• Title/Summary/Keyword: Configurational evolution

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Capturing the Underlying Structure of a 'Segment-line' City: Its Configurational Evolution and Functional Implications

  • Ling, Michelle Xiaohong
    • International Journal of High-Rise Buildings
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    • v.6 no.2
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    • pp.139-147
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    • 2017
  • Analyzing morphological evolution over a long period of time is deemed an effective way to identify problems occurring in the process of urban development, in addition to achieving a fundamental understanding of socio-cultural changes and growth rooted from the context. As far as the urban morphology is concerned, Hong Kong is characterized by its unique high-density and compact layout patterns, which have aroused the interest of a number of authors in the urban design domain. Whilst an increasing number of redevelopment projects in Hong Kong were criticized for ignoring and destroying the old urban fabric, there is a need for research to investigate the origins and changes of various urban patterns and their implications for society. By employing the theories and techniques of space syntax, this paper accordingly provides a morphological analysis based on the Wanchai District - a 'Segment-line' city, which particularly epitomizes various urban grids of Hong Kong and may have different implications for functional aspects. By axial-mapping the urban layouts of five stages of growth since 1842 and subsequently investigating their spatial and functional transformation over the past 170 years, this paper identifies a series of spatial characteristics underlying different grid patterns, as well as achieves a precise understanding of their ever changing relationship. Based on these understandings, this paper intends to provide valuable reference and guidance for upcoming spatial development in Hong Kong and other regions.

Numerical simulations of elliptic particle suspensions in sliding bi-periodic frames

  • Chung, Hee-Taeg;Kang, Shin-Hyun;Hwang, Wook-Ryol
    • Korea-Australia Rheology Journal
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    • v.17 no.4
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    • pp.171-180
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    • 2005
  • We present numerical results for inertialess elliptic particle suspensions in a Newtonian fluid subject to simple shear flow, using the sliding bi-periodic frame concept of Hwang et al. (2004) such that a particulate system with a small number of particles could represent a suspension system containing a large number of particles. We report the motion and configurational change of elliptic particles in simple shear flow and discuss the inter-relationship with the bulk shear stress behaviors through several example problems of a single, two-interacting and ten particle problems in a sliding bi-periodic frame. The main objective is to check the feasibility of the direct simulation method for understanding the relationship between the microstructural evolution and the bulk material behaviors.

Molecular Dynamics Simulation on the Behavior of Si(001) Vicinal Surface by Using Empirical Tersoff Potential (Tersoff 포덴셜을 이용한 Si(001) 미사면 거동에 대한 분자동력학적 연구)

  • Choi, Jung-Hae;Cha, Pil-Ryung;Lee, Seung-Cheol;Oh, Jung Soo;Lee, Kwang-Ryeol
    • Korean Journal of Metals and Materials
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    • v.47 no.1
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    • pp.32-37
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    • 2009
  • Molecular dynamic simulations on the structural evolution of the Si(001) vicinal surfaces, which are tilted with respect to [100] and [110] directions were performed by using the empirical Tersoff potential. Tersoff potential was implemented at LAMMPS code and confirmed to describe the properties of Si. When the steps are generated along [100] direction, symmetric dimer rows formed with respect to the step edges. On the other hand, when the steps are generated along [110] direction, alternating dimer rows form with respect to the step edges. The configurational differences between the two vicinal surfaces were discussed in terms of the surface diffusion and the possibility of preventing step bunching for the (001) vicinal surface tilted along [100] direction was suggested.

Effect of Lead Content on Atomic Structures of Pb-bearing Sodium Silicate Glasses: A View from 29Si NMR Spectroscopy (납 함량에 따른 비정질 Pb-Na 규산염의 원자 구조에 대한 고상 핵자기 공명 분광분석 연구)

  • Lee, Seoyoung;Lee, Sung Keun
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.3
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    • pp.157-167
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    • 2021
  • Lead (Pb) is one of the key trace elements, exhibiting a peculiar partitioning behavior into silicate melts in contact with minerals. Partitioning behaviors of Pb between silicate mineral and melt have been known to depend on melt composition and thus, the atomic structures of corresponding silicate liquids. Despite the importance, detailed structural studies of Pb-bearing silicate melts are still lacking due to experimental difficulties. Here, we explored the effect of lead content on the atomic structures, particularly the evolution of silicate networks in Pb-bearing sodium metasilicate ([(PbO)x(Na2O)1-x]·SiO2) glasses as a model system for trace metal bearing natural silicate melts, using 29Si solid-state nuclear magnetic resonance (NMR) spectroscopy. As the PbO content increases, the 29Si peak widths increase, and the maximum peak positions shift from -76.2, -77.8, -80.3, -81.5, -84.6, to -87.7 ppm with increasing PbO contents of 0, 0.25, 0.5, 0.67, 0.86, and 1, respectively. The 29Si MAS NMR spectra for the glasses were simulated with Gaussian functions for Qn species (SiO4 tetrahedra with n BOs) for providing quantitative resolution. The simulation results reveal the evolution of each Qn species with varying PbO content. Na-endmember Na2SiO3 glass consists of predominant Q2 species together with equal proportions of Q1 and Q3. As Pb replaces Na, the fraction of Q2 species tends to decrease, while those for Q1 and Q3 species increase indicating an increase in disproportionation among Qn species. Simulation results on the 29Si NMR spectrum showed increases in structural disorder and chemical disorder as evidenced by an increase in disproportionation factor with an increase in average cation field strengths of the network modifying cations. Changes in the topological and configurational disorder of the model silicate melt by Pb imply an intrinsic origin of macroscopic properties such as element partitioning behavior.