• Title/Summary/Keyword: Constant-rate Drying

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Enhanced TPH Degradation of Diesel-Contaminated Soil by Microwave Heating (디젤오염토양의 TPH 분해를 위한 마이크로파의 가열특성)

  • Jung, Byung-Gil;Kim, Dae-Yong;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.479-484
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    • 2008
  • The application of microwave technology has been investigated in the remediation of diesel-contaminated soil. The paper deals with economic assessment by means of cost analysis and degradation characteristics at different microwave powers for total petroleum hydrocarbon (TPH) in diesel contaminated soils. The soils from S Mountain around the D University were sampled. The samples were screened with 2.0 mm mesh and dried for 6 hours before the diesel was added into the dried soils. The diesel-contaminated soil (3,300 mg THP/kg soil) was prepared with diesel (S Co.). The drying process was carried out in a microwave oven, a standard household appliance with a 2,450 MHz frequency and 700 W of power. The experiments were conducted from 0 to 20 minutes as the microwave powers increased from 350W to 500W to 700W. The concentrations of TPH were analysed using a gas chromatography/mass spectrometer (GC/MS). The initial concentration of TPH was 3,300 mg TPH/kg soil. The weight of contaminated soil was 200g. The concentration of TPH was decreased to 1,828 mg TPH/kg soil (44.7%), 1,347 mg TPH/kg soil (59.2%) and 1,014 mg TPH/kg soil (69.3%) at 350W, 500W and 700W for 15 minutes respectively. In addition, the curve was best fit with first order kinetics using the least-square method. The ranges of a first order rate constant k and r-square were $0.0298{\sim}0.0375min^{-1}$ and $0.9373{\sim}0.9541$ respectively.

A Study on Process Design of Hot Oil Flushing System Using Oil-Nitrogen Gas Mixing Fluid (오일-질소가스 혼합유체를 이용한 고온 오일플러싱 시스템 공정설계에 관한 연구)

  • Lee, Yoon-Ho;Choi, Bu-Hong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.5
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    • pp.541-548
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    • 2017
  • A theoretical study on gas-liquid two-phase flow flushing systemnitrogen gas to the oil used for existing flushing equipment was conducted on the basis of ISO code so as to improve performance of existing high-temperature oil flushing equipment used in ocean plant facility drying field. For study, we analyzed process simulation results mixed fluid mixing ratio, temperature, Reynolds number and liquid hold up affectcleaning performance after designing oil-nitrogen gas mixture flushing system process. As a result, as the volume flow rate of mixed fluid increases with the tube diameter the volume fraction of the gas phase constant, the liquid fraction difference value at the inlet and outlet of horizontal hydraulic piping increases. It was found that the phase distribution between oil and nitrogen gas bubbles varies depending on the position the pipe lengthdirection. This change in phase distribution is expected to have a significant impact on the clean performance of an oil-nitrogen gas mixture flushing system.

Model Development of Spray Dryer Absorber FGD Process (Spray Dryer Absorber 배연탈황공정의 모델 개발)

  • Jang, Sun-Hee;Oh, Eui-Kyung;Lee, Hyung-Keun;Kim, Sun-Geon
    • Clean Technology
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    • v.2 no.1
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    • pp.80-95
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    • 1996
  • A mathematical model has been developed for simulating the spray dryer absorber (SDA) used in semi-dry flue gas desulfurization process. Fundamental equations include the component mass and heat balances in both gas and droplet phases and the equation of motion for a single droplet. The model developed described the pilot-plant data much better than the existing SPRAYMOD-M model. The effect of the process variables, whose values were chosen within the operation limits of the actual pilot plants, on % $SO_2$ removal or conversion of the sorbent were calculated, and discussed in terms of $SO_2$ absorption rate, the residence time of flue gas, the velocity and drying time of droplets. Finally, the % $SO_2$ removal was calculated with two independent process variables and the results were shown on three-dimensional or two-dimensional diagrams with the lines of constant % $SO_2$ removal, so that they can be easily applied to preliminary design of the SDA.

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Characterization of Hyaluronic Acid Membrane Containing Lactic Acid (젖산이 결합된 히아루론산 막의 특성)

  • Cheong Seong Ihl;Kwon Ji Young
    • Membrane Journal
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    • v.15 no.1
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    • pp.8-14
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    • 2005
  • The hyaluronic acid (HA) with excellent biocompatibility can be combined with the monomer polylactide with good biodegradability to produce biocompatible materials which can control the period of degradation in a human body. By freeze drying method, HA and the lactic acid, monomer of polylactide, or lactide, the ester dimer of polylactide, were crosslinked with crosslinking agent, l-ethyl-3-(3-dimethyl aminopropyl) carbodiimide. The analysis of infrared spectroscopy showed that the ester linkage was formed and the analysis of nuclear magnetic resonance (NMR) spectroscopy showed that the ester linkage was due to the reaction of lactic acid and HA. The conversion (6∼32%) and degree of crosslinking (4∼19%) increased but the selectivity was almost constant at 62% as the mole ratio of LA to HA increased from 1 to 10 in the crosslinking reaction. The brittleness became more pronounced and the rate of degradation became faster with more addition of lactic acid resulting from the higher ratio of LA to HA, and the swelling ratio was in the range of 500 to 2000%.

Analysis of Stream Depletion due to Groundwater Pumping in Variable Stream Stages Using an Analytical Model (해석적 모형을 이용한 지하수 양수 및 하천수위 변화에 따른 하천수 감소 특성 분석)

  • Lee, Jeongwoo
    • The Journal of Engineering Geology
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    • v.29 no.4
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    • pp.439-449
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    • 2019
  • To prevent the drying-out of streams and to make effective use of stream water and groundwater, it is necessary to evaluate the impact of groundwater pumping on nearby streams. To this end, stream depletion due to groundwater pumping should be investigated in terms of various hydraulic characteristics of the aquifer and stream. This study used the Baalousha analytical solution, which accounts for stream-stage variation over time, to analyze stream depletion due to groundwater pumping for cases where the stream level decreases exponentially and recovers after the decrease. For conditions such as an aquifer transmissivity of 10~100 ㎡ d-1, storage coefficient 0.05~0.3, streambed hydraulic conductance 0.1~1.0 m d-1, stream-well distance 100~500 m, and stage recession coefficient 0.1~1.0 d-1, the contribution of stream water (the dimensionless ratio of stream water reduction rate to groundwater pumping rate) was analyzed in cases where stream level change was considered. Considering the effect of stream-stage recession, the contribution of stream water is greatly reduced and is less affected by the stream-depletion factor, which is a function of the stream-to-well distance and hydraulic diffusivity. However, there is no significant difference in stream depletion under constant- and variable-stage recovery after recession. These results indicate that stream level control can distribute the relative impacts on stream water and aquifer storage during groundwater pumping

Enhanced Nasal Absorption of Ketoconazole by Inclusion with Cyclodextrin (시클로덱스트린과의 포접에 의한 케토코나졸의 비점막 흡수증가)

  • Park, Gee-Bae;Seo, Bo-Youn;Ann, Hong-Jik;Rho, Hyun-Goo;Onn, Yun-Sung;Lee, Kwang-Pyo
    • Journal of Pharmaceutical Investigation
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    • v.24 no.2
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    • pp.95-104
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    • 1994
  • Inclusion complexes of ketoconazole(KT) with ${\alpha}^_$, ${\beta}^_$cyclodextrin(CD) and $dimethy1-{\beta}-cyclodextrin$ (CD) and $dimethy1-{\beta}-cyclodextrin(DM{\beta}CD)$ as nasal absorption enhancer were prepared in 1: 2 molar ratios by freeze-drying and solvent evaporation methods. In order to compare with the intrinsic absorptivity of KT in the jejunum(J) and the nasal cavity(N), the in situ simultaneous perfusion method was employed. The in situ recirculation study revealed that KT-CD inclusion complexes with the greater stability constant and the faster dissolution rate proportionally increased the absorption of KT in the J and N of rats. The rank order of apparent KT permeability$(P_{app}\;:\;cm/sec\;{\time}\;1O^{-5}{\pm}S.E.)$, corrected by surface area of absorption, was $5.10{\pm}0.3(N,\; KT-DM{\beta}CD)$ )> $4.13{\pm}0.4(N,\;KT-{\beta}-CD)$ )> $3.52{\pm}0.2(N,\;KT-{\alpha}-CD)$ )> $2.76{\pm}0.3(J,\; KT-DM{\beta}CD)$ )> $2.61{\pm}0.5(J,\;KT-{\beta}-CD)$ )> $2.42{\pm}0.4(J,\;KT-{\alpha}-CD)$ at pH 4.0. The in crease in permeability of $KT-DM{\beta}CD$ inclusion complex was 2.6 folds in the J and 4.5 folds in the N when the perfusing solution was changed from the buffer(pH 4.0) to saline. The absorption rate of $KT-DM{\beta}CD$ inclusion complex after nasal administration was more rapid than those of ketoconazole alone and $KT-DM{\beta}CD$ inclusion complex after oral administration to rats. In comparision with an oral administration of ketoconazole suspension in corn oil, the relative bioavailability was calculated 137.3% for the oral and 195.0% for nasal $KT-DM{\beta}CD$ inclusion complex in rats. The present results suggest that $KT-DM{\beta}CD$ inclusion complex may serve as a potential nasal absorption enhancer for the nasal delivery of ketoconazole.

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Studies on Packaging of Spray-dried Soy Sauce by Means of Flexible Films and Their Laminates (유연(柔軟) 포장재료(包裝材料)를 이용(利用)한 분말(粉末) 간장의 포장(包裝)에 관(關)한 연구(硏究))

  • Chang, K.S.;Yoon, H.K.;Kim, M.S.
    • Applied Biological Chemistry
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    • v.21 no.3
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    • pp.144-149
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    • 1978
  • Fermented soy sauce was dehydrated by spray drying to form powder, and moisture sorption properties of powdered soy sauce with or without cover of the flexible films were examined on different relative humidity by using saturated salt solutions at $30^{\circ}$. The results obtained were summarized as follows: The equilibrium moisture content of spray-dried soy sauce containing 18.3% moisture was determined to 52% by graphical interpolation method, and E.M.C. of powdered soy sauce covered with plastic films decreased at low relative humidity whereas sharply increased curves were seen at high relative humidity. The rate constant of moisture adsortion K for the power covered with films were $66.2{\times}10^{-5}\;to\;225{\times}10^{-5}/hr$., and K' became greater when film having higher water vapor transmission rate was used. The shelf-life of powdered soy sauce covered with Al. foil/P.E. film by Brown formula at the accelerated condition of $38^{\circ}$, 92% R. H. was the longest period, 164 days compared with any other films used, and the shortest period, 18 days in P.V.C. film.

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Properties of Dangmyuns Using Different Starches and Freeze Dried Dangmyuns (몇가지 전분으로 만든 당면과 동결건조 당면의 특성)

  • Lee, Young-Chul;Oh, Se-Wook;Han, Seung-Bae;Han, Sun-Dong;Kang, Nam-Kil
    • Korean Journal of Food Science and Technology
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    • v.34 no.1
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    • pp.24-29
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    • 2002
  • The study was performed to investigate the degrees of gelatinization at various processing steps during the preparation of Dangmyuns using sweet potato, potato, corn and tapioca starches, and also determined the rehydration of the freeze dried sweet potato Dangmyun. The degrees of gelatinization after extrusion cooking showed higher value than other processing steps. The degrees of gelatinization after extrusion cooking were 63.5% in sweet potato, 80.0% in potato, 82.3% in corn, and 86.5% in tapioca Dangmyuns. The degree of gelatinization in Dangmyuns after extrusion cooking step decreased as the processing steps, such as cold storage, freezing, thawing, and sun drying, progressed. L values of color in Dangmyuns decreased in the order of corn>tapioca>potato>sweet potato Dangmyuns. The cooking loss decreased in the order of tapioca>corn>potato>sweet potato Dangmyuns. The percentage of weight gain was the highest in sweet potato Dangmyun followed by corn, potato, and tapioca Dangmyuns. The water absorption rate constant was the highest in sweet potato Dangmyun followed by corn, potato, and tapioca Dangmyuns. In the rehydration of freeze dried Dangmyuns, freeze dried sweet potato Dangmyun showed better than the others. An increase from 60% to 70% of the added amount of water in the mixing step resulted in an increase of the degrees of gelatinization after extrusion cooking from $63.4{\sim}70.7%$ to $73.8{\sim}75.0%$. An increase of the added water in the mixing step and a decrease of diameter in the extrusion cooking step slightly improved the rehydration in the boiled water of freeze dried sweet potato Dangmyun.

GABA Productivity in Yoghurt Fermented by Freeze Dried Culture Preparations of Lactobacillus acidophilus RMK567 (Lactobacillus acidophilus RMK567의 동결건조 컬쳐로 제조한 요구르트에서 GABA 생성력)

  • Lim, Sang-Dong;Yoo, Sung-Ho;Yang, Hae-Dong;Kim, Sang-Ki;Park, Seung-Yong
    • Food Science of Animal Resources
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    • v.29 no.4
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    • pp.437-444
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    • 2009
  • ${\gamma}-Aminobutyric$ acid (GABA) producing lactic acid bacteria, Lactobacillus acidophilus RMK567 was cultivated in 50 L of sterilized MRS broth using a fermenter at $40^{\circ}C$ for 24 h. The cell number was increased to $10.04{\pm}0.13$ Log CFU/mL with a growth rate constant (k) of 0.454 generation/h and a generation time (g) of 2.303 h after a lapse of a lag phase (L) of 5.16 h. A total of 487 g of cell paste with 40.5% moisture was harvested with viable cell number of 12.48 Log CFU/g cell paste. The cell pastes after preparation with glycerol, glucose, and polydextrose as cryo-protectants were lyophilized under a vacuum of 84 m torr. A total of 408 g of freeze dried (FD) cell powders were mixed with a commercial strain of Streptococcus thermophilus to prepare of three types FD starter cultures with the viable cell numbers of 12.42 (FDA-GY), 12.60 (FDBGG) and 12.91 (FDC-GP) Log CFU/g. During preservation the FD cultures at -$18^{\circ}C$, the cell viability of the FD starter cultures were rapidly dropped to below 3.24% of the day of storage. No significant difference was found in the cell viabilities among three types of FD starters cultures, but significant difference (p<0.01) was found in storage periods. Yoghurts fermented through FD starter culture of L. acidophilus RMK567 were determined to contain $155.16{\pm}8.53$ ppm, $243.82{\pm}4.27$ ppm, and $198.64{\pm}23.46$ ppm of GABA, respectively. This study shows that GABA production activity of L. acidophilus RMK567 is not affected during the freeze drying process and would be available for commercial production of yoghurt containing high GABA content.

A Study on the Growth Analysis of Pinus koraiensis Seedings under Various Relative Light Intensities and Planting Densities (잣나무 묘목(苗木)의 생육환경(生育環境) 요인(要因)에 따른 생장해석적(生長解析的) 연구(硏究))

  • Kim, Young Chai
    • Journal of Korean Society of Forest Science
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    • v.78 no.3
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    • pp.314-322
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    • 1989
  • For the improvement of nursery condition and the study of eco-physiological characteristics of Pinus koraiensis(2-2) seedlings, the primary productivity was investigated and the growth characteristics and their correlationship were analyzed from May to September in 1987. Seedlings used in this study were grown at the nursery of Experimental Forestry of Kyung Hee Univ. The installation of experimental plots were divided into control plot (100%), 63%, 37% and 19% relative light intensity, and each relative light intensity plots were split into $15{\times}15/m^2$, $12{\times}12/m^2$, $9{\times}9/m^2$ and $6{\times}6/m^2$ plnting density by randomized black design method. To take into account the edge effect of plant population, material were selected from each plot by random sampling at 30 days interval. Each sampled material was divided into leaf and stem drived in a drying oven at the temperature of $85^{\circ}C$ until it had constant weight and weighed. and leaf area was surveyed. Growth analysis for RGR and NAR was done by Blackman method and correlation coefficient were investigated between RGR and NAR by analyzing the dry matter production and growth characteristics of the material, cultivated on the experimental nursery under the condition of different treatment the obtained result were as follows : 1. The increasing rate of dry matter was similar at early stage of growth, but not at late stage. 2. Leaf area growth was the maximum value at 63% relative light intensity and the minimum at 19% RLI 3. The value of RGR was the highest on June under $6{\times}6/m^2$ planting density in 63% relative light intensity, the lowest on September under $12{\times}12/m^2$ of 19% relative light intensity. 4. The change NAR decreased in early stage of growth, while it increased on August and September, The value of RGR on June under $6{\times}6/m^2$ planting density in 100 light intensity was the highest, and on September under $12{\times}12/m^2$ planting density in 19% relative light intensity was the lowest. 5. Regression and correlation between RGR and NAR showed significantly positive.

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