• Title/Summary/Keyword: Constant rate model

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A Determination of Design Parameters for Application of Composite Coil Spring in a Passenger Vehicle (승용차 복합재 코일스프링 개발을 위한 설계변수들의 결정)

  • Oh, Sung-Ha;Choi, Bok-Lok
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.1
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    • pp.77-83
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    • 2013
  • This paper presents the feasibility on the application of composite coil spring, which has great interest in the automobile industry. In order to obtain much lighter weight of the composite spring, it will be necessary to optimize the design variables such as fiber angles and diameter of coil, etc. First of all, mechanical properties were measured to consider the effects of FVR and ply angles for carbon fiber composite material. And the shear modulus with respect to ply angles were derived based on twisting angles calculated by torsional beam model. Next we determined the design parameters of composite coil spring, which has equivalent spring rate to the steel coil spring. In order to assess the proposed method, finite element model of the composite spring was developed and analysed to obtain the spring constant. The results showed that static spring rate of the composite spring was in a good agreement with that of steel spring.

Flame Hole Dynamics Model of a Diffusion Flame in Turbulent Mixing Layer (난류 혼합층에서 확산화염에 대한 flame hole dynamics 모델)

  • Kim, Jun-Hong;Chung, S.H.;Ahn, K.Y.;Kim, J.S.
    • Journal of the Korean Society of Combustion
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    • v.8 no.3
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    • pp.15-23
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    • 2003
  • Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics in order to develop a prediction model for turbulent flame lift off. The essence of flame hole dynamics is derivation of the random walk mapping, from the flame-edge theory, which governs expansion or contraction of flame holes initially created by local quenching events. The numerical simulation for flame hole dynamics is carried out in two stages. First, a direct numerical simulation is performed for constant-density fuel-air channel mixing layer to obtain the turbulent flow and mixing fields, from which a time series of two dimensional scalar dissipation rate array is extracted at a fixed virtual flame surface horizontally extending from the end of split plate to the downstream. Then, the Lagrangian simulation of the flame hole random walk mapping projected to the scalar dissipation rate array yields temporally evolving turbulent extinction process and its statistics on partial quenching characteristics. The statistical results exhibit that the chance of partial quenching is strongly influenced by the crossover scalar dissipation rate while almost unaffected by the iteration number of the mapping that can be regarded as a flame-edge speed.

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Photopolymerization Kinetics of Urethane-acrylate Oligomer (우레탄-아크릴레이트 올리고머의 광경화 거동)

  • Kim, In-Beom;Song, Bong Jin;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.33-36
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    • 2006
  • The kinetics of photopolymerization of urethane-acrylate oligomer which has many applications in photopolymerizable adhesives was analysed to investigate the influence of polymerization temperature and functionality of oligomer using the autocatalytic model. It was revealed that the maximum polymerization rate decreased as the polymerization temperature increased. The reaction rate constant, k, showed little change with the increase in polymerization temperature, while exponents m and n exhibited an increase. These results could be related to the diffusion and mobility restriction of reactive species during the cross-linking reaction. The decrease in photopolymerization rate with increase of temperature was mainly controlled by the reaction order n.

Fractal kinetic characteristics of uranium leaching from low permeability uranium-bearing sandstone

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Tan, Kaixuan;Zhang, Shuwen;Ye, Wenhao
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1175-1184
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    • 2022
  • The pore structure of uranium-bearing sandstone is one of the critical factors that affect the uranium leaching performance. In this article, uranium-bearing sandstone from the Yili Basin, Xinjiang, China, was taken as the research object. The fractal characteristics of the pore structure of the uranium-bearing sandstone were studied using mercury intrusion experiments and fractal theory, and the fractal dimension of the uranium-bearing sandstone was calculated. In addition, the effect of the fractal characteristics of the pore structure of the uranium-bearing sandstone on the uranium leaching kinetics was studied. Then, the kinetics was analyzed using a shrinking nuclear model, and it was determined that the rate of uranium leaching is mainly controlled by the diffusion reaction, and the dissolution rate constant (K) is linearly related to the pore specific surface fractal dimension (DS) and the pore volume fractal dimension (DV). Eventually, fractal kinetic models for predicting the in-situ leaching kinetics were established using the unreacted shrinking core model, and the linear relationship between the fractal dimension of the sample's pore structure and the dissolution rate during the leaching was fitted.

Cutting Force Estimation Considering the Specific Cutting Force Constant (비절삭 저항상수에 따른 절삭력 예측)

  • Kim, Jong-Do;Yoon, Moon-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.10
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    • pp.75-82
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    • 2019
  • Few studies have been conducted regarding theoretical turning force modelling while considering cutting constant. In this paper, a new cutting force modelling technique was suggested which considers the specific cutting force coefficients for turning. The specific cutting force is the multiplication of the cutting force coefficient and uncut chip thickness. This parameter was used for experimental modelling and prediction of theoretical cutting force. These coefficients, which can be obtained by fitting measured average forces in several conditions, were used for the formulation of three theoretical cutting forces for turning. The cutting force mechanism was verified in this research and its results were compared with each of the experimental and theoretical forces. The deviation of force was incurred by a small amount in this model and the predicted force considering feed rate, nose radius, and radial depth shows a physical behavior in main force, normal force, and feeding force, respectively. Therefore, this modelling technique can be used to effectively predict three turning forces with different tool geometries considering cutting force coefficients.

Measurement and Acceleration of Biodegradation in Soil. (토양매립에 의한 생분해도 측정 및 가속화)

  • 김은정;박태현;신평균
    • Microbiology and Biotechnology Letters
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    • v.26 no.5
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    • pp.465-469
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    • 1998
  • The quantitative and rapid method for measuring the biodegradation of polymer materials in soil was developed. In this study, cellophane film was used as a model biodegradable polymer and the biodegradation was assayed by measuring the amount of glucose which was produced by a hydrolysis reaction using HCl after collecting the film from soil. Cellophane film was degraded 41.2% in 4 months during winter while it was degraded 76.5% in 2 months during summer. It means that biodegradation in soil is affected by environmental conditions. The biodegradation was also measured in an incubator (30$^{\circ}C$, humidity 50-55%) to exclude the environmental variations. Cellophane film was degraded 94% in that condition in 40 days. The biodegradation showed the first order kinetics and the rate constant was 0.067 (1/day). Acceleration of the biodegradation in soil was also studied. We added cultured soil microorganisms or nutrients such as N, P, and S into the soil. While the addition of microorganisms showed the temporary increase of rate constant, the addition of nutrients not only showed the increase of rate constant from 0.096 (1/day) to 0.21 (1/day) but also maintained the effect continuously.

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Influence of barley grain treated with alkaline compounds or organic extracts on ex vivo site and extent of digestion of starch

  • Naseroleslami, Reza;Mesgaran, Mohsen Danesh;Tahmasbi, Abdolmansour;Vakili, Seyed Alireza;Ebrahimi, Seyed Hadi
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.2
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    • pp.230-236
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    • 2018
  • Objective: Two ex vivo experiments were conducted to verify the effect of barley grain (Nusrat cultivar) treated with alkaline compounds (AC) including alum, ammonium, and sodium hydroxide or cation-exchanged organic extracts (OE) prepared from alfalfa hay, sugar beet pulp and Ulva Fasciata, on extent and digestion of starch. Methods: In the first study, the in vitro first order disappearance kinetic parameters of dry matter (DM), crude protein (CP) and starch were estimated using a non-linear model ($D_{(t)}=D_{(i)}{\cdot}e^{(-k_d{\cdot}time)}+I$, where: $D_{(t)}$ = potentially digestible residues at any time, $D_{(i)}$ = potentially digestible fraction at any time, $k_d$ = fractional rate constant of digestion (/h), I = indigestible fraction at any time). In the second experiment, the ruminal and post-ruminal disappearance of DM, CP, and starch were determined using in situ mobile nylon bag. Results: Barley grains treated with alum and alfalfa extract had a higher constant rate of starch digestion (0.11 and 0.09/h) than others. Barley grain treated with OE had a higher constant rate of CP digestion and that of treated with AC had a higher constant rate of starch digestion (0.08 and 0.11/h) compared with those of the other treatments. The indigestible fraction of starch treated with alum and sugar beet pulp extract was higher than that of the control group (0.24 and 0.25 vs 0.21). Barley grain treated with AC and OE had significant CP disappearance in the rumen, post-rumen and total tract, and also starch disappearance for post-rumen and total tract compared with the untreated (p<0.001). Conclusion: This study demonstrated that AC and OE might have positive effects on the starch degradation of the barley grain. In addition, treating barley grain with alum and sugar beet pulp extract could change the site and extend digestion of protein and starch.

Clinical Pharmacokinetics of Vancomycin in Ovarian Cancer Patients (난소암 환자에서 반코마이신의 임상약물동태)

  • Kim, Yang Woo;Choi, Jun Shik;Lee, Jin Hwan;Park, Jae Young;Choi, Byong Chul;Burm, Jin Pil
    • Korean Journal of Clinical Pharmacy
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    • v.8 no.1
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    • pp.13-18
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    • 1998
  • The purpose of this study was to determine pharmacokinetic parameters of vancomycin using the compartment model dependent and compartment model independent analysis in 6 Korean normal volunteers and 8 ovarian cancer patients. Vancomycin was administered 1.0 g bolus by IV infusion over 60 minutes. The elimination rate constant ($\beta$), volume of distribution (Vd), total body clearance (CLt), and area under the plasma level-time curve (AUC) of vancomycin in normal volunteers using the compartment model dependent analysis were $0.150\pm0.030\;hr^{-1},\;32.9\pm2.81\;L/kg,\;5.36\pm0.63\;L/hr,\;and\;186.5\pm20.5\;{\mu}g/ml{\cdot}hr$, respectively. The $\beta$, Vd, CLt, and AUC of vancomycin in ovarian cancer patients using the compartment model dependent analysis were $0.109\;0.008\;hr^{-1},\;41.5\pm3.01\;L/kg,\;4.58\pm0.57\;L/hr\;and\;218.3\pm22.9\;{\mu}g/ml{\cdot}hr$, respectively. There were significant differences (p<0.05,\;p<0.01) in $\beta$, Vd, CLt, and AUC between normal volunteers and ovarian cancer patients. The elimination rate constant (Kel), CLt, and AUC of vancomycin in normal volunteers using the compartment model independent analysis were $0.152\pm0.022\;hr^{-1},\;5.77\pm0.75\;L/hr,\;and\;173.2\pm22.5;{\mu}g/ml{\cdot}hr$, respectively. The Kel, CLt, and AUC of vancomycin in ovarian cancer patients using the compartment model independent analysis were $0.126\pm0.012\;hr^{-1},\;4.96\pm0.55\;L/hr,\;and\;201.7\pm25.6;{\mu}g/ml{\cdot}hr$, respectively. There were significant differences (p<0.05, p<0.01) in Kel, CLt, and AUC between normal volunteers and ovarian cancer patients. And also, there was significant difference (p<0.05) in Kel of vancomycin in ovarian cancer patients between the compartment model dependent and independen analysis. It is necessary for effective dosage regimen of vancomycin in ovarian cancer patient to use these population parameters.

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Estimation of Empirical Fatigue Crack Propagation Model of AZ31 Magnesium Alloys under Different Maximum Loads (최대하중 조건에 따른 AZ31 마그네슘합금의 실험적 피로균열전파모델 평가)

  • Choi, Seon-Soon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.522-528
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    • 2012
  • It is the aim of this paper to propose the empirical fatigue crack propagation model fit to describe a crack growth behavior of AZ31 magnesium alloys. The statistical data of a crack growth for an estimation are obtained by fatigue crack propagation tests under the three cases of maximum load. The empirical models estimated are Paris-Erdogan model, Walker model, Forman model, and modified-Forman model. It is found that the empirical model fit to describe a crack growth behavior of AZ31 magnesium alloys is Paris-Erdogan model and Walker model. It is also verified that a fatigue crack growth rate exponent of a empirical model is to be a material constant.

Liquid-liquid extraction process for gas separation from water in polymeric membrane: Mathematical modeling and simulation

  • Salimi, Nahid;Moradi, Sadegh;Fakhar, Afsaneh;Razavi, Seyed Mohammad Reza
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.463-476
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    • 2016
  • In this study, application of polypropylene hollow fiber membrane contactors for $CO_2$ removal from water in liquid-liquid extraction (LLE) mode was simulated. For this purpose, a steady state 2D mathematical model was developed. In this model axial and radial diffusion was considered to $CO_2$ permeation through the hollow fibers. $CO_2$ laden water is fed at a constant flow rate into the lumen side, permeated through the pores of membrane and at the end of this process, $CO_2$ solution in the lumen side was extracted by means of aqueous diethanolamine (DEA) and chemical reaction. The simulation results were validated with the experimental data and it was found a good agreement between them, which confirmed the reliability of the proposed model. Both simulation and experimental results confirmed the reduction in the percentage of $CO_2$ removal by increment of feed flow rate.