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검색결과 842건 처리시간 0.025초

활성탄에 의한 Reactive Blue 4 염료의 흡착에 대한 등온선, 동력학 및 열역학적 특성 (Characteristics of Isotherm, Kinetic, and Thermodynamic Parameters for Reactive Blue 4 Dye Adsorption by Activated Carbon)

  • 이종집
    • 청정기술
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    • 제26권2호
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    • pp.122-130
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    • 2020
  • 입상 활성탄에 대한 reactive blue 4 (RB 4) 의 등온흡착과 동력학적, 열역학적 파라미터에 대해 활성탄의 양, pH, 초기농도, 접촉시간, 온도를 흡착변수로 하여 조사하였다. 활성탄에 의한 RB 4 염료의 흡착은 pH 7을 기점으로 양쪽으로 흡착 백분율이 증가하는 concave 모양을 나타내었다. 등온흡착자료는 Langmuir, Freundlich, Temkin 등온흡착식에 적용하였다. Freundlich과 Langmuir 등온흡착식이 모두 잘 맞았다. 계산된 Freundlich 분리계수(1/n = 0.125 ~ 0.232)과 Langmuir 분리계수(RL = 1.53 ~ 1.59) 으로부터 활성탄이 RB 4를 효과적으로 처리할 수 있다는 것을 알 수 있었다. Temkin의 흡착열관련상수(BT = 17.611 ~ 29.010 J mol-1)는 이 공정이 물리흡착임을 나타냈다. 동력학적 실험으로부터 흡착공정은 유사 이차 반응속도식에 잘 맞았다. 입자 내 확산식에 대한 결과는 표면확산을 나타내는 두 번째 직선의 기울기보다 입자내 세공확산을 나타내는 첫 번째 직선의 기울기가 작게 나타나서 입자내 세공확산이 속도지배단계인 것을 확인하였다. Gibbs 자유에너지 변화(ΔG = -3.262 ~ -7.581 kJ mol-1)와 엔탈피 변화(ΔH = 61.08 kJ mol-1)은 각각 흡착공정이 자발적 공정 및 흡열과정임을 나타내었다.

서로 다른 스캔 방식을 이용하여 CAD/CAM에 의해 제작된 코핑의 변연 및 내면의 적합성 (Marginal and Internal Fit of Copings Made by CAD/CAM using Different Scanning Methods)

  • 조영범;정재헌;김희중
    • 구강회복응용과학지
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    • 제29권4호
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    • pp.366-376
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    • 2013
  • 구강내 스캔(Group 1), 모델 광학 스캔(Group 2)과 모델 접촉식 스캔(Group 3)방식으로 각각 zirconia 코핑을 제작하여 광학 현미경으로 적합성을 관찰하였다. 측정항목은 변연오차(absolute marginal discrepancy;AMD), 변연간극(marginal gap; MG), 측방간격(gap of axial wall; GA), 선각간격(gap of line angle; GL)와 교합간격(gap of occusal surface; GO)이었으며, 결과는 아래와 같았다. 1. Group 1, Group 2, Group 3의 평균 AMD는 각 각 $141.21{\pm}42.94{\mu}m$, $140.63{\pm}31.64{\mu}m$, $109.37{\pm}28.42{\mu}m$이고, Group1, Group 2, Group 3의 MG는 각 각 $82.52{\pm}43.99{\mu}m$, $90.28{\pm}27.93{\mu}m$, $66.55{\pm}28.77{\mu}m$였다. AMD와 MG는 각 그룹에서 통계학적으로 유의한 차이를 보여주지 않았다(Anova test, P>0.05). 2. Group 2의 GA가 Group 1과 Group 3에 비해 통계학적으로 유의하게 적은 수치를 나타내었다(Anova test, P<0.05). 3. Group 1의 GL과 GO가 다른 그룹에 비해 통계학적으로 높은 수치를 나타내었다(Mann-whitney test(P<0.05). 세 가지 스캔 방식으로 제작된 zirconia 코핑은 세라믹 보철의 가장 중요한 평가 요소인 AMD와 MG에서 서로 통계학적 차이를 보이지 않았다.

인천광역시 지하철 역사 내 지하수 및 수돗물의 라돈 위해성 검토 (Radon Hazard Review of Spilled Groundwater and Tap Water in Incheon Metropolitan City Subway Station)

  • 이유상;이상복;강민석;정동하;김진홍;오윤식;최세린;박정수;김성철
    • 대한방사선기술학회지:방사선기술과학
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    • 제44권6호
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    • pp.671-677
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    • 2021
  • Interest in the everyday hazards of radon has recently increased as such, this study attempted to examine the dangers of radon in spilled groundwater by comparing the radon concentrations of the drained groundwater and tap water used in recirculating systems in Incheon Subway restrooms. At five stations of Incheon Subway Line 1 and three stations of Line 2, drained groundwater is recirculated and used in restrooms for toilet flushing. Stations restroom tap water for hand washing that used as a control and the measured values of each were compared. With the cooperation of Incheon Transportation Corporation, samples of spilled groundwater and tap water were collected sealed to prevent contact with the air, and a DURRIDGE RAD7 was used as the experimental equipment. The collected samples were subjected to radial equilibration for approximately 3.5 h, at which the radon concentration reached its maximum, and then calculated as 10 measurements using the RAD7 underwater radon measurement mode. In all eight stations, the radon concentration in tap water was lower than the recommended amount. However, in an average of 7 out of the eight stations, the radon concentration in the effluent groundwater was 100 times higher than that in tap water. Since high radon concentrations in groundwater runoff can be harmful to humans, and there is no accurate standard for radon concentrations in domestic water, it is necessary to continuously monitor radon in water and prepare a guidance of recommended values.

동적탄력튜빙 보행훈련 프로그램이 만성 파킨슨병 환자의 자세정렬과 보행능력과 삶의 질에 미치는 영향 : 사례연구 (Effects of Dynamic Tubing Gait Training on Postural Alignment, Gait, and Quality of Life in Chronic Patients with Parkinson's Disease : Case Study)

  • 이동률
    • 한국엔터테인먼트산업학회논문지
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    • 제15권8호
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    • pp.363-377
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    • 2021
  • 본 연구에서는 만성 파킨슨병 환자의 동적탄력튜빙 보행 훈련 (I, II)이 자세정렬, 보행, 삶의 질에 미치는 영향을 조사하였다. 총 3명의 만성 파킨슨병 환자를 모집하여 사례 연구를 시행하였다(Hoehn 및 Yahr 1-3단계 각 1명). 동적탄력튜빙 보행 훈련 (I 및 II)은 파킨슨병 환자에게 하루 30분, 주 5일, 5주 동안 25세션 적용되었다. 본 연구의 효과를 알아보기 위해, 자세정렬검사, 근 활성도검사, 보행분석 및 파킨슨병 환자의 삶의 질을 평가하였다. Dynamic tubing 보행 훈련(I, II) 중재 후 몸통 굽힘은 감소되었다. 또한 초기 접촉기(IC)에서 중간 디딤기(Mst)까지 보행 시 넙다리네갈래근, 뒤넙다리근, 앞정강근(TA)의 근 활성도가 증가하고 장딴지근의 근활성도가 감소하였다. 척추세움근(ES T12, L3)의 근활성도는 H&Y I, III 단계에서 증가하고 H&Y II 단계에서 감소하였다. 압력 중심(COP) 매개변수인 보행선의 길이, 한 발 지지선, 앞/뒤 위치, 좌우대칭 값이 개선되었다. 시공간 보행 매개변수인 보폭, 보폭, 의 속도는 증가하고 분당걸음수는 감소되었다. 나아가 파킨슨 병 환자의 삶의 질도 개선되었다. 이러한 연구 결과를 바탕으로 동적탄력튜빙 보행 훈련 (I 및 II)은 약물 내성이 절반으로 감소된 5년 이상된 만성 파킨슨병 환자의 자세, 보행, 삶의 질을 개선하기 위한 새로운 접근 방식으로 적용될 수 있을 것이다.

방향족 유기화합물의 가스상 시료를 이용한 피복류의 흡착특성 비교에 대한 예비연구 (A preliminary study of sorptive characteristics of aromatic volatile organic compounds (VOC) on clothing materials)

  • 김기현;임문순;박신영;홍윤정;최여진;이유선;김성덕;남상호;옥준석
    • 분석과학
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    • 제19권3호
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    • pp.255-262
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    • 2006
  • 본 연구에서는 VOC가 옷감이나 물질소재와 접촉하여 흡착손실하는 경향을 평가하고자 하였다. 이를 위하여 필터홀더에 필터의 형식으로 비교대상 소재를 장착하고 이들에 VOC 가스를 흘려주는 방식으로 화합물의 흡착손실반응을 평가할 수 있는 기법의 적용 가능성을 다각도로 평가하였다. 테플론 소재의 필터는 양호한 안정성이나 재현성을 보여 주었다. 이러한 시스템에 각각의 소재(글래스 파이버, 면, 나일론)를 장착한 상태로 벤젠, 톨루엔, 자일렌이 혼합된 가스를 흘려 주면서 각각의 검량선을 작성하였다. 본 연구의 결과에 의하면, 각각의 소재 및 VOC 성분별로 뚜렷한 흡착특성을 확인할 수 있었다. 소재들 중에서는 글래스 파이버 < 면 < 나일론의 순서로 그리고 성분별로는 벤젠 < 톨루엔 <자일렌의 순서로 흡착손실이 증가하는 양상이 뚜렷하게 나타났다. 그 결과, 재질이나 화학물질의 특성과 같은 변수가 동시에 흡착손실의 경향성을 결정짓는다는 결론에 도달하였다.

도시형 자기부상열차 분기기 구간의 제3궤조 전차선 시스템 개발 (The Development of Third-Rail System Applied to Turn-out Section for Urban Maglev)

  • 민병찬;허영태;홍두영;이원주;조수연;정남철
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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    • pp.3046-3051
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    • 2011
  • The third-rail system is an important device supplying power directly to the Maglev train through physical contact with the collecting shoe. It is directly related to safety and reliability for the running of Maglev. However, most the third-rail system used in Korea depend on foreign product or technologies, Korea Urban Maglev in the development of appropriate power feeding is urgent. In particular, the turnout section is the weakness point in the system because bending force by turnout section movement and fatigue caused by repetitive motion as well as the expansion by temperature, the forces by Maglev collecting shoe is added th the third-rail. Therefore, this paper proposes the third-rail system appropriate for Korean Urban Maglev of turnout section. To verify the structural stability of POSCO ICT third-rail system, the finite element analysis and physical testing was performed. The third-rail is fixed on each side of the turn-out section steel structure by epoxy insulation supporter and the integral behaviors are occurred. Therefore, the maximum horizontal displacements of each support are investigated and then, it is applied to finite element model of the third-rail to investigate the moments and stress. Also, the bending test about one million times and Expansion Joint for the third-rail was performed. The third-rail system safety and reliability was identified by test line on Korea Institute of Machinery & Materials in Deajeon for under the actual usage environment such as the Maglev and turn-out operation.

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Surface Preparation of III-V Semiconductors

  • 임상우
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.86.1-86.1
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    • 2015
  • As the feature size of Si-based semiconductor shrinks to nanometer scale, we are facing to the problems such as short channel effect and leakage current. One of the solutions to cope with those issues is to bring III-V compound semiconductors to the semiconductor structures, because III-V compound semiconductors have much higher carrier mobility than Si. However, introduction of III-V semiconductors to the current Si-based manufacturing process requires great challenge in the development of process integration, since they exhibit totally different physical and chemical properties from Si. For example, epitaxial growth, surface preparation and wet etching of III-V semiconductors have to be optimized for production. In addition, oxidation mechanisms of III-V semiconductors should be elucidated and re-growth of native oxide should be controlled. In this study, surface preparation methods of various III-V compound semiconductors such as GaAs, InAs, and GaSb are introduced in terms of i) how their surfaces are modified after different chemical treatments, ii) how they will be re-oxidized after chemical treatments, and iii) is there any effect of surface orientation on the surface preparation and re-growth of oxide. Surface termination and behaviors on those semiconductors were observed by MIR-FTIR, XPS, ellipsometer, and contact angle measurements. In addition, photoresist stripping process on III-V semiconductor is also studied, because there is a chance that a conventional photoresist stripping process can attack III-V semiconductor surfaces. Based on the Hansen theory various organic solvents such as 1-methyl-2-pyrrolydone, dimethyl sulfoxide, benzyl alcohol, and propylene carbonate, were selected to remove photoresists with and without ion implantation. Although SPM and DIO3 caused etching and/or surface roughening of III-V semiconductor surface, organic solvents could remove I-line photoresist without attack of III-V semiconductor surface. The behavior of photoresist removal depends on the solvent temperature and ion implantation dose.

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마케팅 믹스를 활용(活用)한 의류(衣類)브랜드 웹사이트 분석(分析) -유니섹스 브랜드를 중심(中心)으로- (A Study on Website Analysis of apparel Brand through Marketing Mix -Focusing on Unisex Brand-)

  • 이미경;나수임
    • 패션비즈니스
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    • 제11권4호
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    • pp.69-81
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    • 2007
  • This study, for the purpose of comparing and analyzing 23ea of national unisex apparel brands website consists of product, price, promotion and place divided by marketin gmix. Based of theoretical study and pre-research about the marketing mix, we made the classification standard for the marketing mix and analyzed the unisex apparel brand website according to 4P's individual item and the result was appeared like this. First of all, in the product section, this study provide information about product introduction/guidance, a product figure for item, introduction for new items, propose for coordination and brand introduction/information. Secondly, in the price part, almost apparel brands are provide their product's image, or present their goods photo with price, or displayed through the banner advertisement of discount or special price. Thirdly, For the marketing promotion part, compare to the other component in the most of apparel brand's website, marketing promotion has more section than the other marketing mix. And, especially, various events and customer service space has more weight than the others. Forth, in the place section, it's focused on the information of shopping mall location, contact number, address, and on-line shopping mall. In Conclusion, when the most of apparel brands are doing internet marketing, they're concern to product and promotion, but price and place needs more supplement in the unisex apparel brand's marketing mix.

정밀 공작기계 안내면의 평행도 측정 (Parallelism Measurement for Guide Rails of Precision Machine Tools)

  • 황주호;박천홍;;김승우
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.792-795
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    • 2005
  • The guide-ways of precision machine tools are one of important element of machine tools. It has usually a pair of surfaces for constraint of one direction with bearing. In the case of precision machine tools, non-contact bearing such as hydrostatic bearing and aerostatic bearing is adopted usually. In this case, profiles of rails has effect on straightness and the clearance of bearing has effect on stiffness of guide way, which changes to higher if clearance changes to smaller. The clearance is varied along moving table according to relative distance of pair of rails. The relative distance of pair of rail can be divided by three properties. First and second properties are straightness of each pair of rail and bearing pad. And, third is parallelism about pair of rails and pairs of bearing pad. There are several methods for measuring straightness of each surface such as reversal method, sequential two point method, and way straightness. These straightness measuring methods are always acquiring deviation of profile from eliminating linear fitted inclined line and don't have the information of parallelism. Therefore, to get the small clearance for high stiffness, the straightness of rail and bearing pad and parallelism about pair of rails and pair of bearing pads are measured for correction such as regrinding, reassembling and lapping. In this research, new and easy method for measuring parallelism of pair of rails is suggested. Two displacement probe and sensor stage, which is carry on the displacement sensor, are needed. The simulation and experiment was accomplished about pair of horizontal guide way to confirm the measurement of parallelism. And, the third probe is added to measure the straightness of each rails by sequential two point method. From the estimation of combined these two methods, it is confirmed that the profiles of a pairs of rails can be measured.

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EGL 공정용 컨덕터 롤 폴리셔 수명 예측에 관한 연구 (A Study on Wear-Life Prediction of Conductor Roll Polisher in EGL Polishing Process)

  • 구자경;고종민;구태완;강범수
    • 한국정밀공학회지
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    • 제28권9호
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    • pp.1062-1069
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    • 2011
  • In electro-galvanizing line to manufacture the electro-galvanized steel sheet, polishing system is required to maintain clean surface of conductor roll and to secure the quality of the steel sheet. At the same time, prediction and decision of the replacement cycle for felt material and its brush installed in the polishing system is also important because the brush is directly contacted on the conductor roll surface. In this study, the polishing system has been designed which the brush is repetitive translating according to the longitudinal direction of the conductor roll. Furthermore, the prediction on the wear-life of the felt material used for the brush is performed using the contact pressure extracted by finite element analysis. And to verify the predicted wear-life of the felt material, the experimental study is also carried out. From the comparison result between the predicted and the measured wear-life of the felt material, it is presented that the wear-life and the replacement cycle of the felt material are well predicted by considering a wear compensation factor, and the wear compensation factor is useful and reasonable.