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http://dx.doi.org/10.6111/JKCGCT.2010.20.5.227

Fabrication of super hydrophilic TiO2 thin film by a liquid phase deposition  

Jung, Hyun-Ho (Korea Institute of Ceramic Engineering and Technology, Electronic & Optic Material Center)
Kim, Jin-Ho (Korea Institute of Ceramic Engineering and Technology, Electronic & Optic Material Center)
Hwang, Jong-Hee (Korea Institute of Ceramic Engineering and Technology, Electronic & Optic Material Center)
Lim, Tae-Young (Korea Institute of Ceramic Engineering and Technology, Electronic & Optic Material Center)
Choi, Duk-Gun (Korea Institute of Ceramic Engineering and Technology, Electronic & Optic Material Center)
Abstract
Super hydrophilic $TiO_2$ thin films with photocatalytic property were successfully fabricated on a glass substrate by liquid phase deposition (LPD). The $TiO_2$ thin film formed nano particles on a surface at $70^{\circ}C$. As an immersion time in $TiF_4$ solution increased, the thickness of thin films gradually increased. $TiO_2$ thin film showed a water contact angel of below ca. $5^{\circ}$ and the transmittance of ca. 75~90 % in visible range. In addition, $TiO_2$ thin film showed the photocatalytic property to decompose methyl orange solution by the illumination of UV light. The surface morphologies, optical properties and contact angel of prepared thin films with a different immersion time were measured by field emission scanning electron microscope (FE-SEM), atomic force microscope (AFM), UV-Vis spectrophotometer and contact angle meter.
Keywords
$TiO_2$; Thin film; Super hydrophilic; Photocatalyst; LPD;
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1 M. keshmiri, M. Mohseni and T. Troczynski, "Development of novel $TiO_{2}$ sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation", Appl. Catal. B: Environ. 53 (2004) 209.   DOI   ScienceOn
2 K.S. Yeung and Y.W. Lam, "A simple chemical vapour deposition method for depositing thin $TiO_{2}$ films", Thin Solids Films 109 (1983) 169.   DOI   ScienceOn
3 J.H. Kim and S. Shiratori, "Characterization of $TiO_{2}$/ Polyelectrolyte thin film fabricated by a layer-by-layer self-assembly method", Jpn. J. Appl. Phys. 44 (2005) 7588.   DOI
4 Y. Tsuge, J.H. Kim, Y. Sone, O. Kuwaki and S. Shiratori, "Fabrication of transparent $TiO_{2}$ film with high adhesion by using self-assembly method: Application to super-hydrophilic film", Thin Solid Films 516 (2008) 2463.   DOI   ScienceOn
5 E.T. Fitzgibbons, K.J. Sladek, W.H. Hartwig and J. Electrochem, "$TiO_{2}$ film properties as a function of processing temperature", J. Electrochem. Soc. 119 (1972) 735.   DOI
6 R. Wang, K. Hashimoto, A. Fujishima, M. Chikni, E. Kojima, A. Kitamura and M. Shimohigoshi, "Photogeneration of highly amphiphilic $TiO_{2}$ surfaces", Advanced Material 2 (1998) 135.
7 F. Saylkan, M. Asilturk, P. Tater, N. Kiraz, S. Sener, E. Arpac and H. Saykan, "Photocatalytic performance of Sn-doped $TiO_{2}$", Materials Research Bulletin 43 (2008) 127.   DOI   ScienceOn
8 M. Takeuchi, T. Itoh and H. Nagasaka, "Dielectric properties of sputtered $TiO_{2}$ films", Thin Solids Films 51 (1978) 83.   DOI   ScienceOn
9 P. Chrysicopoulou, D. Davazoglou, Chr. Trapalis and G. Kordas, "Optical properties of very thin (< 100 nm) solgel $TiO_{2}$", Thin Solid Films 323 (1998) 188.   DOI   ScienceOn