• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.73-74
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• 2022

The corrosion inhibitive effect of a new hydrazone-based heterocyclic compound for steel in simulated concrete pore solution with 3.5 wt.% sodium chloride was investigated by experimental and computational techniques. Electrochemical studies, up to 30 days of immersion, and surface analysis (X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscope (SEM)) were performed to assess the corrosion protection abilities of investigated compound for steel rebar. Results showed that adding the organic compound to the chloride contaminated concrete pore solution decreased the corrosion rate of the steel rebar thanks to the effective adsorption of inhibitor molecules. After 30 days of immersion of steel rebar in inhibited chloride contaminated synthetic concrete pore solution, the inhibition efficiency exceeded 80% at low concentration of 1 mmol/L. Computational studies by Density Functional based Tight Binding (DFTB) method revealed the formation of covalent bonds between the hydrazone molecule and the iron surface.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.255-256
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• 2023

The development of corrosion inhibitors with outstanding performance is a never-ending and complex process engaged in by researchers, engineers and practitioners. Computational assessment of organic corrosion inhibitors performance is a crucial step towards the design of new task-pecific materials. Herein, electronic features, adsorption characteristics and bonding mechanisms of two pyridine oximes, namely 2-pyridylaldoxime (2POH) and 3-pyridylaldoxime (3POH) with the iron surface were investigated using molecular dynamics (MD), and self-consistent-charge density-unctional tight-binding (SCC-DFTB) simulations. SCC-DFTB simulations revealed that 3POH molecule can form covalent bonds with iron atoms in its neutral and protonated states, while 2POH molecule can only bond with iron through its protonated form, resulting in interaction energies of -2.534, -2.007, -1.897, and -0.007 eV for 3POH, 3POH+, 2POH+, and 2POH, respectively. Projected density of states (PDOSs) analysis of pyridines-Fe(110) interactions indicated that pyridine molecules chemically adsorbed on the iron surface.

• Proceedings of the KOR-KST Conference
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• 1995.05a
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• pp.239-250
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• 1995

With speeding up the process of being international municipality, the gravity of lacking parking lots in Shanghai urban area, which directly blocks the traffic in the city, has been revealed. This thesis analyses present automobiles parking capability and forecasts the future's needs for the city. To solve the problem, the concept could be to expand parking areas in city center recently to relax the tention and to do thoughtful planning in the near future on the foundation of fully consideration the trend. The municipal government has to set up policy properly, amplify regulations, strenthern the administration and open up a path to raise founds. Berween road system administration which is dynamic and parking lot system administration which is static, there are a knot on macroscopic meaning and an interference as well. The coordination of these two systems would be reflested on the effects of whole municipal traffic adminisration. Basically, public parking lots are city's foundal facilities, just like roads, bridges, etc. The main problems now in Shanghai are large parking space demands, insufficient facilities, cheap parking expenses comparing with the cost of parking lots construcion and poor administration. According to the forecast on social economy development, there will be 580 thousand automobiles in Shanghai by the year 2000, and the amount of private cars will increase greatly. The frequency of automobiles going out will be 1.45 million per day. Public parking lots being able to afford 105 thousand units are needed. To satisfy the demands, the recent aim of planning should be speed up the parking lots construction, the planning objective in next period should be developing reasonably and exceed the demands properly. In order to realize the planning objective, the government has to formulate correct policy and amplify administration regulations. The government has to adopt both administration and economy means, including charging parking people reasonably, collect necessary taxes, bringing the parking lots planning into general municipality planning, opening up an effective path to raise founds, such as set up founds for parking lots construction, issue bonds and stocks, get loans at home and abroad, etc.

• Journal of the Korea Furniture Society
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• v.19 no.2
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• pp.106-110
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• 2008

This paper investigated and validated the mechanisms and principles for constructing reticular structure of plant fiber through frothing solution approach. After process, plant fibers became low-density reticular-structured block with all properties meeting Chinese standards for cushion packing materials. The bonds between fibers acted as knots in a truss and were strong enough to keep space occupied by bubbles in the frothing solution from shrinking in the subsequent draining process. The formation of the reticular structure depends mainly on the pressure difference between inside and outside bubble, the effect of surface adsorbent force on bubble film, and hydrogen bond among fiber hydroxide.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.333-341
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• 2006

The concept for the decolorization in biological dye wastewater treatment systems is based on anaerobic treatment, for the reductive cleavage of the dyes' azo linkages, in combination with aerobic treatment, for the degradation of the products from azo dye cleavage, aromatic amines. Batch tests were conducted to examine the conditions and the factors affecting biological treatment of dye wastewater. From the tests, the removal efficiencies of organics and colors of dyeing wastewater were improved to $COD_{Cr}$ 27% and color 9% by injecting 10% of the domestic wastewater as a cosubstrate, and $COD_{Cr}$ 30%, color 22% with 30% injection of domestic wastewater. Therefore it was proved that decolorization efficiency is demonstrated with domestic wastewater as a cosubstrate. The analysis of aromatic amines in wastewater showed that decolorization was achieved by cometabolism while aromatic amines were produced by cleavage of azo bonds under anaerobic conditions and these products were removed in an aerobic tank subsequently.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1177-1181
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• 2014

A 2D grid-like (4, 4)-connected topology coordination polymer, $[Co(BTA)_2(H_2O)_2]_n$ (1), where HBTA = 2-(1H-benzotriazol-1-yl)acetic acid, has been synthesized by hydrothermal method and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and surface photovoltage spectroscopy (SPS). X-ray diffraction analyses indicated that 1 displays octahedral metal centers with secondary building units (SBUs) [$Co(BTA)_2(H_2O)_2$] bridged by the $BTA^-$ ligands. In the crystal, the 2D supramolecular architecture is further supported by $O-H{\cdots}O$, $O-H{\cdots}N$, $C-H{\cdots}O$ hydrogen bonds and ${\pi}{\cdots}{\pi}$ stacking interactions. The SPS of polymer 1 indicates that there are positive response bands in the range of 300-600 nm showing photo-electric conversion properties. There are good relationships between SPS and UV-Vis spectra.

• Journal of the Korean Institute of Landscape Architecture
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• v.46 no.6
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• pp.1-16
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• 2018

The decline in the construction industry has led to a decrease the profitability of small and medium-sized landscape contractors. To relieve this situation, small and medium-sized landscape contractors have continued to proactively find ways to enter global construction markets. However, many small and medium-sized landscape contractors face risks due to their lack of capacity and insufficient preparations to extend the business abroad. Thus, this study aims to analyze the current condition of the Vietnamese construction market and the related risk factors. It then suggests strategies to improve the small and medium-sized landscape contractors' competitiveness in that market. We investigated the business climate and analyzed risk factors. Finally, we developed expansion strategies and conducted in-depth interviews with six overseas construction professionals. The study results first showed that efforts to improve infrastructure and the increased demand for housing in Vietnam will lead to more opportunities for small and medium-sized landscape contractors entering the Vietnamese construction market. However, changes in the Vietnamese business climate may act as a variable. Second, we found that small and medium-sized landscape contractors' risk factors are mainly related to laws and regulations, government finance, market fluctuations, public administration system, minimum wage increases, financing and bonds, contracting, trees and materials, and design errors. Finally, small and medium-sized landscape contractors are required to consider the following when seeking to enter the Vietnamese construction market: short-term strategy and mid-to-long-term strategy. This study will be used as the basis for small and medium-sized landscape contractors to plan to enter the Vietnamese construction market and to contribute to the expansion of the global construction market in the landscape industry.

• Journal of Sensor Science and Technology
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• v.29 no.2
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• pp.89-92
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• 2020

Polytetrafluoroethylene (PTFE) fibers are widely used in the textile industry, filter media, membrane distillation, electronic appliances, and construction. In this study, PTFE-polyethylene oxide (PEO) fibrous membranes were fabricated by emulsion electrospinning; subsequently, pure PTFE nanofibers were obtained via sintering. PTFE-PEO electrospinning solutions were prepared using different weight ratios to determine the optimized condition. As the ratio of the PEO increased, the fiber structure improved. Scanning electron microscopy and Fourier-transform infrared spectroscopy observations indicate that PEO is removed and PTFE fused gradually to form bonds among them during sintering. The obtained pristine PTFE membrane demonstrated hydrophobicity at 143.6° water contact angle and oleophilicity at 0° oil contact angle, which is known to be utilized for oil/water separation. A simple separation experiment was performed to remove oil droplets from water. The PTFE membrane exhibited good chemical stability and a high surface-area-to-volume nanofiber ratio. These excellent properties suggest that it is applicable to oil/water separation in harsh chemical environments.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.09a
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• pp.241-252
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• 2010

This study investigates the application of dilatometer test for evaluating the deformation characteristics of granular soil. $K_D$ is the most sensitive to the stress history among CPT and DMT measurements, and $E_D$ and $q_c$ are observed to be similarly affected by the stress history. The coefficient of at-rest earth pressure($K_0$) is an indirect measure evaluating the stress history of granular soil. A relation using only DMT indices provides appropriate prediction of $K_0$ values. Although penetration of dilatometer inevitably induces the failure of cementation bonds, $E_D$ reflects the deformation characteristics of undamaged cementation relatively well. Therefore, a slightly better prediction of M value for cemented sand is achieved by using $E_D$ rather than $q_c$. Because of the weaker particle strength of calcareous sand compared than quartz sand, the majority of sand particles adjacent to dilatometer probe will be crushed during penetration. The particle crushing will induce the less contraction of the dilatometer membrane during penetration, consequently, the smaller $K_D$ and $E_D$ of calcareous sand.

• Geomechanics and Engineering
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• v.8 no.5
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• pp.707-726
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• 2015

This paper investigates the time dependent behaviour of Haarajoki test embankment on soft structured clay deposit. Half of the embankment is constructed on an area improved with prefabricated vertical drains, while the other half is constructed on the natural deposit without any ground improvement. To analyse the PVD-improved subsoil, axisymmetric vertical drains were converted into equivalent plane strain conditions using three different approaches. The construction and consolidation of the embankment are analysed with the finite element method using a recently developed anisotropic model for time-dependent behaviour of soft clays. The constitutive model, namely ACM-S accounts for combined effects of plastic anisotropy, interparticle bonding and degradation of bonds and creep. For comparison, the problem is also analysed with isotropic Soft Soil Creep and Modified Cam Clay models. The results of the numerical analyses are compared with the field measurements. The results show that neglecting effects of anisotropy, destructuration and creep may lead to inaccurate predictions of soft clay response. Additionally, the numerical results show that the matching methods accurately predict the consolidation behaviour of the embankment on PVD improved soft clays and provide a useful tool for engineering practice.