MCFC) with three different structures were successfully fabricated in order to reduce the thickness of the anode down to 0.3 mm; one was the non-supported anode made by a conventional tape casting method, and others were the supported anodes made by lamination or direct casting on the nickel screen. It was seen from the physical analyses and cell operation that the supported thin anodes made by direct casting showed good mechanical strength and cell performance because of a good contact between the anode materials and the support. The single cell using the above anode showed the cell voltage of 0.858 V at the current density of 150$mA/cm^2$ with the nitrogen cross-over of only 0.6% at the operation time of 1,000 h, which was similar to the performance of the conventional thick (0.7 mm) anode. The ability to utilize a thin configuration of anode should cut down the amount of nickel alloy and consequently reduce its manufacturing cost.

• Progress in Superconductivity and Cryogenics
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• v.16 no.1
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• pp.36-41
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• 2014

Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction ($k_g$), solid conduction ($k_s$), radiation ($k_r$) and thermal contact ($k_c$). Among these components, $k_g$ and $k_s$ were calculated by Zehner and Schlunder model (1970). Other component values for $k_c$ and $k_r$, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.6
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• pp.130-138
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• 2012

There are increasing demands from the industry for intelligent robot-calibration solutions, which can be tightly integrated to the manufacturing process. A proposed solution can simplify conventional robot-calibration and teaching methods without tedious procedures and lengthy training time. iGPS(Indoor GPS) system is a laser based real-time dynamic tracking/measurement system. The key element is acquiring and reporting three-dimensional(3D) information, which can be accomplished as an integrated system or as manual contact based measurements by a user. A 3D probe is introduced as the user holds the probe in his hand and moves the probe tip over the object. The X, Y, and Z coordinates of the probe tip are measured in real-time with high accuracy. In this paper, a new approach of robot-calibration and teaching system is introduced by implementing a 3D measurement system for measuring and tracking an object with motions in up to six degrees of freedom. The general concept and kinematics of the metrology system as well as the derivations of an error budget for the general device are described. Several experimental results of geometry and its related error identification for an easy compensation / teaching method on an industrial robot will also be included.

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1945-1950
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• 2007

Two fluorene-based conjugated copolymers containing hexyl-thiophene derivatives, PF-1T and PF-4T, were synthesized via the palladium-catalyzed Suzuki coupling reaction. The number-average molecular weights (Mn) of PF-1T and PF-4T were found to be 19,100 and 13,200, respectively. These polymers were soluble in common organic solvents such as chloroform, chlorobenzene, toluene, etc. The UV-vis absorption maximum peaks of PF-1T and PF-4T in the film state were found to be 410 nm and 431 nm, respectively. Electrochemical characterization revealed that these polymers have low highest occupied molecular orbital (HOMO) levels, indicating good resistance against oxidative doping. Thin film transistor devices were fabricated using the top contact geometry. PF-1T showed much better thin-film transistor performance than PF-4T. A thin film of PF- 1T gave a saturation mobility of 0.001-0.003 cm2 V?1 s?1, an on/off ratio of 1.0 × 105, and a small threshold voltage of ?8.3 V. To support TFT performance, we carried out DSC, AFM, and XRD measurements.

• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.1
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• pp.29-36
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• 2011

HPAI (High pathogenic avian influenza) which is a disease legally designated as an epidemic generally shows rapid spread of disease resulting in high mortality rate as well as severe economic damages. Because Korea is contiguous with China and southeast Asia where HPAI have occurred frequently, there is a high risk for HPAI outbreak. A prompt treatment against epidemics is most important for prevention of disease spread. The spread of HPAI should be considered by both direct and indirect contact as well as various spread factors including airborne spread. There are high risk of rapid propagation of HPAI flowing through the air because of collective farms mostly in Korea. Field experiments for the mechanism of disease spread have limitations such as unstable weather condition and difficulties in maintaining experimental conditions. In this study, therefore, computational fluid dynamics which has been actively used for mass transfer modeling were adapted. Korea has complex terrains and many livestock farms are located in the mountain regions. GIS numerical map was used to estimate spreads of virus attached aerosol by means of designing three dimensional complicated geometry including farm location, road network, related facilities. This can be used as back data in order to take preventive measures against HPAI occurrence and spread.

• Transactions of Materials Processing
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• v.25 no.6
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• pp.379-389
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• 2016

As a stator for steam turbine diaphragm, hollow-type nozzle stator to substitute for conventional solid one is introduced in this study. This hollowed stator can be separated into two parts such as upper and lower plates with large and curved surface area. This study focuses on thick plate forming process for the upper plate of the hollow-partitioned nozzle stator. First, to reduce forming defects such as under-cut and localized thinning of the deformed plate, and to avoid tool interruption between forming punch and lower die, tool design including the position determination of forming surfaces is performed. Uni-axial tensile tests are carried out using SUS409L steel plate with initial thickness of 5.00mm, and plastic strain ratio (r-value) is also obtained. Due to the asymmetric curved configuration of the upper plate, it is hard to adopt a series of blank holder or draw-bead, so the initial plate during this thick plate forming experiences unstable and non-uniform contact. To easy this forming difficulty and find suitable tool geometry without sliding behavior of the workpiece in the die cavity, two geometric parameters with respect to each shoulder angle of the lower die and the upper punch are adopted. FE models with consideration of 21 combinations for the geometric parameters are built-up, and numerical simulations are performed. From the simulated and predicted results, it is shown that the geometric parameter combinations with ($30^{\circ}$, $90^{\circ}$) and ($45^{\circ}$, $90^{\circ}$) for the shoulder angle of the lower die and the upper punch are suitably applied to this upper plate forming of the hollow-partitioned nozzle stator used for the turbine diaphragm.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1503-1512
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• 2013

In this study, we proposed an indentation evaluation method for fracture toughness using cohesive finite element simulations. First, we examined the effect of material properties (yield strain, Poisson's ratio, and elastic modulus) on crack size during Vickers indentation and then generated a regression formula that explains the relations among fracture toughness, indentation load, and crack size. We also proposed another indentation formula for fracture toughness evaluation using the contact size a and E/H (H: hardness). Finally, we examined the relation between the crack size and the indenter shapes. Based on this, we can generate from the formula obtained using the Vickers indenter a formula for an indenter of different shapes. Using the proposed method, fracture toughness is directly estimated from indentation data.

• Smart Structures and Systems
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• v.18 no.3
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• pp.485-500
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• 2016

Stay cables in some cable-stayed bridges suffer large amplitude vibrations under the simultaneous occurrence of rain and wind. This phenomenon is called rain-wind-induced vibration (RWIV). The upper rivulet oscillating circumferentially on the inclined cable surface plays an important role in this phenomenon. However, its small size and high sensitivity to wind flow make measuring rivulet size and its movement challenging. Moreover, the distribution of the rivulet along the entire cable has not been measured. This paper applies the videogrammetric technique to measure the movement and geometry dimension of the upper rivulet along the entire cable during RWIV. A cable model is tested in an open-jet wind tunnel with artificial rain. RWIV is successfully reproduced. Only one digital video camera is employed and installed on the cable during the experiment. The camera records video clips of the upper rivulet and cable movements. The video clips are then transferred into a series of images, from which the positions of the cable and the upper rivulet at each time instant are identified by image processing. The thickness of the upper rivulet is also estimated. The oscillation amplitude, equilibrium position, and dominant frequency of the rivulet are presented. The relationship between cable and rivulet variations is also investigated. Results demonstrate that this non-contact, non-intrusive measurement method has good resolution and is cost effective.

• Structural Engineering and Mechanics
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• v.70 no.4
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• pp.499-511
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• 2019

In this study, the axial compressive behavior of novel quadruple C-channel built-up cold-formed steel columns with different slenderness ratio was investigated, using the experimental and numerical analysis. The axial compressive capacity and failure modes of the columns were obtained and analyzed. The finite element models considering the geometry, material and contact nonlinearity were developed to simulate and analyze the structural behavior of the columns further. There was a great correlation between the numerical analyses and test results, which indicated that the finite element model was reasonable and accurate. Then influence of, slenderness ratio, flange width-to-thickness ratio and screw spacing on the mechanical behavior of the columns were studied, respectively. The tests and numerical results show that due to small slenderness ratio, the failure modes of the specimens are generally local buckling and distortional buckling. The axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns decrease with the increase of maximum slenderness ratio. When the screw spacing is ranging from 150mm to 450mm, the axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns change little. The axial compressive capacity of quadruple C-channel built-up cold-formed steel columns increases with the decrease of flange width-thickness ratio. A modified effective length factor is proposed to quantify the axial compressive capacity of the quadruple C-channel built-up cold-formed steel columns with U-shaped track in the ends.