• 제목/요약/키워드: Constituent materials

검색결과 346건 처리시간 0.027초

The effect of nano-sized starting materials and excess amount of Bi on the dielectric/piezoelectric properties of 0.94[(BixNa0.5)TiO3]-0.06[BaTiO3] lead free piezoelectric ceramics

  • Khansur, Neamul Hayet;Ur, Soon-Chul;Yoon, Man-Soon
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.31.1-31.1
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    • 2009
  • In an approach to acclimate ourselves torecent ecological consciousness trend, a lead-free piezoelectric material, bismuth sodium titanate (abbreviated as BNT) based bismuth sodium barium titanate (abbreviated as BNT-BT), was considered as an environment-friendly alternative for a lead based piezoelectric system. Ceramic specimens of0.94[(BixNa0.5)TiO3]-0.06[BaTiO3] (x = 0.500~0.515) compositions were prepared by a modified mixed oxide method. To increase the chemical homogeneity andre action activity, high energy mechanical milling machine and pre-milled nanosized powder has been used. In this method (BixNa0.5)TiO3 (x=0.500~0.515) andBaTiO3 were prepared separately from pre-milled constituent materials at low calcination temperature and then separately prepared BNTX (X=1, 2, 3 and 4) and BT were mixed by high energy mechanical milling machine. Without further calcination step the mixed powders were pressed into disk shape and sintered at $1110^{\circ}C$. Microstructures, phase structures and electrical properties of the ceramic specimens were systematically investigated. Highly dense ceramic specimens with homogenous grains were prepared in spite of relatively low sintering temperature. Phase structures were not significantly influenced by the excess amount Bi. Large variation on the piezoelectric and dielectric properties was detected at relative high excess Bi amounts. When $x{\leq}0.505$, the specimens exhibit insignificant variation in piezoelectric and dielectric constant though depolarization temperature is found to be decreased. Considerable amount of decrease in piezoelectric and dielectric properties are observed with higher excess of Bi amounts ($x{\geq}0.505$). This research indicates the advantages of high energy mechanical milling and importance of proper maintenance of Bi stoichiometry.

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Microstructure-Strengthening Interrelationship of an Ultrasonically Treated Hypereutectic Al-Si (A390) Alloy

  • Kim, Soo-Bae;Cho, Young-Hee;Jung, Jae-Gil;Yoon, Woon-Ha;Lee, Young-Kook;Lee, Jung-Moo
    • Metals and materials international
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    • 제24권6호
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    • pp.1376-1385
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    • 2018
  • Ultrasonic melt treatment (UST) was applied to an A390 hypereutectic Al-Si alloy in a temperature range of $750-800^{\circ}C$ and its influence on the solidification structure and the consequent increase in strength was investigated. UST at such a high temperature, which is about $100^{\circ}C$ above the liquidus temperature, had little effect on the grain refinement but enhanced the homogeneity of the microstructure with the uniform distribution of constituent phases (e.g. primary Si, ${\alpha}-Al$ and intermetallics) significantly refined. With the microstructural homogeneity, quantitative analysis confirmed that UST was found to suppress the formation of Cu-bearing phases, i.e., $Q-Al_5Cu_2Mg_8Si_6$, $Al_2Cu$ phases that form in the final stage of solidification while notably increasing the average Cu contents in the matrix from 1.29 to 2.06 wt%. A tensile test exhibits an increase in the yield strength of the as-cast alloy from 185 to 208 MPa, which is mainly associated with the solute increment within the matrix. The important role of UST in the microstructure evolution during solidification is discussed and the mechanism covering the microstructure-strengthening interrelationship of the ultrasonically treated A390 alloy is proposed.

Self-textured Al-doped ZnO transparent conducting oxide for p-i-n a-Si:H thin film solar cell

  • 김도영;이준신;김형준
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.50.1-50.1
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    • 2009
  • Transparent conductive oxides (TCOs) play an important role in thin-film solar cells in terms of low cost and performance improvement. Al-doped ZnO (AZO) is a very promising material for thin-film solar cellfabrication because of the wide availability of its constituent raw materials and its low cost. In this study, AZO films were prepared by low pressurechemical vapor deposition (LPCVD) using trimethylaluminum (TMA), diethylzinc(DEZ), and water vapor. In order to improve the absorbance of light, atypical surface texturing method is wet etching of front electrode using chemical solution. Alternatively, LPCVD can create a rough surface during deposition. This "self-texturing" is a very useful technique, which can eliminate additional chemical texturing process. The introduction of a TMA doping source has a strong influence on resistivity and the diffusion of light in a wide wavelength range.The haze factor of AZO up to a value of 43 % at 600 nm was achieved without an additional surface texturing process by simple TMA doping. The use of AZO TCO resulted in energy conversion efficiencies of 7.7 % when it was applied to thep-i-n a-Si:H thin film solar cell, which was comparable to commercially available fluorine doped tin oxide ($SnO_2$:F).

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단일 탐침법을 이용한 수평형 지중열교환기 뒤채움재의 열확산계수 산정 (Thermal Diffusivity Evaluation of Backfilling Materials for Horizontal Ground Heat Exchanger Using Single-Probe Method)

  • 손병후;최항석
    • 설비공학논문집
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    • 제23권5호
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    • pp.356-364
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    • 2011
  • Storage and transfer heat in soils is governed by the soil thermal properties and these properties are therefore needed in many engineering applications, including horizontal ground heat exchanger for ground-coupled heat pumps. This paper presents the evaluation results of the thermal diffusivity of soils (silica, quartzite, limestone, sandstone, granite, and two masonry soils used for the trench backfilling materials of the horizontal ground heat exchanger. To assess this thermal property, we (i) measure the soil thermal conductivities using single-probe method and (ii) use the de Vries method of summing the heat capacities of the soil constituents. The results show that the thermal diffusivity tends to increase as dry soil begins to wet, but it approaches a constant value or even decreases as the soil continues to wet. Combined algorithm with and improved model for the thermal conductivity of soils and the constituent equation provides accurate estimates of the soil thermal diffusivity.

${\cdot}$부극 재료의 특성에 따른 리튬이온전지의 용량설계 (Capacity Design of Lithium Ion Battery Based on the Characteristics of Materials)

  • 문성인;도칠훈;윤성규;염덕형
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 1998년도 전지기술 심포지움
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    • pp.7-27
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    • 1998
  • In order to design capacity of lithium ion battery, some calculations were carried out based on the characteristics of materials by the given battery shape and dimension. The principle of design was built by the interpretation of the correlation of material, electrochemical and battery factors. Parameters of materials are fundamental physical properties of constituent such as cathode. separator, anode, current collectors and electrolyte. Electrochemical factor includes potential pattern as a function of specific capacity, specific discharge capacity(or initial irreversible specific capacity or Ah efficiency) as a function of specific charge capacity and material balancing. Parameters of battery are dimension, construction hardware and performance. Battery capacity was simulated for a lithium cobalt dioxide as cathode and a hard carbon as anode to achieve 1100 mAh for the charge limit voltage of 4.2V, the weight ratio(+/-) of 2.4 and ICR18650. A fabricated test cell (ICR18650) which have weight ratio(+/-) of 2.4 discharged to 1093 mAh for the charge limit voltage of 4.2V. The sequential discharge capacity show good correspondence with designed capacity.

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기계적 특성이 우수한 원통형 복합재료 안테나의 설계 및 충격 실험 (Design and Impact Testing of Cylindrical Composite-Antenna-Structures having High Mechanical Performanc)

  • 김동섭;조상현;황운봉;이중희
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 추계학술발표대회 논문집
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    • pp.35-38
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    • 2005
  • The Objective of this work was to design Composite Antenna Structures (CAS) and investigate impact behavior of CAS which was various curvature. This term, CAS, indicates that structural surface becomes antenna. Constituent materials were selected considering electrical properties, dielectric constants and tangent loss as well as mechanical properties. For the antenna performance, microstrip antenna layers inserted into structural layers were designed for satellite communication at the resonant frequency of 12.5 GHz and final demonstration article was. After making five kinds of curved CAS, which radii of curvature are flat, 200, 150, 100, 50 mm. The antenna performance changed in accordance with variation of curvature. The Reflection coefficient was independent of curvature but the gain decreased with the radius of curvature. The impact test equipment was Dyna-8250 drop weight tester. The impact characteristic in accordance with curvature is maximum absorb energy is same each other. The impact energy was 8.5 J. For various Impact energy test, five energy levels 3 J, 5 J, 7 J, 10 J, 20 J were used. The performance of impact damaged antenna was estimated by measuring the return loss and the radiation pattern. It was revealed that the performance of antenna was not related to the impact damage. Because the impactor did not damage the patch directly. CAS have good impact stability for the antenna performance.

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Nonlocal-integro-vibro analysis of vertically aligned monolayered nonuniform FGM nanorods

  • Yuan, Yuan;Zhao, Ke;Zhao, Yafei;Kiani, Keivan
    • Steel and Composite Structures
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    • 제37권5호
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    • pp.551-569
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    • 2020
  • Vibration of vertically aligned-monolayered-nonuniform nanorods consist of functionally graded materials with elastic supports has not been investigated yet. To fill this gap, the problem is examined using the elasticity theories of Eringen and Gurtin-Murdoch. The geometrical and mechanical properties of the surface layer and the bulk are allowed to vary arbitrarily across the length. The nonlocal-surface energy-based governing equations are established using differential-type and integro-type formulations, and solved by employing the Galerkin method by exploiting admissible modes approach and element-free Galerkin (EFG). Through various comparison studies, the effectiveness of the EFG in capturing both nonlocal-differential/integro-based frequencies is proved. A constructive parametric study is also conducted, and the roles of nanorods' diameter, length, stiffness of both inter-rod's elastic layer and elastic supports, power-law index of both constituent materials and geometry, nonlocal and surface effects on the dominant frequencies are revealed.

Microstructure and Consolidation of Gas Atomized Al-Si Powder

  • Hong, S.J.;Lee, M.K.;Rhee, C.K.;Chun, B.S.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.994-995
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    • 2006
  • The microstructure of the extruded Al-20Si bars showed a homogeneous distribution of eutectic Si and primary Si particles embedded in the Al matrix. The grain size of ${\alpha}-Al$ varied from 150 to 600 nm and the size of the eutectic Si and primary Si in the extruded bars was about 100 - 200 nm. The room temperature tensile strength of the alloy with a powder size $<26{\mu}m$ was 322 MPa, while for the coarser powder ($45-106{\mu}m$) it was 230 MPa. With decreasing powder size from $45-106{\mu}m$ to $<26{\mu}m$, the specific wear of all the alloys decreased significantly at all sliding speeds due to the higher strength achieved by ultrafine-grained constituent phases. The fracture mechanism of failure in tension testing and wear testing was also studied.

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Antibacterial Activities of Persimmon Roots-derived Materials and 1,4-Naphthoquinone's Derivatives against Intestinal Bacteria

  • Kim, Hyung-Wook;Lee, Chi-Hoon;Lee, Hoi-Seon
    • Food Science and Biotechnology
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    • 제18권3호
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    • pp.755-760
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    • 2009
  • The growth-inhibiting activities of persimmon roots-derived materials against intestinal bacteria were evaluated and compared with that of 1,4-naphthoquinone as a positive control. The active constituent isolated from persimmon roots was characterized as 5-hydroxy-2-methyl-1,4-naphthoquinone using various spectroscopic analyses. Treatment with 1,4-naphthoquinone at a dose of 1.0 mg/disc strongly inhibited the growth of 6 intestinal bacteria. Furthermore, when the structure-activity relationships of 1,4-naphthoquinone's derivatives were evaluated, 5-hydroxy-2-methyl-1,4-naphthoquinone and 2-methyl-1,4-naphthoquinone were found to strongly inhibit the growth of Clostridium difficile, Clostridium perfringens, and Escherichia coli without adversely affecting the growth of Bifidobacterium adolescentis, Bifidobacterium longum, and Lactobacillus acidophilus. Additionally, 2-hydroxy-1,4-naphthoquinone and 5-hydroxy-1,4-naphthoquinone strongly inhibited the growth of C. difficile and C. perfringens, but did not inhibit the growth of E. coli. Taken together, these results indicate that persimmon roots-derived materials and some of 1,4-naphthoquinone's derivatives could be useful preventive agents against diseases caused by harmful intestinal bacteria.

요철형 금, 백금, 팔라듐 나노플레이트의 촉매성 환원 효율 비교 (Catalytic Reduction Efficiency Comparison between Porous Au, Pt, and Pd Nanoplates)

  • 신우준;김영진;장홍제;박지훈;김영관
    • Composites Research
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    • 제32권2호
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    • pp.85-89
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    • 2019
  • 나노입자에 기반한 화학 촉매 반응 효율성에는 크기, 형태 및 조성이 중요한 영향을 미치는 것으로 알려져 있다. 이에 대한 체계적인 비교를 위해 갈바닉 치환 반응을 통해 100 nm 직경의 요철형 표면 구조를 갖는 금, 백금, 팔라듐 나노플레이트에 대한 정량적인 분석 조건 형성이 가능하였으며, 4-나이트로페놀과 4-나이트로아닐린을 대상으로한 촉매 반응 진행을 분광분석법을 통해 확인할 수 있었다. 이로부터 동일 형태 및 형태에서 구성 원소에 따라 확연히 다른 Pd > Au > Pt의 촉매성 환원 반응 효율을 보임을 관찰할 수 있었으며, 기질의 형태에 따라 추가적인 영향을 받음을 관찰 가능하였다.