• Title/Summary/Keyword: Contact conditions

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Water repellency of glass surface coated with fluorosilane coating solutions containing nanosilica (나노실리카를 함유한 불소실란으로 코팅된 유리 표면의 발수 특성)

  • Lee, Soo;Kim, Keun Min
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.531-540
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    • 2019
  • Hydrophilic and hydrophobic nanosilica and tetraethyl orthosilicate (TEOS) as a coupling agent was used to form a coarse spike structure as well as an excellent reactive hydroxyl groups on the glass surface. Then, a second treatment was carried out using a trichloro-(1H,1H,2H,2H)perfluorooctylsilane(TPFOS) solution for ultimate water repellent glass surface formation. The formation of hydrophobic coating layer on glass surface using silica aerosol, which is hydrophobic nanosilica, was not able to form a durable hydrophobic coating layer due to the absence of reactive -OH groups on the surface of nanosilica. On the other hand, a glass surface was first coated with a coating liquid prepared with hydrophilic hydroxyl group-containing nanosilica and hydrolyzed TEOS, and then coated with a TPFOS solution to introduce a hydrophobic surface on glass having a water contact angle of $150^{\circ}$ or more. The sliding angle of the coated glass was less than $1^{\circ}$, which meant the surface had a super water-repellent property. In addition, as the content of hydrophilic nanosilica increased, the optical transmittance decreased and the optical transmittance also decreased after 2nd coating with the TPFOS solution. The super-hydrophobic property of the coated glass was remained up to 50 times of rubbing durability test, but only hydrophobic property was shown after 200 times of rubbing durability test. Conclusively, the optimal coating conditions was double 1st coatings with the HP3 coating solution having a hydrophilic nanosilica content of 0.3 g, and subsequent 2nd coating with the TPFOS solution. It is believed that the coating solution thus prepared can be used as a surface treatment agent for solar cells where light transmittance is also important.

The Study on the Non-Point Pollutants Reduction Using Friendly Bank Protection Anaerobic/Aerobic Contact Filtration Zone (혐기/호기 접촉여과대를 이용한 자연형 하천호안공법의 비점오염 저감 특성 연구)

  • Chang, HyungJoon;Kim, SungDuk
    • Journal of Korean Society of Disaster and Security
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    • v.12 no.1
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    • pp.23-34
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    • 2019
  • It is an urgent issue to manage and reduce non-point pollution sources for improving the water quality of stream and lakes in rural areas. In this study, in order to reduce non-point pollution sources in rural area, Gabion mattresses was proposed to provide protection of riverbanks with anaerobic and aerobic area. The utilization of this was assessed by lab scale model test and pilot plant test. After filling the inside of the gabion mattresses with aggregate, the filtration zone under anaerobic and aerobic conditions was formed to treat the contaminants. In addition, vegetation was deposited on the surfae of the gabion to prevent the inflow of soil and to promote purification by the plant. COD and nitrogen content (T-N, $NH_4{^+}$, -N, $NO_3{^-}N$) were monitored in model and field tests. The lab scale model test showed removal efficiency of 17% of TCOD, 35% of SCOD, 14% of TN, 62% of $NH_4{^+}$, -N, and 33% of $NO_3{^-}$ N. Also, pilot plant test showed removal efficiency of 24% of TCOD, 29% of SCOD, 47% of TN, 50% of $NH_4{^+}-N$, 33% of $NO_3{^-}$, N and 29% of TP.

An approach for moment-rotation relationship and bearing strength of segment lining's joint (세그먼트 라이닝 이음부의 모멘트-회전 관계와 지압강도 계산)

  • Lee, Young Joon;Chung, Jee Seung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.2
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    • pp.93-106
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    • 2021
  • In general, segment lining tunnel refers to a tunnel formed by connecting precast concrete segments as a ring and connecting such rings to each other in the longitudinal direction of the tunnel. As the structural properties of the segment lining is highly dependent on the behavior of the segment joints, thus correct modelling of joint behavior is crucial to understand and design the segment tunnel lining. When the tunnel is subjected to ground loads, the segment joint behaves like a hinge that resists rotation, and when the induced moment exceeds a certain limit of the rotation then it may enter into non-linear field. In understanding the effect of the segment joint on the lining behavior, a moment-rotation relationship of the segment joint was explored based on the Japanese practice and Janssen's approach commonly used in the actual design. This study also presents a method to determine the rotational stiffness of joint refer to the bearing strength. The rotation of the segment joint was estimated in virtual design conditions based on the existing models and the proposed method. And the sectional force of the segment lining and joint were calculated along with the estimated rotation. As the rotation at the segment joint increases, the joint contact area decreases, so the designer have to verify the segment joint for bearing strength as well. This paper suggests a consistent method to determine the rotational stiffness and bearing strength of joints.

Development of High-Durability Ceramic Hollow Fiber and Performance Evaluation of Contact Membrane Process according to Pressure Conditions (고내구성 세라믹 중공사 개발과 압력 조건에 따른 접촉막 공정의 특성 평가)

  • Lee, Seung Hwan;Jeong, Byeong Jun;Shin, Min Chang;Zhuang, Xuelong;Jung, Jiwon;Lee, Yeon Jun;Won, Dongyeon;Park, Jung Hoon
    • Membrane Journal
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    • v.30 no.6
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    • pp.443-449
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    • 2020
  • In this study, CO2 separation experiment was performed on a CH4/CO2 mixed gas using a ceramic hollow fiber membrane contactor module (HFMC). In order to fabricate high-durability HFMC, a high-durability hollow fiber membrane was prepared and evaluated. HFMC was fabricated using the prepared hollow fiber membrane, and the experiment used a mixture of CH4/CO2 (30% CO2, CH4 balance) and monoethanolamine (MEA). During HFMC operation, the effect of gas and absorbent pressure on the CO2 removal efficiency was evaluated. The CO2 removal efficiency increased as the gas pressure increased, and the CO2 absorption flux also showed a tendency to increase with the liquid flow rate. In addition, when the CO2 absorption rate was less than 40%, LTS-1, a counter-current form where the absorbent enters from the bottom, has higher CO2 removal performance than LTS-2, a countercurrent form in which the absorbent enters from the top. and when the absorption rate was 40% or higher, LTS-2 had higher performance than LTS-1.

Hydrophobicity and Adhesion of SiO2/Polyurethane Nanocomposites Topcoat for Aircraft De-icing with Different Pre-curing Time (선경화 시간에 따른 항공기 De-icing용 나노실리카/폴리우레탄 복합재료 탑코트의 소수성 및 접착특성 평가)

  • Kim, Jong-Hyun;Shin, Pyeong-Su;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.33 no.6
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    • pp.365-370
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    • 2020
  • The icing formation at aircraft occur problems such as increasing weight of the body, fuel efficiency reduction, drag reduction, the error of sensor, and etc. The viscosity of polyurethane (PU) topcoat was measured at 60℃ in real time to set the pre-curing time. SiO2 nanoparticles were dispersed in ethanol using ultra-sonication method. The SiO2/ethanol solution was sprayed on PU topcoat that was not cured fully with different pre-curing conditions. Surface roughness of SiO2/PU nanocomposites were measured using surface roughness tester and the surface roughness data was visualized using 3D mapping. The adhesion property between SiO2 and PU topcoat was evaluated using adhesion pull-off test. The static contact angle was measured using distilled water to evaluate the hydrophobicity. Finally, the pre-curing time of PU topcoat was optimized to exhibit the hydrophobicity of SiO2/PU topcoat.

Structural Behavior of RC Beams with Headed Bars using Finite Element Analysis (유한요소해석 기반 확대머리 이형철근 상세 따른 RC보의 구조성능 효과 분석)

  • Kim, Kun-Soo;Park, Ki-Tae;Park, Chang-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.40-47
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    • 2021
  • In this study, the structural behavior by the details of the lap region with the headed bar was estimated through finite element analysis. To solve the finite element analysis of the anchorage region with complex contact conditions and nonlinear behavior, a quasi-static analysis technique by explicit dynamic analysis was performed. The accuracy of the finite element model was verified by comparing the experimental results with the finite element analysis results. It was confirmed that the quasi-static analysis technique well reflected the behavior of enlarged headed bar connection. As a result of performing numerical analysis using 21 finite element models with various development lengths and transverse reinforcement indexes, it was confirmed that the increase of development length and transverse reinforcement index improved the maximum strength and ductility. However, to satisfy the structural performance, it should be confirmed that both design variables(development length and transverse reinforcement index) must be enough at the design criteria. In the recently revised design standard(KDS 14 20 52 :2021), a design formula of headed bar that considers both the development length and the transverse reinforcing bar index is presented. Also the results of this study confirmed that not only the development length but also transverse reinforcing bars have a very important effect.

Adsorption Removal of Eosin Y by Granular Activated Carbon (입자상 활성탄에 의한 Eosin Y의 홉착제거)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.16 no.4
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    • pp.277-283
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    • 2010
  • Eosin Y is used a colorant and dye but eosin Y is harmful toxic substance. In this study, the adsorption characteristics of granular activated carbon have been investigated for the adsorption of eosin dye dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of eosin by a fixed amount of activated carbon have been studied in batch adsorber and fixed bed. The adsorptivity of activated carbon for eosin Y were largely improved by pH control. When the pH was 3 in the sample, the eosin Y could be removed 99% of initial concentration (10 mg/L). The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 293 to 333 K. The estimated values of k and ${\beta}$ are 19.56-134.62, 0.442-0.678, respectively. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet eosin Y concentration is increased from 10 to 30 mg/L, the corresponding adsorption breaktime appears to decrease from 470 to 268 min at bed height of 3 cm and a constant flow rate of 2 g/min. When the initial eosin Y flow rate is increased from 1 to 3 g/min, the corresponding adsorption breaktime appears to decrease from 272 to 140 min at bed height of 3 cm and inlet concentration of 10 mg/L. Also, breaktime increased with increasing bed height at flow rate of 2 g/min and inlet concentration of 10 mg/L. And length of adsorption zone showed similar patterns.

Interfacial and Durability Evaluation of Jute and Hemp Fiber/Polypropylene Composites Using Micromechanical Test and Acoustic Emission (미세역학적시험법과 음향방출을 이용한 Jute 및 Hemp 섬유/폴리프로필렌 복합재료의 내구성 및 계면 평가)

  • Kim, Pyung-Gee;Jang, Jung-Hoon;Kim, Sung-Ju;Hwang, Byung-Sun;Park, Joung-Man
    • Composites Research
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    • v.20 no.3
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    • pp.55-62
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    • 2007
  • Interfacial evaluation and durability of Jute and Hemp fibers/polypropylene (PP) composites were investigated. Moisture content of various treated conditions were measured by thermogravimetic analyzer (TGA). After boiling water test, mechanical properties and IFSS between Jute, Hemp fibers and PP matrix decreased. On the other hand, work of adhesion increased due to swelled fibril by water. Surface energies of Jute and Hemp fibers before and after boiling water test were obtained using dynamic contact angle measurement. IFSS was not always consistent with thermodynamic work of adhesion. In boiling water case, since Jute and Hemp fibers could be swelled by water, surface area and moisture infiltration space increased. Environmental effect on microfailure modes of Jute or Hemp fibers and Jute or Hemp fibers/PP composites were obtained by observing via optical microscope and by monitoring acoustic emission (AE) events and their AE parameters. After boiling water test, unlike Hemp fiber, microfailure process of Jute fiber could occur due to low tensile strength by swelled fibril. In addition, AE events occurred more and AE amplitude and energy became lower than those of before boiling water test.

Determining of Ground Condition Criteria for Dam Reinforced RIM Grouting (댐체 강화 RIM부 그라우팅을 위한 지반상태 기준 결정)

  • Han, Kiseung;Lee, Donghyuk;Park, Duhee
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.2
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    • pp.181-186
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    • 2022
  • Dam slope RIM is a highly important contact interface where the main body and the base surface are connected. In general, when the grouting for the slope of the dam structure is designed, it is planned using limited data (drilling, geological map, etc.). This makes it very difficult to accurately consider the original ground characteristics of the slope RIM grouting target, In addition, when the grouting volume planned during the design is drilled and injected into the original ground where the waterstop is secured, there is a possibility that the original ground with the waterstop is disturbed and the effect of the waterstop is rather diminished. In order to overcome such problems, it is more suitable to first consider geological conditions and determine whether to perform optimal grouting on the original ground through on-site repair tests before performing RIM grouting. In this paper, to determine the grouting of the RIM unit, a pilot hole water pressure test was performed on the rock of the slope in the target section. The analysis shows grouting volume of 1 Lugeon or less, and the cement injection amount also shows the injection result of 1 kg/m or less. In this case, performing grouting is rather counterproductive. This result can be evaluated through a rock of which some degree of order of mass is secured, as it is a dam design standard of 1 Lugeon or less when analyzed, using the results of visual observation and geological map creation during slope cutting. Therefore, in conclusion, it is preferable to make the decision for using RIM grouting on the slope of the dam body structure, based on 1 Lugeon in a rock state, and the cement injection amount also at 1 kg/m.

Dynamic analysis of a coupled steel-concrete composite box girder bridge-train system considering shear lag, constrained torsion, distortion and biaxial slip

  • Li Zhu;Ray Kai-Leung Su;Wei Liu;Tian-Nan Han;Chao Chen
    • Steel and Composite Structures
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    • v.48 no.2
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    • pp.207-233
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    • 2023
  • Steel-concrete composite box girder bridges are widely used in the construction of highway and railway bridges both domestically and abroad due to their advantages of being light weight and having a large spanning ability and very large torsional rigidity. Composite box girder bridges exhibit the effects of shear lag, restrained torsion, distortion and interface bidirectional slip under various loads during operation. As one of the most commonly used calculation tools in bridge engineering analysis, one-dimensional models offer the advantages of high calculation efficiency and strong stability. Currently, research on the one-dimensional model of composite beams mainly focuses on simulating interface longitudinal slip and the shear lag effect. There are relatively few studies on the one-dimensional model which can consider the effects of restrained torsion, distortion and interface transverse slip. Additionally, there are few studies on vehicle-bridge integrated systems where a one-dimensional model is used as a tool that only considers the calculations of natural frequency, mode and moving load conditions to study the dynamic response of composite beams. Some scholars have established a dynamic analysis model of a coupled composite beam bridge-train system, but where the composite beam is only simulated using a Euler beam or Timoshenko beam. As a result, it is impossible to comprehensively consider multiple complex force effects, such as shear lag, restrained torsion, distortion and interface bidirectional slip of composite beams. In this paper, a 27 DOF vehicle rigid body model is used to simulate train operation. A two-node 26 DOF finite beam element with composed box beams considering the effects of shear lag, restrained torsion, distortion and interface bidirectional slip is proposed. The dynamic analysis model of the coupled composite box girder bridge-train system is constructed based on the wheel-rail contact relationship of vertical close-fitting and lateral linear creeping slip. Furthermore, the accuracy of the dynamic analysis model is verified via the measured dynamic response data of a practical composite box girder bridge. Finally, the dynamic analysis model is applied in order to study the influence of various mechanical effects on the dynamic performance of the vehicle-bridge system.