• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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• pp.93-93
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• 2003

Electrically conducting polyaniline/cyanoethyl resin (PANI/Cyan) blends were prepared by in situ polymerization. The mechanical properties of the blend films increased with increasing cyanoethyl resin and the blend films have moderate conductivity.

• E2M - 전기 전자와 첨단 소재
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• 제9권2호
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• pp.165-173
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• 1996

We prepared polythiophene and poly(3-methylthiophene) films, known as conducting polymer, by electrochemical method. Polythiophene and poly(3-methylthiophene) films were doped and undoped dopant for the studing the understanding of doping mechanism and possible application to the color change switch. We observed that the anodic, cathodic wave and absorption spectra were slightly changed during doping and undoping process in polythiophene. It shows that doping and undoping process were showed some difference by the appearance and disappearance of polaron and bi-polaron. In the relation of the peak of oxidative current density and potential sweep rate of cyclic voltammograms, the amount of dopant in polythiophene film was homogeneously increased at low scan rate. This also can be applied to the poly(3-methlythiophene).

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.927-933
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• 2011

Conducting polyaniline-poly($\varepsilon$-caprolactone) polymer composites were synthesized via in situ deposition techniques. By dissolving different weight percentages of poly($\varepsilon$-caprolactone) (PCL) (10%, 20%, 30%, 40%, and 50%), the oxidative polymerization of aniline was achieved using ammonium persulfate as an oxidant. FTIR, UV-vis spectra, and X-ray diffraction studies support a strong interaction between polyaniline (PANI) and PCL. Structural morphology of the PANI-PCL polymer composites was studied using scanned electron microscopy (SEM) and transmittance electron microscopy (TEM), and thermal stability was analyzed by thermogravimetric analysis (TGA) technique. The temperature-dependent DC conductivity of PANI-PCL polymer composite films was studied in the range of 305-475 K, which revealed a semiconducting behavior in the transport properties of the polymer films. Conductivity increased with the increase of PCL in below critical level, however conductivity of the polymer film was decreased with increase of PCL concentration higher than the critical value.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.81-82
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• 2006

In this study, the applications of the block copolymer thin films are introduced. For this purpose, we first obtained cylindrical nanodomains in polystyrene-block-poly(methyl methacrylate) copolymer perpendicularly oriented to a substrate. Then, nanoporous templates were prepared after removing the PMMA nanodomains by UV treatment. By using electropolymerization, high density nanowire arrays of conducting polymer of poly(pyrrole) and poly( 3-hexyl thiopene) were obtained and their electric properties were measured. Also, these nanoporous thin films were found to be very useful for the separation of human Rhinovirus type 14 (HRV 14), major pathogen of a common cold in humans, from the buffer solution.

• 통합자연과학논문집
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• 제2권2호
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• pp.69-72
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• 2009

Pentiptycenediacetylene is very useful precursor materials for the synthesis of conducting polymer materials. The incorporation of rigid three-dimensional pentiptycene moieties into conjugated polymer backbones would offer several design advantages. They prevent ${\pi}$-stacking of the polymer backbones and thereby maintain high fluorescence quantum yields and spectroscopic stability in thin films. The pentiptycenediactylene was synthesized and characterized by 1H- and 13C-NMR spectroscopy.

• 공업화학
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• 제26권3호
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• pp.275-279
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• 2015

전도성 고분자인 poly(3,4-ethylenedioxythiophene) : poly(styrenesulfonate) (PEDOT : PSS)는 우수한 전기 전도도와 광투과도, 유연성을 가지고 있기 때문에 유기태양전지와 유기발광소자의 투명전극으로서 많은 각광을 받고 있다. PEDOT : PSS의 전기 전도도는 솔벤트를 도핑함에 따라 큰 폭으로 증가한다는 사실은 잘 알려져 있다. 본 연구에서는 다양한 솔벤트의 도핑과 솔벤트 후처리 공정에 따른 PEDOT : PSS 박막의 전기 전도도와 구조적 특성 변화를 연구하였다. 솔벤트 도핑으로 PEDOT : PSS의 전도도는 884 S/cm까지 증가하였고, 후처리 공정을 통해서 1131 S/cm의 전도도 값을 얻을 수 있었다. 이러한 전도도의 증가는 PSS 물질이 빠져나가거나 구조적인 재배열에 따른 전도성 PEDOT 입자의 접촉 면적이 증가함에 따른 것으로 사료되고, 광학적인 방법으로 PSS의 추출을 관찰하였다. 솔벤트 후처리 공정은 PEDOT : PSS 박막의 전도도를 향상하는 매우 효과적인 방법으로 확인되었고, 저가형 플렉서블 유기전자소자의 투명전극으로써의 사용이 적합할 것으로 예상된다.

• 한국표면공학회지
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• 제30권4호
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• pp.223-230
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• 1997

Tungsten oxide and nickel oxide thin films were deposited onto ITO(Indium Tin Oxide) transparent glass by the E-beam evaporation and were used as a cathode and an anode for the EC(Electrochromic) smart window, respectively. Stoichiometric structures of the deposited films were investigated by the implementation of XPS(X-ray Photoelectron Spectroscopy) analysis and the results were $WO_{2.42}$ and $NiO_{0.44}$. This oxygen deficincy might affect affect the transparency of the thin films. The electrolyte for the EC smart windows was PAN-$LiCIO_4$ conducting polymer. EC(Ethylene Carbonate)and PC(Propylene Carbonate) were added as plasticizer to enhance ion conductivity. When the weight ratio of the EC : PC was 3 : 1, transmission difference and cycle life performance were tested. Polymer EC windows showed 40% $\Delta$T at 1.5V operating volage for 3,200 cycles. Structural degradation was observed by the SIMS(Secondary Ion Mass Spectroscopy) analysis and it was confirmed that structural degradation of polymer caused by the solvent evaporation was the main cause to degrade EC smart windows.

• Macromolecular Research
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• 제12권3호
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• pp.303-310
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• 2004

We have prepared an aqueous dispersion of poly(aniline-dodecyl benzene sulfonic acid complex) (PANI-DC) that has an intrinsic viscosity (〔η〕) near 1.3 dL/g using aniline as a monomer, dodecyl benzene sulfonic acid(DBSA) as a dopant/emulsifier, and ammonium peroxodisulfate(APS) as an oxidant. We found that the electrical conductivity of a PANI-DC pellet was 0.7 S/cm. A waterborne-polyurethane (WBPU) dispersion, obtained from isophorone diisocyanate/polytetramethylene oxide glycol/dimethylol propionic acid/ethylene diamine/triethylene amine, was used as a matrix polymer. We prepared blend films of WBPU/PANI-DC with variable weight ratios (from 99/1 to 66/34) by solution blending/casting and investigated the effects that the PANI-DC content has on the mechanical and dynamic mechanical properties, hardness, electrical conductivity, and antistaticity of these films. The tensile strength, percentage of elongation, and hardness of WBPU/PANI-DC blend films all decreased markedly upon increasing the PANI-DC content. The antistatic half-life time ($\tau$$\sub$$\frac{1}{2}$/) of pure WBPU film was about 110 s, but we found that those of WBPU/ultrasound-treated PANI-DC blend films decreased exponentially from 1.2 s to 0.1 s to almost 0 s upon increasing the PANI-DC content from 1 wt% to 15 wt% to > 15 wt%, respectively.

• Bulletin of the Korean Chemical Society
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• 제33권4호
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• pp.1128-1134
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• 2012

We investigated a new method for patterning organic field-effect transistors (OFETs) using a photopatternable conducting polymer nanocomposite, consisting of poly(3-hexylthiophene) (P3HT)-coated gold nanoparticles (AuNPs) that had been modified with a photoreactive cinnamate group, to form P3HT-AuNP-CI. We found that the addition of the cinnamate group to the nanoparticle surface assisted the preparation of a solvent-resistive semiconducting film and preserved the P3HT ordering, which was interrupted by Au-P3HT interactions, as well as provided UV-controllable electrical properties. The P3HT-AuNPs-CI films could be microscale-patterned via a UV crosslinking photoreaction, represented as a promising photopatternable semiconductor material for use in advanced applications, with tunable electrical properties for fabrication of sub-micron and microscale electronic devices.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.349-352
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• 1996

Electrical capacitance at the interface between electrolyte solution and conducting polypyrrole film electrode was measured by a simple electrochemical method. The polymer films were electropolymerized in the presence of perchlorate (PPy-ClO4) or Nafion (PPy-Nafion) anions as the dopant ions. Both polymers exhibited large double layer capacitances which were slightly potential dependent within the potential range where the polymers are conductive. The capacitance increased in proportion to the polymer thickness. The specific capacitance were about 10 Fg-1and 44 F g-1 for PPy-Nafion and PPy-ClO4, respectively.