• 제목/요약/키워드: Contact angel

검색결과 13건 처리시간 0.02초

습식 공정법에 의한 초발수 $TiO_2$ 박막 제조 (Fabrication of superhydrophobic $TiO_2$ thin films by wet process)

  • 김진호;정현호;황종희;임태영;최덕균;정덕수;김세훈
    • 한국결정성장학회지
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    • 제19권5호
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    • pp.262-267
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    • 2009
  • 초발수 $TiO_2$ 박막을 습식 공정법에 의해 유리 기판 위에 성공적으로 제조하였다. Micro-nano 복합구조의 거친 표면을 갖는 박막을 제조하기 위하여 layer-by-layer(LBL) deposition 법과 liquid phase deposition(LPD) 법이 이용되었다. 초발수 박막은 LBL 법에 의해 texture 구조를 갖는(PAH/PAA) 박막을 제조 한 후 그 위에 LPD 법에 의해 $TiO_2$ 나노 입자를 적층시키고 그 표면을 fluoroalkyltrimethoxysilane(FAS)를 사용하여 발수 처리를 하여 제조하였다. $(PAH/PAA)_{10}$ 박막의 표면에 45분 동안 $TiO_2$를 적층한 박막은 RMS roughness가 65.6 nm로 거친 표면을 보여주었고 발수 처리 이후에 접촉각 $155^{\circ}$ 정도의 초발수 특성과 함께 파장 650 nm 이상에서는 80% 이상의 투과율을 보여주었다. 서로 다른 조건에서 제조된 박막의 표면 구조,광학적 특성, 접촉각을 FE-SEM, AFM, UV-Vis, contact angel meter를 이용하여 측정하였다.

유한요소해석을 이용한 이형성 고관절의 선반형성술에 대한 생체역학 해석 (Biomechanical Analysis of the Shelf Operation for Dysplastic Hip Joint by Finite Element Analysis)

  • 박원만;김윤혁
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.519-520
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    • 2006
  • The aim of this study was biomechanical analysis of shelf operation in patients with dysplastic hip joint by finite element contact analysis. Two dimensional CT images were used to construct the finite element models to analyze the contact pressure, and the 3D expansion of the Ninomiya's method was used in the calculation of the resultant force in the hip joint. The surgery recovered the center-edge angles to the normal anatomical range and increased the contact areas in two patients. The maximum contact pressures and von-mises stresses were decreased. The present study provides the biomechanical guideline of optimal surgical parameters to maximize the surgical efficiency and the clinical outcomes in dysplastic hip joint using the shelf operation.

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플라즈마처리에 따른 에폭시 복합재료의 표면특성 (Surface Properties of Epoxy Composites by Plasma Treatment)

  • 임경범;이백수;이덕출
    • 한국전기전자재료학회논문지
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    • 제14권10호
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    • pp.821-827
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    • 2001
  • In this study performed to identify a degradation mechanism in macromolecular insulating material, the contact angel, surface potential decay, surface resistivity, and XPS analysis were compared after exposure of FRP laminate to plasma discharge. In the case of contact angle, the surface of specimen untreated showed weak hydrophobic property of 73。. However, the contact angle was decreased to 20。in the plasma-treated specimen. In the case of chemical changes arising form plasma treatment, carboxl radicals were generated mainly in the surface treated, which was rapidly changed to the hydrophilic one. In the corona potential decay study to determine the electrical changes of the surface, positive charges were rapidly decreased when compared with negative charges, leading to negative property in the surface of specimen not treated. However, in the case of the hydrophilic surface, lots of carboxl radicals acting as positive polarity were generated, resulting in positive surface. Owing to such positive surface, charges of negative polarity applied were rapidly decreased.

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마이크로웨이브 플라즈마 처리를 통한 섬광체 패널 기판의 접촉가 특성변화 (Characteristics of the Contact Angle Using the Microwave Plasma Treatment on Scintillator Panel Substrates)

  • 김병욱;김영주;유철우;최병정;권영만;이영춘;김명수;조규성
    • 방사선산업학회지
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    • 제8권1호
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    • pp.43-47
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    • 2014
  • By measuring decrease change of the contact angle after microwave plasma treatment on the glass and Al as a scintillator panel sample substrate, the adhesive performance of scintillator panel can be expected to improve. Also resolution and sensitivity of scintillator panel after microwave plasma treatment can be expected to maintain highly.

액상증착법에 의한 초친수 TiO2 박막 제조 (Fabrication of super hydrophilic TiO2 thin film by a liquid phase deposition)

  • 정현호;김진호;황종희;임태영;최덕균
    • 한국결정성장학회지
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    • 제20권5호
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    • pp.227-231
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    • 2010
  • 광촉매 특성을 지닌 초친수 $TiO_2$ 박막을 액상증착법에 의해 유리 기판 위에 성공적으로 제조하였다. 제조된 $TiO_2$ 박막은 $70^{\circ}C$에서 박막표면에 $TiO_2$ 나노 입자들을 형성하였다. $TiF_4$ 용액의 침적시간이 증가됨에 따라 박막의 두께도 일정하게 증가되었다. $TiO_2$ 박막은 약 $5^{\circ}$ 이하의 접촉각과 가시영역에서 약 75~90 %의 투과율을 보여주었다. 또한 제조된 $TiO_2$ 박막은 자외선 조사에 의해 메칠오렌지 용액을 분해하는 광촉매 특성을 보여주었다. 침적시간 조건에 따라 제조된 박막의 표면 구조, 광학적 특성, 접촉각을 FE-SEM, AFM, UV-Vis, contact angle meter를 이용하여 측정하였다.

하악의 비틀림회전운동에 영향을 미치는 요인 (Factor Affecting Mandibular Rotational Troque Movements)

  • 이유미;한경수;허문일
    • Journal of Oral Medicine and Pain
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    • 제23권2호
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    • pp.143-155
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    • 1998
  • This study was performed to investigate the factor that might affect mandibualr body rotation. For the study, 115 patients with temporomandibular disorders and 35 dental students without angy signs and symptoms of temporomandibular disorders were randomly selected as the patient group and the contreol group, respectively. Preferred chewing side, Angle' classification, lateral guidance pattern, and affected side were clinically recorded, and the amount of Mandibular body rotational torque movement was measured in wide opening and closure, in right and left excursion with vertical and lateral distance in frontal plane, right and left rotational angel in horizontal and in frontal plane. Masticatory muscle activity of anteriorocclusal contact pattern on maximal hard biting were also observed synchronously with BioEMG and T-Scan , respectively. The observed items were muscle activity of anterior temporalis and superficial masseter, and tooth contact status related to contact number, force, duration, and occlusal unbalance between right and left arch. The data collected were analyzed by SAS statistical program. The results of this study were as follows : 1. Mean value of vertical distance in frontal plane in wide opening and closure was more in control subjects than in patients, but there was no difference for rotational angle. In right excursion, rotational angles were greater in patient group than in control group. 2. Comparison among the subjects by preferred chewing side did not reveal any significant difference, but comparison among patients by affected side showed more rotational amount in bilaterally affected patients than in unilaterally affected patients. 3. Comparison among the subjects by Angle's classification or lateral guidance pattern revealed no difference. There was also no difference between preferred chewing side and contralateral side, and between affected side and contralateral side. 4. Positive correlation in madibular rotational torque movements were observed among vertical distance, total horizontal rotation angle, electromyographic activity of anterior temporalis, tooth contact number, and tooth contact force but total frontal rotation angle almost did not show any correlation with other variables except vertical distance.

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접촉 반력을 이용한 4 족 보행로봇의 경사면 감지 및 보행 알고리즘 (Slope Detecting and Walking Algorithm of a Quadruped Robot Using Contact Forces)

  • 이순걸
    • 한국정밀공학회지
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    • 제16권4호통권97호
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    • pp.138-147
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    • 1999
  • For autonomous navigation, a legged robot should be able to walk over irregular terrain and adapt itself to variation of supporting surface. Walking through slope is one of the typical tasks for such case. Robot needs not only to change foot trajectory but also to adjust its configuration to the slope angle for maintaining stability against gravity. This paper suggests such adaptation algorithm for stable walking which uses feedback of reaction forces at feet. Adjusting algorithm of foot trajectory was studied with the estimated angel of slope without visual feedback. A concept of virtual slope angle was introduced to adjust body configuration against slope change of the supporting terrain. Regeneration of foot trajectory also used this concept for maintaining its stable walking against unexpected landing point.

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컨테이너 크레인용 쐐기형 레일 클램프의 쐐기각에 대한연구 (Study on the Wedge Angle of Wedge Type Rail Clamp for Container Crane)

  • 한근조;이호;심재준;한동섭;안찬우;전영환
    • 한국정밀공학회지
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    • 제21권9호
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    • pp.119-126
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    • 2004
  • In this paper, we design a wedge type rail clamp which can protect container crane from a sudden strong blast with constant clamping force regardless of the operating period. When we design wedge type rail clamp, it is important to determine the angle of wedge and analyze a contact condition of roller and wedge so that we might develop a wedge type rail clamp for parking devices of port cargo working system with variable capacity. Therefore, this paper suggests a process to decide wedge angles within feasible range which could be obtained using load analysis and FEA of wedge type rail clamp

Gallate group이 포함된 친수성 안의료용 렌즈의 광물리적 특성 (Optophysical Properties of Hydrogel Ophthalmic Lenses Containing Gallate Group)

  • 박세영;성아영
    • 대한화학회지
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    • 제56권6호
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    • pp.725-730
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    • 2012
  • 본 연구는 ethyl 및 propyl gallate를 첨가제로 사용하여 대표적인 친수성 렌즈 재료로 사용되는 HEMA (2-hydroxyethyl methacrylate)와 교차결합제인 EGDMA (ethylene glycol dimethacrylate), MMA (methyl methacrylate), AA (acrylic acid) 그리고 개시제인 AIBN (azobisisobutyronitrile)과 함께 공중합 하였다. 생성된 고분자의 물리적 특성을 측정한 결과, 굴절률 1.433-1.435, 함수율 38.71-38.99%, 가시광선 투과율 85.4-88.8%, 인장강도 0.2468-0.2740 kgf 그리고 접촉각의 경우 $49.77^{\circ}$에서 $36.29^{\circ}$ 범위의 분포를 나타내었다. Ethyl 및 propyl gallate를 0.1-1.0% 첨가한 친수성 콘택트렌즈의 경우, UV-B 영역에서 49.0-7.4%, UV-A 영역에서 71.0-43.4%의 투과율을 나타내어 자외선 차단 효과가 있는 것으로 나타났다. 본 실험 결과 중합된 ethyl gallate와 propyl gallate를 첨가한 친수성 안의료용 콘택트렌즈 재료의 경우, 기본적인 의료용 렌즈의 물성을 만족하였으며 함수율의 큰 변화를 나타내지 않으면서도 우수한 습윤성과 자외선 차단효과를 증가시키는 결과를 보였다.

교호흡착법에 의해 제조된 초친수 박막 특성 (Characterization of superhydrophilic thin films fabricated by a layer-bylayer self-assembly method)

  • 김진호;황종희;임태영;장장훈;김세훈
    • 한국결정성장학회지
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    • 제20권4호
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    • pp.168-172
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    • 2010
  • 양전하를 갖는 poly(allylamine hydrochloride)(PAH)와 음전하를 갖는 poly(acrylic acid)(PAA) 전해질 폴리머를 사용하여 layer-by-layer(LBL) self-assembly 방법에 의해 초친수 특성을 갖는 박막을 제조하였다. PAH/PAA 박막의 밀착강도를 증가시키기 위하여 glutaraldehyde(GA) 수용액을 이용하여 amine-aldehyde의 화학반응에 따른 박막의 표면구조 변화, 막두께, 투과율, 접촉각, 밀착강도 특성을 측정하였다. PAH와 PAA 용액 침적 사이에 기판을 GA 수용액에 침적함으로써 박막의 두께는 감소하였지만 밀착강도는 2배 이상 증가하였다. 밀착강도의 증가는 PAH 와 GA의 amine-aldehyde의 화학반응에 의한 결과라는 것을 fourier transform infrared(FT-IR) spectroscopy를 사용하여 확인하였다. 제조된 PAH/PAA and PAH/GA/PAA 박막은 물 접촉각 $5^{\circ}$이하의 초친수 박막 특성을 보여주었고, 550 nm 파장에서 91.3% 이상의 높은 투과율을 나타내었다.