• Nuclear Engineering and Technology
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• 제32권4호
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• pp.361-371
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• 2000

The 123Te(p,n)123I, 124Te(p,n)124I and 124Te(p,2n)123I reactions, among the many reaction channels opened, are the major reactions under consideration from a diagnostic purpose because reaction residuals as the gamma emitters are used for most radiophamaceutical applications involving radioiodine. Based on the available experimental data, the absorption cross sections and elastic scattering angular distributions of the proton-induced nuclear reaction on Te isotopes below 60 MeV are calculated using the optical model code APMNK. The transmission coefficients of neutron, proton, deuteron, trition and alpha particles are calculated by CUNF code and are fed into the GNASH code. By adjusting level density parameters and the pair correction values of some reaction channels, as well as the composite nucleus state density constants of the pre-equilibrium model, the production cross sections and energy-angle correlated spectra of the secondary light particles, as well as production cross sections and energy distributions of heavy recoils and gamma rays are calculated by the statistical plus pre-equilibrium model code GNASH. The calculated results are analysed and compared with the experimental data taken from the EXFOR. The optimized global optical model parameters give overall agreement with the experimental data over both the entire energy range and all tellurium isotopes.

• Geomechanics and Engineering
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• 제13권6호
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• pp.907-928
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• 2017

The effects of seepage force and out-of-plane stress on cavity contracting and tunnel opening was investigated in this study. The generalized Hoek-Brown (H-B) failure criterion and non-associated flow rule were adopted. Because of the complex solution of pore pressure in an arbitrary direction, only the pore pressure through the radial direction was assumed in this paper. In order to investigate the effect of out-of-plane stress and seepage force on the cavity contraction and circular tunnel opening, three cases of the out-of-plane stress being the minor, intermediate, or major principal stress are assumed separately. A method of plane strain problem is adopted to obtain the stress and strain for cavity contracting and circular tunnel opening for three cases, respectively, that incorporated the effects of seepage force. The proposed solutions were validated by the published results and the correction is verified. Several cases were analyzed, and parameter studies were conducted to highlight the effects of seepage force, H-B constants, and out-of-plane stress on stress, displacement, and plastic radius with the numerical method. The proposed method may be used to address the complex problems of cavity contraction and tunnel opening in rock mass.

• Structural Engineering and Mechanics
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• 제14권5호
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• pp.595-610
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• 2002

This paper presents an efficiency of various non-conforming (NC) modes in development of a series of new finite elements with the special emphasis on 4-node quadrilateral elements. The NC modes have been used as a key scheme to improve the behaviors of various types of new finite elements, i.e., Mindlin plate bending elements, membrane elements with drilling degrees of freedom, flat shell elements. The NC modes are classified into three groups according to the 'correction constants' of 'Direct Modification Method'. The first group is 'basic NC modes', which have been widely used by a number of researchers in the finite element communities. The basic NC modes are effective to improve the behaviors of regular shaped elements. The second group is 'hierarchical NC modes' which improve the behaviors of distorted elements effectively. The last group is 'higher order NC modes' which improve the behaviors of plate-bending elements. When the basic NC modes are combined with hierarchical or higher order NC modes, the elements become insensitive to mesh distortions. When the membrane component of a flat shell has 'hierarchical NC modes', the membrane locking can be suppressed. A number of numerical tests are carried out to show the positive effect of aforementioned various NC modes incorporated into various types of finite elements.

• 한국정보통신학회논문지
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• 제18권5호
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• pp.1096-1102
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• 2014

적외선 조명을 이용한 간접시선추적 시스템에서는 촬영된 이미지에서 동공에 반사된 조명의 위치에 대한 캘리브레이션이 필수적이다. 하지만 안구의 크기나 머리의 위치에 따라 달라질 수도 있는 변수가 캘리브레이션 과정에서 정의된 상수로 계산에 포함되어 있어 오차를 감소시키는데 한계가 있다. 본 논문은 적외선 조명을 사용하면서도, 사용자 캘리브레이션 과정을 생략할 수 있는 방법을 연구한다. 반사각에 의한 글린트(glint)위치 차이에 영향을 받지 않게 하면서, 시스템의 모델과 시선 계산은 단순하게 하여 실시간 연산이 가능하도록 하는 것이 목표이다.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1397-1402
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• 2014

The complete active space self-consist field method followed by the internally contracted multireference configuration interaction method has been used to compute the potential energy curves of $X^2\prod_g$, $a^4\prod_u$, $A^2\prod_u$, $b^4\sum_{g}^{-}$, and $B^2\sum_{g}^{-}$ states of $S{_2}^+$ cation with large correlation-consistent basis sets. Utilizing the potential energy curves computed with different basis sets, the spectroscopic parameters of these states were evaluated. Finally, the transition dipole moment and the Franck-Condon factors of the transition from $A^2\prod_u$ to $X^2\prod_g$ were evaluated. The radiative lifetime of $A^2\prod_u$ is calculated to be 887 ns, which is in good agreement with experimental value of $805{\pm}10$ ns.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1385-1390
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• 2014

Hydrofluoroethers (HFEs) are developed as a suitable for the replacement of environmentally hazardous CFCs and are termed as third generation refrigerants. One of the major products of decomposition of HFEs in the atmosphere is a fluoroester. The present study relates to the OH and Cl initiated oxidation of $CF_3C(O)OCH_2CF_3$ formed from the oxidation of HFE-356mff. The latter is used as a solvent in the industry and reaches the atmosphere without any degradation. Kinetics of the titled molecule has been studied at MPWB1K/6-31+G(d,p) level of theory. Single point energy calculations have been made at G2(MP2) level of theory and barrier heights are determined. The rate constants are calculated using canonical transition state theory. Tunnelling correction are made using one-dimensional Eckart potential barrier. The rate constant calculated during the present study are compared with the experimental values determined using relative rate method and FTIR detection technique.

• Steel and Composite Structures
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• 제34권1호
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• pp.75-89
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• 2020

The current paper illustrates the effect of in-plane varying compressive force on critical buckling loads and buckling modes of sandwich composite laminated beam rested on elastic foundation. To generalize a proposed model, unified higher order shear deformation beam theories are exploited through analysis; those satisfy the parabolic variation of shear across the thickness. Therefore, there is no need for shear correction factor. Winkler and Pasternak elastic foundations are presented to consider the effect of any elastic medium surrounding beam structure. The Hamilton's principle is proposed to derive the equilibrium equations of unified sandwich composite laminated beams. Differential quadrature numerical method (DQNM) is used to discretize the differential equilibrium equations in spatial direction. After that, eigenvalue problem is solved to obtain the buckling loads and associated mode shapes. The proposed model is validated with previous published works and good matching is observed. The numerical results are carried out to show effects of axial load functions, lamination thicknesses, orthotropy and elastic foundation constants on the buckling loads and mode shapes of sandwich composite beam. This model is important in designing of aircrafts and ships when non-uniform compressive load and shear loading is dominated.

• 해양환경안전학회지
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• 제26권5호
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• pp.531-541
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• 2020

우리나라 서남해 연안역에서 해수유동을 재현하기 위해 모든 분조를 포함하고 절점변조진폭, 위상보정인자 및 천문인수를 적용한 완전한 형태의 실조석(Real Tide)을 도입하였다. 실조석으로 해수유동을 재현한 결과, 조석의 관측치와 계산치의 상관계수는 1.0으로 진폭 및 위상의 정확도가 매우 우수하였고, U성분 및 V성분으로 구분하여 나타낸 조류는 각각 평균 0.883과 0.936의 높은 상관도를 보여 실조석으로 재현하는 것이 타당한 것으로 보였다. 그리고 잔차류의 관측치와 계산치의 차는 평균 0.006 m/s로 유의미하지 않았고, 그 진행방향은 서로 매우 유사하였다. 그리고 본 연구의 계산결과에서 관측치와 계산치 간에 나타난 유속성분 오차는 주로 고파랑이나 폭풍을 비롯한 남풍계열의 강한 바람과 같은 기상적 요인에 의한 것이 원인으로 분석되었다. 향후 해수유동 수치모형 실험에서 하나의 변수로 작용하는 기상적 요인을 고려하고 본 연구의 실조석을 재현한다면 계산결과는 더욱 향상될 것으로 기대된다.

• 한국환경농학회지
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• 제37권1호
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• pp.41-48
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• 2018

BACKGROUND: This study was performed to calculate the biological half-lives and regression coefficient of bistrifluron and cyenopyrafen dissipation in peach and to estimate the Pre-Harvest Residue Limits (PHRLs). METHODS AND RESULTS: The bistrifluron and cyenopyrafen were prepared on the basis of good agricultural practice for peach and treated with a single application. Peaches were harvested at 0, 1, 3, 5, 7, 10 and 14 days after application, prepared for analysis, and analyzed by HPLC-DAD. The limits of quantitation (LOQ) of bistifluron and cyenopyrafen were 0.02 mg/kg and 0.04 mg/kg, respectively. The recoveries of bistrifluron and cyenopyrafen were 99.5~108.7% and 88.4~98.9% at two different concentration levels. The biological half-lives of field I (Sejong) and field II (Pyeongtaek) were 6.1 and 7.0 days for bistifluron, and 6.3 and 7.0 days for cyenopyrafen, respectively. The 95% confidence intervals of dissipation rate constants of bistrifluron in peach were 0.0805~0.1457 and 0.0577~0.1417 for field I and field II, respectively, and those of cyenopyrafen were 0.0911~0.1278 and 0.0576~0.1417, respectively. CONCLUSION: Residue dissipation of bistrifluron and cyenopyrafen in peach were similar to that of correction to sample weight difference during the harvest periods. This study suggests that residue dissipation rate would be helpful to set the PHRLs that protect public health.

• 대한환경공학회지
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• 제29권7호
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• pp.839-845
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• 2007

용해성 glucose를 기질로 하여 혐기성 산발효조에서 동역학정수에 대한 온도의존성을 검토하였다. 온도범위는 $15^{\circ}C$에서 $30^{\circ}C$이며, 포화정수$(K_s\upsilon)$와 증식수율(Y)은 온도의 상승에 따라 감소하였지만, 최대비기질소비속도$(\upsilon_{max})$는 증가하였다. 기질소비속도와 균체 증식속도의 온도보정인자$(Q_{10})$ 값은 각각 1.3에서 2.2, 1.5에서 2.2의 범위를 보였다. 최대비기질소비속도$(\upsilon_{max})$가 증식수율(Y) 보다 온도의 변화에 대하여 더 민감하였다. $20^{\circ}C$에서 $30^{\circ}C$까지의 온도영역에서 체류시간과 기질농도의 관계에 대한 시물레이션 모델은 $1/SRT={(6.53){\cdot}(1.038)^{T-20}{\cdot}(S/X)}/{(1.38){\cdot}(0.983)^{T-20}+(S/X)}$이다.